• 열처리공학회지
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• 제13권5호
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• pp.337-345
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• 2000

As a case hardening process for stainless steels, nitriding is more preferred and widely used than carburizing which deterioates corrosion resistance severely. In order to add the nitrogen into the stainless steels, passive film on the surface must be removed effectively before nitriding. Conventional gas nitriding process is performed in the temperature range of 500 to $600^{\circ}C$ with $NH_3$ gas, which often leads to sensitization of stainless steels. In this study, we tried to activate passive film of austenitic stainless steels by heating at low pressure. ($900^{\circ}C$, $5{\times}10^{-2}$ Torr.) Nitriding was performed at the solution treatment temperature of $1100^{\circ}C$ with nitrogen molecules instead of $NH_3$ gas. An attainable nitrogen content in a case depends on the nitrogen gas pressure at constant nitriding temperature. A case depth is proportional to the square root of solution time, which suggests that inward diffusion of nitrogen follows the Fick's 2nd law. Surface nitrogen atoms are dissolved as interstitial solutes, or precipitated in the form of MN, $M_2N$ nitrides, which increase the case hardeness. Dissolved nitrogen in the case enhances the cavitation resistance of austenitic stainless steels dramatically.

• Journal of Welding and Joining
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• 제32권2호
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• pp.14-17
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• 2014

Ferritic stainless steels are widely used in the construction industry and in exhaust manifolds due to their low cost and relatively superior stress corrosion cracking resistance and pitting corrosion resistance compared to austenite stainless steels. Ferritic stainless steels are currently welded by various welding process including gas tungsten arc welding (GTAW), electron resistance welding (ERW) and laser beam welding. However, when these stainless steels are welded by fusion welding, some problems occur in the fusion zone (FZ) and heat affected zone (HAZ). First, the ductility of the weld is reduced due to the grain growth in the FZ and HAZ. Second, as its HAZ is frequently sensitized during welding, corrosion resistance deteriorates in this region due to the Cr depletion zone. To prevent these problems, it is recommended that ferritic stainless steels be welded with a low heat input. In this study, recent researches in the view of friction stir welded ferritic stainless steels are briefly reviewed.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 추계학술대회 논문집
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• pp.230-233
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• 2008

Stainless steels are alloy steels with iron as the primary constituent and chromium, nickel, and manganese as principal alloying elements. In addition to automotive, construction, and transportation industries, stainless steels have a variety of applications in the food, chemical, and pharmaceutical industries. Some common products made from stainless steel are sinks, wash basins, kitchen vessels, and cutlery. Among ferritic stainless steels, type 409 can be cold-formed easily and are used for deep-drawn parts such as vessels for the chemical and food industries. In this study, forming analyses and experiments to prevent the occurrence of inferiority such as wrinkles, crack, and neck for automotive muffler part are carried out to save the optimal conditions during forming by modifying the blank size and shape, blank holding force etc.

• 열처리공학회지
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• 제34권1호
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• pp.10-16
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• 2021

Exhaust manifold is a very important component that is directly connected to air environment pollution and that requires strict mechanical properties such as high temperature fatigue and oxidation. Among stainless steels, the ferritic stainless steel with body-centered cubic structure shows excellent resistance of stress-corrosion cracking, ferromagnetic at room temperature, very excellent cold workability and may not be enhanced by heat treatment. The microstructural characteristics of four cast ferritic stainless steels which are high heat-resistant materials, were analyzed. By comparing and evaluating the mechanical properties at room temperature and high temperature in a range of 400℃~800℃, a database was established to control and predict the required properties and the mechanical properties of the final product. The precipitates of cast ferritic stainless steels were analyzed and the high-temperature deformation characteristics were evaluated by comparative analysis of hardness and tensile characteristics of four steels at room temperature and from 400℃ to 800℃.

• Corrosion Science and Technology
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• 제11권2호
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• pp.56-64
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• 2012

Factors affecting corrosion of stainless steels such as pH, oxidation and redox potential (ORP), soil resistivity, water content of soil, chloride ion concentration, bacteria activity, and corrosion potential have been investigated using soil analysis, bacterial analysis, surfacial analysis, and analysis of corrosion potentials of several stainless steels buried in 8 sites of Seoul metropolitan for one year. Corrosion potential was affected by occurrance of corrosion as well as bacteria activity but the behavior of corrosion potential with time is different depending on occurrance of corrosion and bacteria activity. The main factor affecting corrosion of stainless steels in soil is level of chloride ion concentration which is also a main factor affecting corrosion of stainless steels in chloride containing drinkable water. Furthermore, guideline of stainless steels in drinkable water is concluded to be applicable to that in soil by the results from surfacial analysis.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.752-756
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• 2002

Variable weld bead penetrations related to the base metal chemistry of stainless steels in GTA welding have been under constant investigations due to their industrial implications. It has been proposed that among other elements, the sulfur content of steels determines the weld pool geometry, particularly its penetration. It is suggested that the surface tension temperature gradient of steels becomes positive with appropriate dosing in sulfur and results in inward melt flow, propitious for deeper welds. However, the chemistry of industrial steels is complex due to the presence of multiple minor elements either deliberately added or remnant impurity traces. With this in view, investigations on 41 austenitic and nine martensitic stainless steels were carried to see if there existed any possible relation between the weld profile and some of the designated elements. The results suggest no direct correlation between sulfur or any other major or trace element and weld penetration. At first glance the results are contradictory to what is often asserted.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1999년도 제3회 압연심포지엄 논문집 압연기술의 미래개척 (Exploitation of Future Rolling Technologies)
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• pp.366-372
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• 1999

The deformation behavior of commercial stainless steels under hot rolling conditions was investigated by means of hot compression tests performed in the temperature range 800$^{\circ}C$ to 1200$^{\circ}C$. The measured flow stress-strain curves were analyzed by using a simple flow stress model. It was found that the reference strength of stainless steels are much higher than that of carbon steel and that nitrogen and molybdenum alloying greatly increases flow stress of austenitic stainless steel. Ferritic and duplex stainless steel showed comparatively low flow stresses. The flow stress model, which correlates the flow stress with temperature and strain rate, was applied to predict roll forces during hot-plate rolling of stainless steels.

• Archives of Metallurgy and Materials
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• 제64권3호
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• pp.921-924
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• 2019

In this study, ODS ferritic stainless steels were fabricated using a commercial alloy powder, and their microstructures and mechanical properties were studied to develop the advanced structural materials for high temperature service applications. Mechanical alloying and uniaxial hot pressing processes were employed to produce the ODS ferritic stainless steels. It was revealed that oxide particles in the ODS stainless steels were composed of Y-Si-O, Y-Ti-Si-O, and Y-Hf-Si-O complex oxides were observed depending on minor alloying elements, Ti and Hf. The ODS ferritic stainless steel with a Hf addition presented ultra-fine grains with uniform distributions of fine complex oxide particles which located in grains and on the grain boundaries. These favorable microstructures led to superior tensile properties than commercial stainless steel and ODS ferritic steel with Ti addition at elevated temperature.

• 한국표면공학회지
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• 제38권6호
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• pp.227-233
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• 2005

Electrochemical characteristics of welded stainless steels containing Ti have been studied by using the electrochemical techniques in 0.5 M $H_2SO_4$+0.01 M KSCN solutions at $25^{\circ}C$. Stainless steels with 12 mm thick-ness containing $0.2{\~}0.9 wt\%$ Ti were fabricated with vacuum melting and following rolling process. The stainless steels were solutionized for 1hr at $1050^{\circ}C$ and welded by MIG method. Samples were individually prepared with welded zone, heat affected zone, and matrix for intergranular corrosion and pitting test. Optical microscope, XRD and SEM are used for analysing microstructure, surface and corrosion morphology of the stainless steels. The welded zone of the stainless steel with lower Ti content have shown dendrite structure mixed with $\gamma$ and $\delta$ phase. The Cr-carbides were precipitated at twin and grain boundary in heat affected zone of the steel and also the matrix had the typical solutionized structure. The result of electrochemical measurements showed that the corrosion potential of welded stainless steel were Increased with higher Ti content. On the other hand, reactivation($I_r$), passivation and active current($I_a$) density were decreased with higher Ti content. In the case of lower Ti content, the corrosion attack of welded stainless steel was remarkably occurred along intergranular boundary and ${\gamma}/{\delta}$ phase boundary in heat affected zone.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.29-37
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• 2002

High alloyed stainless steels stand out for a high corrosion resistance due to a protective passive layer which is formed when the content of chromium exceeds 13%. When welding these steels, heat tints arise in the area of the weldment. They may occur from flint yellow to intensive blue in the spectrum depending on the applied welding process and the quality of the backing gas used. Due to their structures, they partly drastically reduce the corrosion resistance of stainless steels so that they may lead to damages of the technical application of welded components. In the following the pitting resistance by different backing gases and the chemical composition of the stainless steel itself are described.