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Characterization and Photocatalytic effect of ZnO nanoparticles synthesized by spray-pyrolysis method

  • Lee, Sang-Duck;Nam, Sang-Hun;Kim, Myoung-Hwa;Lee, Kang-Suk;Kim, Young-Dok;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.101-101
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    • 2010
  • ZnO shows a direct band gap of 3.37eV, large exciton binding energy (~60 meV), high oxidation ability, high sensitivity to many gases, and low cost, and it has been used in various applications such as transparent electrodes, light emitting diodes (LEDs), gas sensors and photocatalysts. Among these applications ZnO as photocatalyst has considerably attracted attention over the past few years because of its high activities in removing organic contaminants generated from industrial activities. In this research, ZnO nanoparticles were synthesized by spray-pyrolysis method using the zinc acetate dihydrate as starting material at synthesis temperature of $900^{\circ}C$ with concentration varied from 0.01 to 1.0M. The physical and chemical properties of the synthesized ZnO nanoparticles were examined by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier Transformation Infrared (FT-IR), and UV-vis spectroscopy. The Miller indices of XRD patterns indicate that the synthesized ZnO nanoparticles showed a hexagonal wurtzite structure. With increased precursor concentration, a primary, secondary particle sizes of ZnO nanoparticles increased by 0.8 to $1.5{\mu}m$ and 15 to 35nm, and their crystallinity was improved. Methyleneblue (MB) solution ($1{\mu}M$) as a test comtaminant was prepared for evaluating the photocatalytic activities of ZnO nanoparticles synthesized in different precursor concentration. The results show that the photocatalytic efficiency of ZnO nanoparticles was gradually enhanced by increased precursor concentration.

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Reaction Path Modelling on Geochemical Evolution of Groundwater and Formation of Secondary Minerals in Water-Gneiss Reaction System (편마암-물 반응계에서 지하수의 지화학적 진화 및 이차광물 생성에 관한 반응경로 모델링)

  • 정찬호;김천수;김통권;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.10 no.1
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    • pp.33-44
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    • 1997
  • The reaction path of water-gneiss in 200m borehole at the Soorichi site of Yugu Myeon, Chungnam was simulated by the EQ3NR/EQ6 program. Mineral composition of borehole core and fracture-filling minerals, and chemical composition of groundwater was published by authors. In this study, chemical evolution of groundwater and formation of secondary minerals in water-gneiss system was modelled on the basis of published results. The surface water was used as a starting solution for reaction. Input parameters for modelling such as mineral assemblage and their volume percent, chemical composition of mineral phases, water/rock ratio reactive surface area, dissolution rates of mineral phases were determined by experimental measurement and model fit. EQ6 modelling of the reaction path in water-gneiss system has been carried out by a flow-centered flow through open system which can be considered as a suitable option for fracture flow of groundwater. The modelling results show that reaction time of 133 years is required to reach equilibrium state in water-gneiss system, and evolution of present groundwater will continue to pH 9.45 and higher na ion concentration. The secondary minerals formed from equeous phase are kaolinite, smectite, saponite, muscovite, mesolite, celadonite, microcline and calcite with uincreasing time. Modeling results are comparatively well fitted to pH and chemical composition of borehole groudwater, secondary minerals identified and tritium age of groundwater. The EQ6 modelling results are dependent on reliability of input parameters: water-rock ratio, effective reaction surface area and dissolution rates of mineral phases, which are difficult parameters to be measured.

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Studies on Preparation of $^{99m}Tc$ Labelled 3-Iodo-2,4,6-trimethyl-iminodiacetic acid $(^{99m}Tc-IOTIDA)$ for Diagnosis of Hepatobiliary Disease (간.담도계 질환 진단용 $^{99m}Tc$ 표지 3-요오도-2,4,6-트리메틸 이미노 2초산$(^{99m}Tc-IOTIDA)$의 제조에 관한 연구)

  • Park, Kyung-Bae;Awh, Ok-Doo;Kim, Jae-Rok
    • The Korean Journal of Nuclear Medicine
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    • v.24 no.1
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    • pp.49-55
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    • 1990
  • For the development of $^{99m}Tc-labelled$ 3-iodo-2,4,6-trimethyl-iminodiacetic acid $(^{99m}Tc-IOTIDA)$, various experiments such as synthesis of IOTIDA, establishment of labelling conditions, determination of radiochemical purity, examination of stability, and organ distribution of rat were carried out. 1) IOTIDA was synthesized with a total yield of 42% from the starting material of 2,4-6-trimethylaniline via chloroacetylation, iodination, and condensation with iminodiacetic acid (IDA). 2) Freeze-dried instant labelling kits were prepared from aqueous solution $(pH\;5.8\sim6.0)$ so as to contain 40 mg IDA compound and 0.4 mg $SnCl_2$, per vial. Labelling of the contents of kit vials with $Na^{99m}TcO_4$, exhibited formation of two kinds of complex which was identified by ITLC-SA. After labelling, complex ( I ) was gradually converted to complex (II) with time. Labelling yield and radiochemical purity were above 99.5% based on the two complexes over-all. 3) $^{99m}Tc-IOTIDA$ maintained high radiochemical purity of above 99% until 6 hours after preparation at room temperature. Instant labelling kits stored at $4^{\circ}C$ for 6 month period also exhibited high labelling yield of above 99%. 4) Results obtained from animal experiments showed that most of the $^{99m}Tc-IOTIDA$ was rapidly excreted through hepatobiliary track into the intestines but with negligible renal excretion.

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Secure Multiparty Computation of Principal Component Analysis (주성분 분석의 안전한 다자간 계산)

  • Kim, Sang-Pil;Lee, Sanghun;Gil, Myeong-Seon;Moon, Yang-Sae;Won, Hee-Sun
    • Journal of KIISE
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    • v.42 no.7
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    • pp.919-928
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    • 2015
  • In recent years, many research efforts have been made on privacy-preserving data mining (PPDM) in data of large volume. In this paper, we propose a PPDM solution based on principal component analysis (PCA), which can be widely used in computing correlation among sensitive data sets. The general method of computing PCA is to collect all the data spread in multiple nodes into a single node before starting the PCA computation; however, this approach discloses sensitive data of individual nodes, involves a large amount of computation, and incurs large communication overheads. To solve the problem, in this paper, we present an efficient method that securely computes PCA without the need to collect all the data. The proposed method shares only limited information among individual nodes, but obtains the same result as that of the original PCA. In addition, we present a dimensionality reduction technique for the proposed method and use it to improve the performance of secure similar document detection. Finally, through various experiments, we show that the proposed method effectively and efficiently works in a large amount of multi-dimensional data.

A Study on Overseas Business Archives Professional Organization (해외 기업 아카이브 전문가조직에 관한 연구)

  • Kim, hyosun;Kim, Jihyun
    • Journal of Korean Society of Archives and Records Management
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    • v.19 no.4
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    • pp.139-173
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    • 2019
  • At present, no outside organization provides systematic support for business archives, even though there are companies that operate their own. To resolve this situation, this study suggested that overseas business archives professionals organization could apply in Korea by analyzing the form of organizations and functional roles. As such, the organization of professionals in overseas business archives was analyzed through their website, literature research, and email interviews of the staff. Based on the analysis, overseas organizations of business archives professionals were established in the form of sections and independent organizations to systematically support business archives through long-term projects. Thus, this study proposed an organizational structure of professionals organizations for the development of domestic business archives and the functional role of supporting activities, educational activities, and publishing activities. In addition, the ultimate development of business archives is clearly no longer the only solution to the change in perception and strategy of individual companies' business records. Moreover, this study is significant as a starting point for discussion on the establishment of business archives professionals or organizations.

Screening, Cloning, Expression and Characterization of New Alkaline Trehalose Synthase from Pseudomonas monteilii and Its Application for Trehalose Production

  • Trakarnpaiboon, Srisakul;Bunterngsook, Benjarat;Wansuksriand, Rungtiva;Champreda, Verawat
    • Journal of Microbiology and Biotechnology
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    • v.31 no.10
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    • pp.1455-1464
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    • 2021
  • Trehalose is a non-reducing disaccharide in increasing demand for applications in food, nutraceutical, and pharmaceutical industries. Single-step trehalose production by trehalose synthase (TreS) using maltose as a starting material is a promising alternative process for industrial application due to its simplicity and cost advantage. Pseudomonas monteilii TBRC 1196 was identified using the developed screening method as a potent strain for TreS production. The TreS gene from P. monteilii TBRC 1196 was first cloned and expressed in Escherichia coli. Purified recombinant trehalose synthase (PmTreS) had a molecular weight of 76 kDa and showed optimal pH and temperature at 9.0 and 40℃, respectively. The enzyme exhibited >90% residual activity under mesophilic condition under a broad pH range of 7-10 for 6 h. Maximum trehalose yield by PmTreS was 68.1% with low yield of glucose (4%) as a byproduct under optimal conditions, equivalent to productivity of 4.5 g/l/h using enzyme loading of 2 mg/g substrate and high concentration maltose solution (100 g/l) in a lab-scale bioreactor. The enzyme represents a potent biocatalyst for energy-saving trehalose production with potential for inhibiting microbial contamination by alkaline condition.

Problems inherited from Habermas/Luhmann-debate: The relation between communication and action and the problem of attribution (하버마스와 루만의 논쟁이 남긴 문제: 소통과 행위의 관계 및 귀속)

  • Jung, Sunghoon
    • Journal of Korean Philosophical Society
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    • no.120
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    • pp.89-119
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    • 2018
  • Among the controversial issues of Habermas/Luhmann-debate, the more important issue today is the achievement of the two scholars after the debate rather than confirming the old antagonistic framework of critical theory versus systems theory. 'Communicative action' and 'discourse' are such issues. Starting from these issues, Habermas established a theory of communicative action, and Luhmann regarded elements of social systems as communications and considered actions as elements of system's self-observation. In particular, Luhmann's work, which regards communication as a primary concept and action as a result of attribution to the actor, was a very productive conversion of sociological tradition. Nevertheless, this conversion lacks a solution of intensified attribution conflicts. I think it is necessary to pay attention to the '$Verst{\ddot{a}}ndigung$' in Habermas' concept of communicative action in order to solve the problem of infinitely repeated attribution conflicts.

Synthesis of Zeolite A from Coal Fly Ash (석탄회로부터 제올라이트 A의 합성)

  • Jee, Jeong-Dae;Choi, Ko-Yeol
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.214-218
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    • 2011
  • Zeolite A was synthesized from coal fly ash by the microwave heating as well as the conventional heating method. The effects of reaction time, the amount of sodium aluminate, and the reaction temperature on the crystallization of zeolite A were investigated. The optimum crystallization time was about 3 to 6 h in the temperature range of $80{\sim}100^{\circ}C$. The amount of sodium aluminate was found to be optimum when the molar ratio $SiO_2/Al_2O_3$ of starting solution was in the range of 0.44 to 1.05 at above $90^{\circ}C$, However, The more amount of sodium aluminate was required to get zeolite A at $80^{\circ}C$. Although the rate of crystallization was slightly faster in the microwave heating than that in the conventional heating, the reaction time need to obtain fully crystallized zeolite A was similar in both methods. Therefore, the influence of the microwave heating was not so large compared with the conventional heating in the synthesis of zeolite A from coal fly ash.

AprilTag and Stereo Visual Inertial Odometry (A-SVIO) based Mobile Assets Localization at Indoor Construction Sites

  • Khalid, Rabia;Khan, Muhammad;Anjum, Sharjeel;Park, Junsung;Lee, Doyeop;Park, Chansik
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.344-352
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    • 2022
  • Accurate indoor localization of construction workers and mobile assets is essential in safety management. Existing positioning methods based on GPS, wireless, vision, or sensor based RTLS are erroneous or expensive in large-scale indoor environments. Tightly coupled sensor fusion mitigates these limitations. This research paper proposes a state-of-the-art positioning methodology, addressing the existing limitations, by integrating Stereo Visual Inertial Odometry (SVIO) with fiducial landmarks called AprilTags. SVIO determines the relative position of the moving assets or workers from the initial starting point. This relative position is transformed to an absolute position when AprilTag placed at various entry points is decoded. The proposed solution is tested on the NVIDIA ISAAC SIM virtual environment, where the trajectory of the indoor moving forklift is estimated. The results show accurate localization of the moving asset within any indoor or underground environment. The system can be utilized in various use cases to increase productivity and improve safety at construction sites, contributing towards 1) indoor monitoring of man machinery coactivity for collision avoidance and 2) precise real-time knowledge of who is doing what and where.

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Deriving Mobile Robot Delivery Service Security Requirements Using STRIDE Threat Modeling (STRIDE 위협모델링을 활용한 이동로봇 배송 서비스 보안 요구사항 도출)

  • Ji-Yong Choi;Jae-Dong Jang;Sang-Joon Lee
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.34 no.5
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    • pp.927-947
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    • 2024
  • Due to the global low birth rate and aging population, there is a growing interest in utilizing robot technology as a solution to address labor shortages. Specifically, mobile robots, which are growing rapidly, have become intelligent enough to recognize their environment and avoid obstacles to carry out tasks. However, the integration of IT technology into these robots has led to an increase in potential security vulnerabilities, and security research has been conducted to prepare countermeasures. However, research to examine the security threats of mobile robots in general is insufficient. To enhance the overall security of robot systems, it is imperative to systematically identify security threats starting from the design phase. In this paper, we identify security threats within the mobile robot delivery service environment using a structured approach that involves Data Flow Diagram and STRIDE threat modeling. Additionally, we visualize vulnerabilities and attack techniques through Attack Tree based on the Attack Library, and a Check List has finally been created to derive security requirements. We have been conducted this study with the hope that the results derived from this study will be utilized in establishing guidelines and policies related to robot security and contribute to the establishment of a safe robot foundation.