• Title/Summary/Keyword: State Of Charge

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Modulation of Microstructure and Energy Storage Performance in (K,Na)NbO3-Bi(Ni,Ta)O3 Ceramics through Zn Doping (Zn 도핑을 통한 (K,Na)NbO3-Bi(Ni,Ta)O3 세라믹의 미세구조 및 에너지 저장 물성 제어)

  • Jueun Kim;Seonhwa Park;Yuho Min
    • Journal of Powder Materials
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    • v.30 no.6
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    • pp.509-515
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    • 2023
  • Lead-free perovskite ceramics, which have excellent energy storage capabilities, are attracting attention owing to their high power density and rapid charge-discharge speed. Given that the energy-storage properties of perovskite ceramic capacitors are significantly improved by doping with various elements, modifying their chemical compositions is a fundamental strategy. This study investigated the effect of Zn doping on the microstructure and energy storage performance of potassium sodium niobate (KNN)-based ceramics. Two types of powders and their corresponding ceramics with compositions of (1-x)(K,Na)NbO3-xBi(Ni2/3Ta1/3)O3 (KNN-BNT) and (1-x)(K,Na)NbO3-xBi(Ni1/3Zn1/3Ta1/3)O3 (KNN-BNZT) were prepared via solid-state reactions. The results indicate that Zn doping retards grain growth, resulting in smaller grain sizes in Zn-doped KNN-BNZT than in KNN-BNT ceramics. Moreover, the Zn-doped KNN-BNZT ceramics exhibited superior energy storage density and efficiency across all x values. Notably, 0.9KNN-0.1BNZT ceramics demonstrate an energy storage density and efficiency of 0.24 J/cm3 and 96%, respectively. These ceramics also exhibited excellent temperature and frequency stability. This study provides valuable insights into the design of KNN-based ceramic capacitors with enhanced energy storage capabilities through doping strategies.

Model of Particle Growth in Silane Plasma Reactor for Semiconductor Fabrication (반도체 제조용 사일렌 플라즈마 반응기에서의 입자 성장 모델)

  • 김동주;김교선
    • Journal of the Korean Vacuum Society
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    • v.10 no.2
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    • pp.275-281
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    • 2001
  • We used the discrete-sectional model to analyze the particle growth by coagulation of particles in silane plasma reactor, considering the Gaussian distribution function for particle charges. The effects of process conditions such as monomer size and mass generation rate of monomers on particle growth in plasma reactor were analyzed theoretically/ Based on the Gaussian distribution function of particle charges, the large particles of more than 40 nm in size are almost found to be charged negatively, but some fractions of small, tiny particles are in neutral state or even charged positively. As the particle size and surface area increase with time by particle coagulation, the number of charges per particle increases with time. As the large particles are generated by particle coagulation, the particle size distribution become bimodal. The results of discrete-sectional model for the particle growth in silane plasma reactor were in close agreement with the experimental results by Shiratani et al. [3] for the same plasma conditions. We believe the model equations for the particle charge distribution and coagulation between particles can be applied to understand the nano-sized particle growth in plasma reactor.

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Track Distiribution of Recoil Protons in PN-3 Dosimeters Etched in NaOH Solution (NaOH 용액에 의해 부식된 PN-3 선량측정계에서의 되튕긴 양성자의 궤적 분포)

  • Yoo, Done-Sik;Sim, Kwang-Souk
    • Progress in Medical Physics
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    • v.2 no.2
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    • pp.129-139
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    • 1991
  • The method of etching tracks in PN-3 dosimeter has been applied to tracks of recoil protons from a neutron source. Both the etch and the detection response of PN-3 has been studied as a function of etched-track diameters against various parameters. We could obtain very useful informations about charge, energy, and mass of particles and the relationship between the track etching rate and the track forming procedure in order to analyze the particle recorded in the solid state track detector. The best etching condition could be found by means of changing the etching circumstances for various energies and particles in order to detect the charged particle accurately. It could be influenced widely that the polymer plastic detector could develep the detecting technique for the low energy level neutron and could be used as a neutron dosimeter in the radiation field such as the nuclear power station, the medical institute and the nondtructive testing institute.

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A study on the Mossbauer effect and optical properties of $^{57}Fe$-doped-GaAs ($^{57}Fe$ 도프된 GaAs의 Mossbauer 효과 및 광학적 특성에 관한 연구)

  • 고정대;홍성락;김득영;강태원
    • Journal of the Korean Vacuum Society
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    • v.6 no.4
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    • pp.337-342
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    • 1997
  • We have investigated Mossbauer effect and emission properties of the Fe-doped GaAs grown by liquid phase epitaxy (LPE). The powder type of isotope $^{57}Fe$ was used as a dopant source in LPE-GaAs. From the analysis of Mossbauer effect the value of isomer shift, 0.303$\pm$0.018 mm/sec, is calculated at low temperature. This means that charge state of Fe ion in GaAs is 3+. The results of double crystal x-ray rocking curve (DCRC) and low temperature photoluminescence (PL) show the crystal quality of the epitaxial layers are good. Unusual luminescence peaks from the Fe-GaAs epitaxial layers appeared at emission energy of 0.99 eV and 1.15 eV. We attribute these emissions to Fe-acceptor related two deep radiative centers.

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Preliminary Research of CZT Based PET System Development in KAERI

  • Jo, Woo Jin;Jeong, Manhee;Kim, Han Soo;Kim, Sang Yeol;Ha, Jang Ho
    • Journal of Radiation Protection and Research
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    • v.41 no.2
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    • pp.81-86
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    • 2016
  • Background: For positron emission tomography (PET) application, cadmium zinc telluride (CZT) has been investigated by several institutes to replace detectors from a conventional system using photomultipliers or Silicon-photomultipliers (SiPMs). The spatial and energy resolution in using CZT can be superior to current scintillator-based state-of-the-art PET detectors. CZT has been under development for several years at the Korea Atomic Energy Research Institute (KAERI) to provide a high performance gamma ray detection, which needs a single crystallinity, a good uniformity, a high stopping power, and a wide band gap. Materials and Methods: Before applying our own grown CZT detectors in the prototype PET system, we investigated preliminary research with a developed discrete type data acquisition (DAQ) system for coincident events at 128 anode pixels and two common cathodes of two CZT detectors from Redlen. Each detector has a $19.4{\times}19.4{\times}6mm^3$ volume size with a 2.2 mm anode pixel pitch. Discrete amplifiers consist of a preamplifier with a gain of $8mV{\cdot}fC^{-1}$ and noise of 55 equivalent noise charge (ENC), a $CR-RC^4$ shaping amplifier with a $5{\mu}s$ peak time, and an analog-to-digital converter (ADC) driver. The DAQ system has 65 mega-sample per second flash ADC, a self and external trigger, and a USB 3.0 interface. Results and Discussion: Characteristics such as the current-to-voltage curve, energy resolution, and electron mobility life-time products for CZT detectors are investigated. In addition, preliminary results of gamma ray imaging using 511 keV of a $^{22}Na$ gamma ray source were obtained. Conclusion: In this study, the DAQ system with a CZT radiation sensor was successfully developed and a PET image was acquired by two sets of the developed DAQ system.

Effect of Mn on Dielectric and Piezoelectric Properties of 71PMN-29PT [71Pb(Mg1/3Nb2/3)O3-29PbTiO3] Single Crystals and Polycrystalline Ceramics

  • Oh, Hyun-Taek;Joo, Hyun-Jae;Kim, Moon-Chan;Lee, Ho-Yong
    • Journal of the Korean Ceramic Society
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    • v.55 no.2
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    • pp.166-173
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    • 2018
  • In order to investigate the effect of Mn on the dielectric and piezoelectric properties of PMN-PT [$Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3$], four different types of 71PMN-29PT samples were prepared using the solid-state single crystal growth (SSCG) method: (1) Undoped single crystals, (2) undoped polycrystalline ceramics, (3) Mn-doped single crystals, and (4) Mn-doped polycrystalline ceramics. In the case of single crystals, the addition of 0.5 mol% Mn to PMN-PT decreased the dielectric constant ($K_3{^T}$), piezoelectric charge constant ($d_{33}$), and dielectric loss (tan ${\delta}$) by about 50%, but increased the coercive electric field ($E_C$) by 50% and the electromechanical quality factor ($Q_m$) by 500%, respectively. The addition of Mn to PMN-PT induced an internal bias electric field ($E_I$) and thus specimens changed from piezoelectrically soft-type to piezoelectrically hard-type. This Mn effect was more significant in single crystals than in ceramics. These results demonstrate that Mn-doped 71PMN-29PT single crystals, because they are piezoelectrically hard and simultaneously have high piezoelectric and electromechanical properties, have great potential for application in fields of SONAR transducers, high intensity focused ultrasound (HIFU), and ultrasonic motors.

Effects of Work-Family Conflict among Public Social Welfare Officers on Turnover Intentions - Focus on the Mediating Effects of Exhaustion and Job Satisfaction - (사회복지전담공무원의 일가정갈등이 이직의도에 미치는 영향 - 소진과 직무만족의 매개효과를 중심으로 -)

  • Jeong, Kyu-Hyoung;Ryu, Ju-Hyun
    • Journal of the Korea Convergence Society
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    • v.11 no.7
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    • pp.337-344
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    • 2020
  • This study examines the effects of work-family conflict among public social welfare officers on turnover intentions and verifies the mediating effects of exhaustion and job satisfaction. For research and analysis, the data of a survey conducted by the Nowon District Research Organization were used to determine the actual state of welfare personnel in charge of the community center's home-visiting service, and an analysis was conducted of 146 public social welfare officers from 19 community centers located in the Nowon District. The analysis results show that work-family conflict affects exhaustion but does not have either a direct or indirect effect on turnover intentions. On the basis of these results, the study proposes policy and practical implications for a work-family compatibility support policy to reduce exhaustion and increase job satisfaction among public social welfare officers.

Study on Production of Power Monitoring Unit for Electric Propulsion UAV (전기동력 무인항공기용 PMU의 개선 및 제작에 대한 연구)

  • Kang, Jin-Myeong;Jeong, Jin-Seok;Kang, Beom-Soo;Kim, Jang-Mok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.45 no.2
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    • pp.140-147
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    • 2017
  • This paper describes the design and implementation of previously developed PMU (Power Monitoring Unit) for LiPB (Lithium-ion Polymer Battery) that is electric propulsion used as unmanned aerial vehicle's power source. Improved PMU provides stable voltage and current to various sensors and elctric motors necessary during flight. Voltage and current monitoring function that is measured by improved PMU more precisely be enhanced and the monitoring channel and temperature sensor is added. To verify the improved performance of the equipment, it is integrated to electric propulsion system of unmanned aerial vehicle. PMU is calibrated through the ground test. And PMU's performance is checked through the flight test.

Enhanced Electrical Properties of Light-emitting Electrochemical Cells Based on PEDOT:PSS incorporated Ruthenium(II) Complex as a Light-emitting layer

  • Gang, Yong-Su;Park, Seong-Hui;Lee, Hye-Hyeon;Jo, Yeong-Ran;Hwang, Jong-Won;Choe, Yeong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.139-139
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    • 2010
  • Ionic Transition Metal Complex based (iTMC) Light-emitting electrochemical cells (LEECs) have been drawn attention for cheap and easy-to-fabricate light-emitting device. LEEC is one of the promising candidate for next generation display and solid-state lighting applications which can cover the defects of current commercial OLEDs like complicated fabrication process and strong work-function dependent sturucture. We have investigated the performance characteristics of LEECs based on poly (3, 4-ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS)-incorporated transition metal complex, which is tris(2, 2'-bipyridyl)ruthenium(II) hexafluorophosphate in this study. There are advantages using conductive polymer-incorporated luminous layer to prevent light disturbance and absorbance while light-emitting process between light-emitting layer and transparent electrode like ITO. The devices were fabricated as sandwiched structure and light-emitting layer was deposited approximately 40nm thickness by spin coating and aluminum electrode was deposited using thermal evaporation process under the vacuum condition (10-3Pa). Current density and light intensity were measured using optical spectrometer, and surface morphology changes of the luminous layer were observed using XRD and AFM varying contents of PEDOT:PSS in the Ruthenium(II) complex solution. To observe enhanced ionic conductivity of PEDOT:PSS and luminous layer, space-charge-limited-currents model was introduced and it showed that the performances and stability of LEECs were improved. Main discussions are the followings. First, relationship between film thickness and performance characteristics of device was considered. Secondly, light-emitting behavior when PEDOT:PSS layer on the ITO, as a buffer, was introduced to iTMC LEECs. Finally, electrical properties including carrier mobility, current density-voltage, light intensity-voltage, response time and turn-on voltages were investigated.

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Developing a Multi-Functional Smart Down Jacket Utilizing Solar Light and Evaluating the Thermal Properties of the Prototype (태양광을 활용한 스마트 다운재킷 개발 및 보온성능 평가)

  • Yi, Kyonghwa;Kim, Keumwha
    • Journal of Fashion Business
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    • v.19 no.4
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    • pp.92-108
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    • 2015
  • This study aimed at developing a down jacket prototype that utilized sunlight as an alternative energy source with no air pollution. The jacket is filled with flexible solar panels and has a heat-generating function and LED function. In this study, three smart down jacket prototypes were developed, and the jacket's capabilities were demonstrated through the thermal effect on the performance test. The typical output voltage of the flexible solar panels was 6.4V. By connecting the 2 solar cell modules in series, the final output voltage was 12.8V. A battery charge regulator module was used the KA 7809 (TO-220) of 9V. Three heating pads were to be inserted into the belly of the jacket as direct thermal heating elements, and the LED module was configured, separated by a flash and an indicator. The smart down jacket was designed to prevent damage to the down pack without the individual devices' interfering with the human body's motion. Because this study provides insulation from extreme cold with a purpose, the jacket was tested for heat insulation properties of non-heating, heating on the back, heating on the abdomen, and heating on both the back and abdomen in a sitting posture in a static state. Thermal property analysis results from examining the average skin temperature, core temperature, and the temperature and humidity within clothing showed, that placing a heating element in one place was more effective than distributing the heating elements in different locations. Heating on the back was the most effective for maintaining optimal skin temperature, core temperature, and humidity, whereas heating on the abdomen was not effective for maintaining optimal skin temperature, core temperature, or humidity within clothing because of the gap between the jacket and the body.