• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.90.2-90.2
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• 2011

세계 각 국에서는 선진국을 중심으로 기후변화와 치솟는 유가에 대응하기 위하여 다양한 에너지원의 확보를 위해 부단히 노력하고 있다. 특히, 신재생에너지원 중 에너지 지속성이 가장 우수한 연료전지의 경우 1kW급 건물용 연료전지시스템이 도시가스 인프라가 가장 우수한 한국 및 일본을 중심으로 상용화에 가장 근접해 있는 실정이다. 일본의 경우 가정용 연료전지시스템 '에너팜'의 일부 제품이 올해부터 200만엔대로 가격을 내려 보급되어질 예정이고, 아직은 경제성이 떨어지지만 연료전지 조기 상용화를 위해 시스템 가격저감을 통한 기술개발이 한창이다. 또한 700W급 고체산화물형 연료전지시스템을 세계에서 처음 시판 계획을 가지고 있다. 국내의 경우 2009년도부터 시작된 '그린홈 보급확대를 위한 건물용 연료전지 보조기기 가격저감 기술개발'연구를 통해 블로워, 밸브, 유량계 및 펌프 등의 보조기기의 단가를 낮추고자 기술개발에 박차를 가하고 있다. 이에 따른 연료전지 부품 가격저감 기술이 국내 건물용 연료전지 시장보급의 활력소가 되기를 기대한다. 본 연구에서는 건물용 연료전지의 보조기기인 블로워의 가격저감을 위한 연구의 일환으로 블로워의 안전성능 평가를 통한 보조기기의 가격저감 및 안전성을 확보하고자 한다. 1kW급 건물용 연료전지시스템의 여러 블로워 중 도시가스용 연료승압 블로워, 선택산화 공기 블로워, 버너 공기 블로워 및 캐소드 공기 블로워의 안전성능 평가를 수행하였고, 평가결과의 공유를 통하여 국내 블로워 제조사의 설계방향을 제시하고 연료전지시스템의 안전성을 확인하고자 한다. 특히, 내구성, 기밀, 가혹조건시험 및 소음, 진동, 습도, 온도와 같은 내주위환경시험 등의 평가결과 비교를 통하여, 연료전지 부품 인증기준을 재정립하여 연료전지 부품산업의 조기 활성화를 도모하고자 한다.

• Korean Journal of Hazardous Materials
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• v.6 no.2
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• pp.77-86
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• 2018

Interest in renewable energy is increasing for eco-friendly use of energy, and fuel cells are being used in various ways such as houses and buildings as power generation methods that have low emissions such as $NO_X$ and $CO_2$. As the supply of fuel cells expands, more and more boilers are installed in the existing buildings, but safety management is not being performed properly. Therefore, in this study, a prior study was conducted on the status of fuel cell-boiler complex installation and related criteria, and the risk factors were analyzed according to the installation environment and structure. Based on these standards, the safety performance of the fuel cell-boiler combined installation is assessed by conducting a demonstration using the starting product of the simulated operation to derive the installation criteria (proposal) for the fuel cell-boiler combined installation. The installation criteria (proposal) include the construction and connection method of the piping according to the fuel cell-boiler complex installation.

• Environmental Engineering Research
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• v.19 no.4
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• pp.363-367
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• 2014

One chambered sediment microbial fuel cell (SMFC) was equipped with Fe, brass (Cu/Zn), Fe/Zn, Cu, Cu/carbon cloth and graphite felt anode. Graphite felt was used as common cathode. The SMFC was membrane-less and mediator-less as well. Order of anodic performance on the basis of power density was Fe/Zn ($6.90Wm^{-2}$) > Fe ($6.03Wm^{-2}$) > Cu/carbon cloth ($2.13Wm^{-2}$) > Cu ($1.13Wm^{-2}$) > brass ($Cu/Zn=0.24Wm^{-2}$) > graphite felt ($0.10Wm^{-2}$). Fe/Zn composite anode have twisted 6.73% more power than Fe alone, Cu/carbon cloth boosted power production by 65%, and brass (Cu/Zn) produced 65% less power than Cu alone. Graphite felt have shown the lowest electricity generation because of its poor galvanic potential. The estuarine sediment served as supplier of oxidants or electron producing microbial flora, which evoked electrons via a complicated direct microbial electron transfer mechanism or making biofilm, respectively. Oxidation reduction was kept to be stationary over time except at the very initial period (mostly for sediment positioning) at anodes. Based on these findings, cost effective and efficient anodic material can be suggested for better SMFC configurations and stimulate towards practical value and application.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.5
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• pp.37-43
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• 2008

The durability test of turbo-blower for PEM fuel cell is very important process of BOP development. It is a major barrier to the commercialization of these systems for stationary and transportation power applications. Commercial viability depends on improving the durability of the air supply system to increase the reliability and to reduce the lifetime cost. In this study, turbo-blower supported by oil-free bearing is introduced as the air supply system used by 80kW proton exchange membrane fuel systems. The turbo-blower is a turbo machine which operates at high speed, so air foil bearings suit their purpose as bearing elements. The impeller of blower was adopted mixed type of centrifugal and axial. So, it has several advantages for variable operating condition. The turbo-blower test results show maximum parasitic power levels below 1.67kW with the 30,000 rpm rotating speed, the flow rate of air has maximum 163SCFM(@PR1.1). For proper application of FCV, these have to durability test. This paper describes the experiment for confirming endurance and stability of the turbo-blower for 500 hours.

• Journal of Energy Engineering
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• v.27 no.4
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• pp.1-12
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• 2018

The code and standards related to fuel cells were analyzed to derive the SOFC(Solid Oxide Fuel Cell) stack safety performance evaluation items and evaluation methode. Safety performance evluation of the SOFC stack was tested by quoting derived test items. The stack used in the test is an anode-supported type 2 Cell stack (Active surface area : 220cm) manufactured by MICO Inc, and SOFC stack safety performance evaluation system used for the test is self-manufactured. We conducted a leakage test, current voltage characteristic test, rated output test, and power response characteristics test. In the safety performance evaluation test, the stack showed no gas leakage, the maximum output and rated output was recorded to 65.6 W(1.41 V, 46.5 A, $422mA/cm^2$), 62.3 W(1.57 V, 40 A, $363mA/cm^2$). In the power response characteristics test verified that the output is kept stable within two seconds. At the maximum load (40 A) and the minimum load (8 A), the output was recorded 62 W and 16W in $750^{\circ}C$. This study will contribute to the universalization and to provide much safe environment of operating the solid oxide fuel cell system.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.3
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• pp.193-200
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• 2010

Anode off-gas of high temperature fuel cell still contains combustible components such as hydrogen, carbon monoxide and hydrocarbon. In this study, a catalytic combustor has been applied to the high temperature fuel cell so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study is designed to perform the experimental investigation on the combustion characteristics of the three commercial catalysts with a different composition. Screening tests with three catalysts are preceded before the performance examination since it is necessary to determine the most suitable catalyst for design configuration of the catalytic combustor. The performance analysis shows that methane conversion rate strongly depends on gas hourly space velocity (GHSV) as well as inlet gas temperature. Additionally, the GSHV optimization results show that the optimum GHSV will be in the range between 18,000 $hr^{-1}$ and 36,000 $hr^{-1}$. It is also shown that the minimum inlet temperature of catalytic reaction of methane is from $100^{\circ}C$ to $150^{\circ}C$.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.82.1-82.1
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• 2011

최근 국내에서 발생된 대규모 정전사태로 인해 안정적인 전력공급에 대한 국민들의 요구가 커져, 지난 3월 일본 후쿠시마 원전사고 이후 다시 한번 분산전원에 대한 필요성이 대두되어지고 있다. 여러 분산전원 중 연료전지는 다른 에너지원에 비해 에너지의 지속성이 우수하여 가장 안정적인 분산전원 형태의 하나이다. 이에 따라 국내의 경우 우수한 도시가스 인프라로 인해 건물용 연료전지라는 신기술에 대한 국민의 수용성은 점점 높아질 것으로 기대된다. 현재 건물용 연료전지의 경우, 주로 1kW급 연료전지가 시범보급되어 각 가정에 설치되어지고 있으나, 상가, 주유소 및 편의점 등의 상업시설과 생활관 및 소형빌라 등의 집단 주거시설 같은 1kW급 보다 용량을 더 필요로 하는 응용처에 국내에서 개발된 5kW급 연료전지시스템이 적용되어지기를 기대한다. 본 연구에서는 국내 제작된 5kW급 고분자전해질 연료전지시스템의 보급이전에 안전성능 평가를 통해 시스템의 성능 및 안전성 평가결과를 제조사에 피드백 하여 5kW급 건물용 연료전지시스템의 조기 상업화에 앞장서고자 한다. 5kW급 연료전지시스템의 기술개발은 핵심부품인 연료변환기, 스택 및 BOP 기술의 경우 1kW급 연료전지시스템에 적용된 것과는 다른 기술이 필요하고, 단순한 scale-up 과정이 아닌 새로운 기술개발로 제품에 적용시켜야 하는 난점을 가지고 있다. 특히, 연료변환기의 경우 연료 유량의 증가로 인하여 reformer, CO shift 및 Prox 반응기의 유체역학, 열교환 흐름 및 촉매반응 공학적으로 이론을 응용한 새로운 반응기 설계와 제작기술 확립이 선행되어 전체적인 시스템 제작 설계에 반영되어져야 한다. 그러므로 본 연구에서는 연료전지시스템 안전성능 평가를 위해 용량증대에 따른 안전성평가 항목을 검토하고, 5kW급 연료전지시스템평가를 수행하여 시스템의 제품성능, 작동성능 및 계통연계성능에서의 안전성을 확인하였고, 정전 유풍과 같은 이상조건 및 실외 환경에 대한 시스템의 안전성도 확인하였다. 또한 부하운전 조건을 75% 및 50%로 변화시켰을 때 빠른 응답시간과 안정적인 부하변동운전을 확인하였다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.3
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• pp.343-350
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• 2012

A planar solid oxide fuel cell (PSOFC) is studied in its application in a high-temperature stationary power plant. Even though PSOFCs with external reformers are designed for application from the distributed power source to the central power plant, such PSOFCs may sacrifice more system efficiency than internally reformed SOFCs. In this study, modeling of the PSOFC with an external reformer was developed to analyze the feasibility of thermal energy utilization for the external reformer. The PSOFC system model includes the stack, reformer, burner, heat exchanger, blower, pump, PID controller, 3-way valve, reactor, mixer, and steam separator. The model was developed under the Matlab/Simulink environment with Thermolib$^{(R)}$ modules. The model was used to study the system performance according to its configuration. Three configurations of the SOFC system were selected for the comparison of the system performance. The system configuration considered the cathode recirculation, thermal sources for the external reformer, heat-up of operating gases, and condensate anode off-gas for the enhancement of the fuel concentration. The simulation results show that the magnitude of the electric efficiency of the PSOFC system for Case 2 is 12.13% higher than that for Case 1 (reference case), and the thermal efficiency of the PSOFC system for Case 3 is 76.12%, which is the highest of all the cases investigated.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2006.05a
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• pp.300-306
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• 2006

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.2
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• pp.113-120
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• 2013

A steam reformer is a chemical reactor to produce high purity hydrogen from fossil fuel. In the steam reformer, since endothermic steam reforming is heated by exothermic combustion of fossil fuel, the heat transfer between two reaction zones dominates conversion of fossil fuel to hydrogen. Steam Reforming is complex chemical reaction, mass and heat transfer due to the exothermic methane/air combustion reaction and the endothermic steam reforming reaction. Typically, a steam reformer employs burner to supply appropriate heat for endothermic steam reforming reaction which reduces system efficiency. In this study, the heat of steam reforming reaction is provided by anode-off gas combustion of stationary fuel cell. This paper presents a optimization of heat transfer effect and average temperature of cross-section using two-dimensional models of a coaxial cylindrical reactor, and analysis three-dimensional models of a coaxial cylindrical steam reformer with chemical reaction. Numerical analysis needs to dominant chemical reaction that are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming(DSR) reaction. The major parameters of analysis are temperature, fuel conversion and heat flux in the coaxial reactor.