• Title/Summary/Keyword: Standard solution

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The Removal of Heavy Metals in Aqueous Solution by Hydroxyapatite (Apatite를 이용한 중금속 제거)

  • 강전택;정기호
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.325-330
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    • 2000
  • The hydroxyapatite (HAp) for the present study was prepared by precipitation method in semiconductor fabrication and the crystallized at ambient to 95$0^{\circ}C$ for 30min in electric furnace. The ion-exchange characteristics of HAp for various heavy metal ions such as $Cd^{2+}, Cu^{2+}, Mn^{2+}, Zn^{2+}, Fe^{2+}, Pb^{2+}, Al^{3+}, and Cr^{6+}$ in aqueous solution has been investigated. The removal ratio of various metal ions for HAp were investigated with regard to reaction time, concentration of standard solution, amount of HAp and pH of solution. The order of the ions exchanged amount was as follws: $Pb^{2+}, Fe^{3+}>Cu^{2+}>Zn^{2+}>Al^{3+}>Cd^{2+}>Mn^{2+}>Cr^{6+}. The Pb^{2+}$ ion was readily removed by the Hap, even in the strongly acidic region. The maximum amount of the ion-exchange equilibrium for $Pb^{2+}$ ion was about 45 mg/gram of HAp. The HAp would seem to be possible agent for the removal of heavy metal ions in waste water by recycling of waste sludge in semiconductor fabrication.

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Improving Method of Pre-treatment for Detection Benzo($a$)pyrene Contents in Concentrates (농축물의 Benzo($a$)pyrene 함량 측정을 위한 전처리 방법의 개선)

  • Koo, Bon-Soon
    • The Korean Journal of Food And Nutrition
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    • v.24 no.4
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    • pp.797-802
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    • 2011
  • I assessed the B($a$)P content from the Ginseng extract, Red ginseng extract, and Ssangwha extract which have high viscosities. It wasn't easy to extract oil from these samples, consequently measuring of B($a$)P was difficult. In order to know the exact detecting contents, I injected standard material of B($a$)P to the above extractions and pre-treated for measurement but it was also difficult to measure of contents exactly. To improve of detecting method, I removed mucinous materials using a 85% phosphoric acid solution or 10% citric acid solution and then processed continuously with $60^{\circ}C$ hot water. The analysis revealed that extracting the samples contained B($a$)P determined the rate of each 70%, 55%, 67% could increase. As a result the detecting method of B($a$)P contents could be improved.

REMARKS ON FINITE ELEMENT METHODS FOR CORNER SINGULARITIES USING SIF

  • Kim, Seokchan;Kong, Soo Ryun
    • Honam Mathematical Journal
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    • v.38 no.3
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    • pp.661-674
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    • 2016
  • In [15] they introduced a new finite element method for accurate numerical solutions of Poisson equations with corner singularities, which is useful for the problem with known stress intensity factor. They consider the Poisson equations with homogeneous Dirichlet boundary condition, compute the finite element solution using standard FEM and use the extraction formula to compute the stress intensity factor, then they pose a PDE with a regular solution by imposing the nonhomogeneous boundary condition using the computed stress intensity factor, which converges with optimal speed. From the solution we could get accurate solution just by adding the singular part. This approach works for the case when we have the accurate stress intensity factor. In this paper we consider Poisson equations with mixed boundary conditions and show the method depends the accrucy of the stress intensity factor by considering two algorithms.

Immobilization of Microorganisms - Part 1. Preparation of Immobilized Lactobacillus bulgaricus - (미생물(微生物) 고정화(圖定化)에 관한 연구(硏究) - 제1보(第1報). Lactobacillus 균(菌)의 고정화조건(圖定化條件) -)

  • Lee, Kang-Heup
    • Applied Biological Chemistry
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    • v.24 no.2
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    • pp.149-152
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    • 1981
  • The immobilization of Lactobacillus bulgaricus was investigated by various method, e.g. by use of polyacrylamide gel and Al-, Ca-, Fe- or Mg-alginate beads, and the most active immobilized cells were obtained by entrapment in a Ca-alginate beads. These immobilized microbial cells, when introduced into 4.5% lactose solution and whey solution showed maximum relative activity of 28% or lactose solution and 18% for whey solution as measured against the native microbial reference standard (100).

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TSSG-pulling of Sillenite $Bi_{12}TiO_{20}$ for EOS Application

  • Miyazawa, Shintaro
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1999.06a
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    • pp.227-250
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    • 1999
  • The reproducibility of successive growth of Bi12TiO20(BTO) single crystals using a top-seeded solution growth (TSSG) pulling method was evaluated by measuring the lattice constants and their standard deviations. A substantial phase diagram in the region close to the stoichiometric BTO was established experimentally for this purpose, and the existence of a retrograde solid solution close to a BTO was clarified. It was emphasize that a starting solution, with a 10.0~10.1 mol% TiO2 concentration, results in large single crystals with a highly homogeneous lattice constant of within $\pm$1x10-4$\AA$, when the solidified fraction of the grown crystal is less than about 45%. A wavelength dispersion of refractive index was measured for the first time, an it was verified that the refractive index of BTO is larger than that of BSO(Bi12TiO20), allowing the voltage sensitivity of EOS higher than the case with BSO as a probe head.

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Implementation of Khronos OpenVG 1.0 Standard for Vector Graphics (Khronos OpenVG 1.0 벡터 그래픽 표준 API 구현)

  • Lee, Hwan-Yong;Lee, Jun-Young;Oh, Ae-Kyung;Sung, Hyun-Chan;Park, Ki-Hyun
    • Journal of the Korea Computer Graphics Society
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    • v.12 no.3
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    • pp.7-11
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    • 2006
  • 최근 임베디드 환경에서 2차인 Vector Graphics에 대한 요구는 크게 증가하고 있으며, Flash Lite, SVG등의 응용이 이미 널리 사용되고 있다. 반면 이러한 응용을 지원하기 위한 API의 표준은 전무한 실정이었다. OpenVG 1.0은 임베디드 시스템을 위한 미디어 표준 제정 기관인 Khronos Group에서 제정한 2차원 벡터 그래픽스를 위한 API (Application Programming Interface)로 2005년 8월 발표되었다. 본 논문에서는 OpenVG 표준에 대해 간략히 소개하고 (주)휴원에서 세계최초로 상용화 개발에 성공한 AlexVG Engine의 개발과정과 결과에 대하여 설명한다.

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The Adsorption of Phosphate Son Using Hydroxyapatite synthesized by Wastewater Sludge of Semiconductor Fabrication Process (반도체 제조공정의 폐수슬러지로 합성된 Hydroxyapatite를 이용한 인산이온의 흡착)

  • 강전택;정기호;신학기
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.257-262
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    • 2002
  • The hydroxyapatite(HAp) for the present study was prepared with the wastewater sludge from semiconductor fabrication process and it was crystallized in an electric furnace for 30 min at 90$0^{\circ}C$. The adsorption characteristics of HAp for phosphate ion in aqueous solution has been investigated. The adsorbed ratio of phosphate ion for HAp were investigated according to the reaction time, amount of HAp, concentration of standard solution, pH of solution, and influence of concomitant ions. The amount of adsorbed phosphate ion decreased with the increase of pH due to the mutual electrostatic repulsion between adsorbed phosphate ions and competitive adsorption between phosphate ion and OH- ion in aqueous solution. The maxium amount of the adsorption equilibrium for phosphate ion was about 24 mg/g of HAp. The HAp would likely to be a possible adsorbent for the removal of phosphate ion in the waste water.

FINITE ELEMENT SOLUTIONS OF PARTIAL DIFFERENTIAL EQUATION WITH MULTIPLE CONCAVE CORNERS

  • Kim, Seokchan;Woo, Gyungsoo
    • Honam Mathematical Journal
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    • v.40 no.4
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    • pp.785-794
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    • 2018
  • In [8] they introduced a new finite element method for accurate numerical solutions of Poisson equations with corner singularities. They consider the Poisson equations with homogeneous Dirichlet boundary condition with one corner singularity at the origin, and compute the finite element solution using standard FEM and use the extraction formula to compute the stress intensity factor, then pose a PDE with a regular solution by imposing the nonhomogeneous boundary condition using the computed stress intensity factor, which converges with optimal speed. From the solution they could get an accurate solution just by adding the singular part. This approach uses the polar coordinate and the cut-off function to control the singularity and the boundary condition. In this paper we consider Poisson equations with multiple singular points, which involves different cut-off functions which might overlaps together and shows the way of cording in FreeFEM++ to control the singular functions and cut-off functions with numerical experiments.

Experiments on a Regenerator with Thermosyphon for Absorption Heat Pumps (기포 펌프를 적용한 흡수식 열펌프용 고온 재생기의 작동 특성 실험)

  • Park, C.W.;Jurng, J.;Nam, P.W.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.463-472
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    • 1996
  • Experiments were carried out to study the operation characteristics of a regenerator with a thermo-syphon pump and a surface-flame burner for a lithium bromide (LiBr)-water absorption heat pump. A cylindrical-shape metal-fiber burner and commercial grade propane were used. The emission of carbon monoxide and nitric oxide was measured by a combustion gas analyzer. Ther regeneration rate of water vapor as a refrigerant was measured. It could be as a reference value showing the performance of the regenerator. The circulation rate of the LiBr-water solution was also measured from both the tanks for the weak-and the strong-solution. Using a refractometer, the LiBr concetration in the solution was calculated from the measured refractory index of the solution. Temperature of the solution and the condensed water was recorded at several points in the experimental apparatus with thermocouples, using a personal computer. This data collecting system for measuring temperature was calibrated with a set of standard thermometers. The generating rate of water vapor as refrigerant increased linearly with heat supplied. It was about 4.0g/s with the heat supplied at a rate of 16,500kcal/h. The circulation rate of LiBr solution also increases with the heat supplied. The difference in LiBr concentrations between the weak and the strong solution was in the range of 1 to 5% when the concentration of the strong solution was about 60%. It was dependent upon both the heat supplied and the circulation rate of the solution. The initial concentration and the level of the LiBr solution in the regenerator were measured and recorded before experiments. The effect of them on the generating rate of water vapor and the circulation rate of the solution was also studied. The generating rate of water vapor was not strongly dependent upon both the level of the LiBr solution and the initial LiBr concentration. However, the concentration difference of the solution increases with the initial level of the LiBr solution.

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Improvement of accuracy in quantitative TXRF analysis of soil sample by applying external standard method (외부표준법을 적용한 토양시료의TXRF 정량분석 정확도 개선)

  • Park, Jinkyu;Park, Ranhee;Han, Sun Ho;Lim, Sang Ho;Lee, Chi Gyu;Song, Kyuseok
    • Analytical Science and Technology
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    • v.29 no.6
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    • pp.261-268
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    • 2016
  • TXRF is a powerful technique for the soil sample analysis due to its ability to conduct quantitative analysis of powder sample without complicated pre-treatment processes. The conventional internal standard method used for this technique suffers from relatively low accuracy because of varying matrix effects of soil. In order to improve the accuracy, external standard method was applied to analyze two types of soil samples; acid-dissolutionized soil solution and detergent-suspended soil powder. Individual ICP-AES/MS grade standards were mixed, diluted and measured to create standard curves, but applying these curves for analyzing the soil solution sample did not make any improvement in comparison with the internal standard method. On the other hand, standard curves were created with using standard soil powders for the analysis of soil powder samples, and we found that this method increased the accuracy significantly relative to the internal standard method. Especially, Al, Fe, K, Ca, Ti, Ba, Mn, Sr, Rb, Cu was measured with relatively high accuracy (relative error = ${\pm}20%$).