• Title/Summary/Keyword: Stainless Steels

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Effects of Nitrogen Ion Implantation on the Surface Properties of 316L Stainless Steel as Bipolar Plate for PEMFC (고분자전해질 연료전지 분리판용 316L 스테인리스강의 표면특성에 미치는 질소 이온주입 효과)

  • Kim, Min Uk;Kim, Do-Hyang;Han, Seung Hee;Kim, Yu-Chan
    • Korean Journal of Metals and Materials
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    • v.47 no.11
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    • pp.722-727
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    • 2009
  • The bipolar plates are not only the major part of the polymer electrolyte membrane fuel cell (PEMFC) stack in weight and volume, but also a significant contributor to the stack costs. Stainless steels are considered to be good candidates for bipolar plate materials of the PEMFC due to their low cost, high strength and easy machining, as well as corrosion resistance. In this paper, 316L stainless steel with and without nitrogen ion implantation were tested in simulated PEMFC environments for application as bipolar plates. The results showed that the nitride formed by nitrogen ion implantation contributed the decrease of the interfacial contact resistance without degradation of corrosion property. The combination of excellent properties indicated that nitrogen ion implanted stainless steel could be potential candidate materials as bipolar plates in PEMFC. Current efforts have focused on optimizing the condition of ion implantation.

Relationship Between Properties Degradation and Critical Aging Time of Super Austenitic and Duplex Stainless Steels

  • S. H. Choi;Y. R. Yoo;S. Y. Won;G. B. Kim;Y. S. Kim
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.330-340
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    • 2023
  • The objective of this study was to analyze effects of aging time on property degradation of super austenitic stainless steel of PRE 52.8 and super duplex stainless steel of PRE 48.7. To analyze corrosion properties based on aging time, a critical pitting temperature test was performed in a solution of 6% FeCl3 + 1% HCl and an anodic polarization test was performed in deaerated 0.5N HCl + 1N NaCl solution at a temperature of 50 ℃. Surface hardness was measured to analyze mechanical properties. It was found that corrosion properties and mechanical properties deteriorated rapidly as aging time increased. Critical pitting temperature had the most effect on critical aging time at which property changes occurred rapidly, followed by pitting potential and hardness. This trend was found to be closely related to the fraction of sigma phase. Rate of sigma phase formation was found to be significantly faster in duplex stainless steel than in austenitic stainless steel.

Effects of Casting Variables and Alloying Elements on the Fluidity of Thin Wall Stainless Steel Castings (박육 스테인리스 주강의 유동성에 미치는 주조변수 및 합금원소의 영향)

  • Choi, Hak-Kyu;Kang, Sang-Kyu;Park, Heung-Il;Jeong, Hae-Yong;Bae, Cha-Hurn
    • Journal of Korea Foundry Society
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    • v.20 no.5
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    • pp.336-343
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    • 2000
  • The effects of casting variables and alloying elements on the fluidity of thin wall cast stainless steels were investigated. Melts were poured into the sand molds to produce thin wall test castings. The length of it was 245 mm and the thickness varied at the interval of 0.5 in the range of 1.6 to 2.6 mm. For the same casting condition, the fluidities of austenitic stainless steel, ferritic, precipitation hardenable and martensite ones were better in the order. The higher the pouring temperature, the shorter the pouring rate and the better the fluidity were. The fluidity was increased with the addition of Cr and decreased with W and Nb.

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Clad Steel for Application of Hull Structure (클래드강 적용을 위한 선급용 강재의 열처리 특성 평가)

  • Shin, Yong-Taek
    • Journal of Welding and Joining
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    • v.33 no.5
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    • pp.20-25
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    • 2015
  • Clad steel has good corrosion resistance and mechanical properties arising from the hot rolling of dissimilar metals, such as carbon steel and stainless steel. However both good corrosion resistance from the cladding plate material(stainless steel) and mechanical properties from the base plate material (carbon steel) are difficult to obtain because the different steels display opposite behaviors during the cladding process. In order to make clad steel for application in the hulls of ships, proper materials selection and heat-treatment conditions are necessary. In this study, mechanical properties of base plate materials with different chemical composition were evaluated according to heat condition of cladding plate material.

Finite Element Damage Analysis Method for J-Resistance Curve Prediction of Cold-Worked Stainless Steels (조사취화를 모사한 스테인레스강의 파괴저항선도를 예측하기위한 유한요소 손상해석기법)

  • Seo, Jun Min;Kim, Ji Soo;Kim, Yun Jae
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.14 no.1
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    • pp.1-7
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    • 2018
  • Materials in nuclear power plants can be embrittled by neutron irradiation. According to existing studies, the effect of the material property by irradiation embrittlement can be approximately simulated by cold working (pre-strain). In this study, finite element damage analysis method using the stress-modified fracture strain model is proposed to predict J-Resistance curves of irradiated SUS316 stainless steel. Experimental data of pre-strained SUS316 stainless steel material are obtained from literature and the damage model is determined by simulating the tensile and fracture toughness tests. In order to consider damage caused by the pre-strain, a pre-strain constant is newly introduced. Experimental J-Resistance curves for various degrees of pre-strain are well predicted.

Wear Corrosion Behaviour of Nitrogen Ion Implanted Super Stainless Steel (질소이온주입된 초내식성 스테인리스강의 마모부식 특성)

  • Kang, Sun-Hwa;Kim, Cheol-Sang
    • Proceedings of the KOSOMBE Conference
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    • v.1994 no.12
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    • pp.175-177
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    • 1994
  • The wear corrosion behaviour of a nitrogen ion implanted super stainless steel (S.S.S, 22Cr - 20Ni - 6Mo - 0.25N) was compared with those of S.S.S, 316L SS and TiN coated 316L SS. The Cr and Ni amounts won out from the materials were investigated using an electrothermal atomic absorption spectrometry. We observed that the Cr dissolution rate of the S.S.S was similar to that of 316L SS, however, the Ni release of the S.S.S was feater than 316L SS. The metal ions released from the nitrogen ion implanted S.S.S surface were significantly reduced. The wear corrosion behaviour of the stainless steels was not correlated with the results shown by a static metal ion release test.

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Low Temperature Impact Toughness and Stress Corrosion Resistance in Duplex Stainless Steel Welds (2상 스테인리스강 용접부의 저온충격인성과 내응력 부식성에 관한 연구)

  • 김효종;이성근
    • Journal of Ocean Engineering and Technology
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    • v.9 no.1
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    • pp.151-160
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    • 1995
  • The characteristics of low temperature impact toughness and stress corrosion resistance at boiling MgCl$_2$ solution of GTA and SMA weld of duplex stainless steels have been investigated. The impact toughness was highest at the GTAW weld metal and lowest at the SMAW weld, which was almost the same as that of the SMAW heat-affected zone. This was attributable to influence of austenite-ferrite phase balance, and the degree and nature of precipitation that occurred during welding. The SCC resistance of the weldments was slightly higher than that of the base metal, whereas no difference in the SCC resistance was found between two different weldments.

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Development & Application of New Multi-Purpose Rolling Oil (일반강, SiliconSteel, StainlessSteel겸용 수용성 냉간압연유의 개발 및 적용)

  • SONG K. B.;KWOUN G. J.;KIM M. K.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.08a
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    • pp.261-267
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    • 2004
  • Current steel makers are trying to develop new manufacturing process to secure price competition and to improve productivity by testing a various kinds of rolling condition of several kinds of steel at TCM. Accordingly, Reverse Mill operation for Stainless steel is changing to TCM operation and furthermore, even general carbon steel and electric steel plate are requested to be worked at TCM simultaneously. By these changing of rolling condition, it become to be necessary to develop new water-soluble cold rolling oil that has a characteristics to be suitable for various working condition and in this report, we would like to mention lubrication condition to fulfill requested characteristics of each steels and development and applying result of multi-purpose water-soluble cold rolling oil which has such an lubrication property.

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The effect of boron on the corrosion resistance of 304 stainless steels (304 스테인리스강의 내식성에 미치는 붕소의 영향)

  • 안병국;원태연;이윤용;윤정모;최병길;황선효
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.89-95
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    • 1995
  • Effect of boron on corrosion resistance of Type 304 stainless steel has been studied. Boron tends to segregate at the grain boundaries during cooling after solution treatment, and so boron treated steel usually exhibits a ditch structure under the 10% oxalic acid test. However, it was found that the addition of 25 ppm boron in Type 304 steel has no effect on the general and pitting corrosion resistance while it has a little effect on the intergranular corrosion resistance.

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FABRICATION OF GD CONTAINING DUPLEX STAINLESS STEEL SHEET FOR NEUTRON ABSORBING STRUCTURAL MATERIALS

  • Choi, Yong;Moon, Byung M.;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.45 no.5
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    • pp.689-694
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    • 2013
  • A duplex stainless steel sheet with 1 wt.% gadolinium was fabricated for a neutron absorbing material with high strength, excellent corrosion resistance, and low cost as well as high neutron absorption capability. The microstructure of the as-cast specimen has typical duplex phases including 31% ferrite and 69% austenite. Main alloy elements like chromium (Cr), nickel (Ni), and gadolinium (Gd) are relatively uniformly distributed in the matrix. Gadolinium rich precipitates were present in the grains and at the grain boundaries. The solution treatment at $1070^{\circ}$ for 50 minutes followed by the hot-rolling above $950^{\circ}$ after keeping the sheet at $1200^{\circ}$ for 1.5 hours are important points of the optimum condition to produce a 6 mm-thick plate without cracking.