• 한국연소학회지
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• 제15권4호
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• pp.58-64
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• 2010

Spontaneous ignition tests of five different coals with non-iso-thermal and iso-thermal test method based on the standard test procedure of NF T20-036 were carried. These five coals included the 2 low rank coals and 3 bituminous coals. Test results showed that the ignition temperatures of all coals at the iso-thermal conditions were higher than that of non-isothermal condition, and those of low rank SM and BR coal in both nonisothermal and isothermal conditions were lower than bituminous AN and CN coals. The chemical species of coals such as oxygen and hematite also plays an important role in enhancing the ignition rate that the ignition temperature of SM coal was lowered. The heat accumulation tendency of five coals inside outdoor stack pile was monitored with emphasis on the change in the temperature of the coal depth in stack pile. In case of low rank BR coal, its temperature inside coal stack pile due to the rate of high heat accumulation and oxidation was $59^{\circ}C$ compared to $51^{\circ}C$ for other SW bituminous coal. And the heat accumulation rate inside coal stack piles was increased with increased the Cp value which it was defined as the specific heat of coal at constant pressure, whereas other factors such as thermal diffusivity and conductivity of coal relatively had less effect on heat accumulation.

• 한국환경과학회지
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• 제26권12호
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• pp.1333-1339
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• 2017

Coal-fired power plants emit various Particulate Matter(PM) at coal storage pile and ash landfill as well as the stack, and affect the surrounding environment. Field Emission Scanning Electron Microscopy and Energy Dispersive X-ray analyzer(FE-SEM/EDX) were used to develop identification factor and the physico-chemical analysis of PM emitted from a power plant. In this study, three samples of pulverized coal, bottom ash, and fly ash were analyzed. The pulverized coal was spherical particles in shape and the chemical composition of C-O-Si-Al and C/Si and C/Al ratios were 200~300 on average. The bottom ash was spherical or non-spherical particles in shape, chemical composition was O-C-Si-Al-Fe-Ca and C/Si and C/Al ratios were $4.3{\pm}4.6$ and $8.8{\pm}10.0$. The fly ash was spherical particles in shape, chemical composition was O-Si-Ai-C-Fe-Ca and C/Si and C/Al ratios were $0.5{\pm}0.2$ and $0.8{\pm}0.5$.

• 유기물자원화
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• 제28권4호
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• pp.53-68
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• 2020

한우를 전문으로 사육하는 전업농가의 퇴비사에서 암모니아와 황화수소 그리고 미세먼지 발생량을 측정하였다. 시험은 단순퇴적식 퇴비화시설(T1)과 기계교반식 퇴비화시설(T2, T3)로 구분하여 수행하였다. 단순퇴적식 퇴비단(T1)의 경우 최고온도가 46℃를 기록하였고, 2곳의 기계교반식 퇴비화시설들(T2, T3)에서는 각각 63℃와 68℃까지 상승하였다. T1에서의 PM2.5 농도는 15 ㎍/㎥ 수준이었고 T2에서는 PM2.5 농도가 5~10 ㎍/㎥ 내외의 수준을 유지하였다. T3에서는 PM2.5의 농도가 10 ㎍/㎥ 이하의 수준이었다. T1에서 발생하는 암모니아의 최고농도는 4 ppm이었으나 황화수소는 검출되지 않았다. T2에서는 암모니아 농도가 최고 3 ppm 수준이었으나 황화수소는 검출되지 않았다. T3의 암모니아 최고농도는 4 ppm을 나타낸 반면에 황화수소는 검출되지 않았다. T3에서는 교반기가 퇴비를 교반하는 지점에서의 암모니아 농도가 65 ppm까지 상승하였다. 퇴비화 기간이 경과함에 따라 초기에 9.06이었던 퇴비단의 pH가 퇴비화기간을 거치면서 8.94로 낮아졌다가 다시 9.14 수준으로 상승하였다. 염분(NaCl)농도는 퇴비화가 진행된 이후에 0.09% 수준이었다. 수분함량은 65.9% 수준에서 62% 수준으로 낮아졌으며, 총고형물 중에서 휘발성고형물(Volatile Solids)이 차지하는 비율은 퇴비화 초기에 65.6%에서 퇴비화후기에는 64.7% 낮아졌다. 퇴비화 초기에 1.327% 수준이었던 TKN 함량도 퇴비화를 거치면서 1.095%로 낮아졌다.