• Title/Summary/Keyword: Stable region

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Thermal Stability Enhancement of Nickel Monosilicides by Addition of Pt and Ir (Pt와 Ir 첨가에 의한 니켈모노실리사이드의 고온 안정화)

  • Yoon, Ki-Jeong;Song, Oh-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.4
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    • pp.27-36
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    • 2006
  • We fabricated thermally evaporated 10 nm-Ni/(poly)Si, 10 nm-Ni/l nm-Ir/(poly)Si and 10 nm-Ni/l nm-Pt/(poly)Si films to investigate the thermal stability of nickel monosilicides at the elevated temperatures by rapid annealing them at the temperatures of $300{\sim}1200^{\circ}C$ for 40 seconds. Silicides of 50 nm-thick were formed on top of both the single crystal silicon actives and the polycrystalline silicon gates. A four-point tester was used to examine sheet resistance. A scanning electron microscope and field ion beam were employed for thickness and microstructure evolution characterization. An X-ray diffractometer and an Auger depth profiler were used for phase and composition analysis, respectively. Nickel silicides with platinum have no effect on widening the NiSi stabilization temperature region. Nickel silicides with iridium farmed on single crystal silicon showed a low resistance up to $1200^{\circ}C$ while the ones formed on polycrystalline silicon substrate showed low resistance up to $850^{\circ}C$. The grain boundary diffusion and agglomeration of silicides lowered the NiSi stable temperature with polycrystalline silicon substrates. Our result implies that our newly proposed Ir added NiSi process may widen the thermal process window for nano CMOS process.

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Construction and operational characteristics of a Ultra-Short pulse Cr4+:YAG laser (극초단 펄스 Cr4+:YAG 레이저의 제작 및 동작 특성)

  • Lee Bong Yeon;Lee Dong Han;Lee Chi Weon;Yoon Seok Beom;Choo Han Tae
    • Korean Journal of Optics and Photonics
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    • v.15 no.5
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    • pp.455-460
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    • 2004
  • We have developed a mode-locked ultra-short pulse C $r^{4+}$:YAG laser, as well as a continuous wave C $r^{4+}$:YAG laser. The laser was pumped by a Nd:YAG laser and its characteristics were investigated. In continuous wave mode, we obtained as much as 600 mW at 1.436 ${\mu}{\textrm}{m}$ with pumping power of 6 W, by using an output coupler with a reflectivity of 98%. The power slope efficiency was 10%, when the gain medium was cooled to 19$^{\circ}C$. The tuning range was varied from 1.39 ${\mu}{\textrm}{m}$ to 1.55 ${\mu}{\textrm}{m}$ and the maximum power was 400 mW at 1.492 ${\mu}{\textrm}{m}$ with a 3-plate birefringent filter. The C $r^{4+}$:YAG laser was mode-locked by a Kerr lens mode locking method. Mode locking at 1.436 ${\mu}{\textrm}{m}$was initiated by slightly rocking a mirror mount. But the pulses were very unstable because of the strong water absorption at this region. So we shifted the lasing wavelength to 1.492 ${\mu}{\textrm}{m}$ by using a 3-plate birefringent filter. Then we obtained stable state mode-locking with the maximum average power of 280 mW for a pumping power of 6 W. The pulse width of 43 fs was measured using an autocorrelator and the repetition rate was 104.5 MHz.

Influence of Temperature on the Treatment Efficiency of Chlorinated Organic Substances in Groundwater by Permeable Reactive Barrier (염소계 유기화합물로 오염된 지하수의 반응성 투과 벽체 처리 효율에 대한 온도의 영향)

  • Kim, Sun-Hye;Kim, Eun-Zi;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.30 no.2
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    • pp.175-183
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    • 2014
  • The influence of temperature on the treatment efficiency of chlorinated organic substances contained in groundwater by permeable reactive barrier which is composed of $Fe^{\circ}$ has been investigated by constructing the Pourbaix diagrams for Fe-$H_2O$ system at different temperatures based on thermodynamic estimation. In aerobic condition, the equilibrium potentials for $Fe^{\circ}/Fe^{2+}$ and $Fe^{2+}/Fe^{3+}$ were observed to increase, therefore, the dechlorination reaction for organic pollutants by $Fe^{\circ}$ was considered to decline with temperature due to the diminished oxidation of reactive barrier. The result for the variations of the ionization fraction of $Fe^{2+}$ and $Fe^{3+}$ ion in the pH range of 0 ~ 2.5 obtained by employing Visual MINTEQ program showed that the ionization fraction of $Fe^{2+}$ increased with pH, however, that of $Fe^{3+}$ decreased symmetrically and the extent of the variation of ionization fraction for both ions was raised as temperature rises. The equilibrium pH for $Fe^{3+}/Fe(OH)_3$ was examined to decrease with temperature so that the treatment efficiency of chlorinated organic substance was expected to decrease with temperature due to the enhanced formation of passivating film in aerobic condition. The change of the reactivity of a specific chemical species with temperature was defined quantitatively based on the area of its stable region in Pourbaix diagram and depending on this the reactivity of $Fe^{3+}$ was shown to decrease with temperature, however, that of $Fe(OH)_3$ was decreased monotonously as temperature is raised for $Fe^{3+}/Fe(OH)_3$ equilibrium system. In anaerobic condition, the equilibrium potential for $Fe^{\circ}/Fe^{2+}$ was observed to rise and the equilibrium pH for $Fe^{2+}/Fe(OH)_2$ were examined to decrease as temperature increases, therefore, similar to that for aerobic condition the efficiency of the dechlorination reaction for organic substances was considered to be diminished when temperature rises because of the reduced oxidation of $Fe^{\circ}$ and increased formation of $Fe(OH)_2$ passivating film.

An Investigative Study of the Awareness of Person in Charge on the Improvement of Extended Support Project Operation for the Public Libraries' Opening Hours (공공도서관 개관시간 연장지원 사업 운영 개선에 대한 담당자 인식조사 연구)

  • Noh, Younghee;Kim, Dongseok;Kwak, Woojung
    • Journal of the Korean Society for Library and Information Science
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    • v.54 no.1
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    • pp.115-143
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    • 2020
  • This study conducted a survey on the current status and satisfaction of libraries participating in the opening hours support project in order to continue it to meet the purpose of improving information access and life welfare. To this end, a questionnaire and interview survey were conducted for those in charge of opening hours for each library, and the results are as follows. First, the opening hours support project is a project that needs a strategy that fits the characteristics of the region and the environment. Therefore, it is necessary to consider operating independently rather than relying on national support in the future through the preparation of regional-oriented operation plans. Second, it is necessary to establish a flexible operating model for opening hours that both employees and users can understand. Third, it is necessary to prepare an organizational operation plan that requires both duties and responsibilities along with the rights equivalent to existing regular employees. Fourth, in order for national public libraries in Korea to develop and implement a consistent policy for specific policies and projects, it is necessary to unify the separate public library operating system in the future. Fifth, it is necessary to prepare education and guidelines for the continuity and stable operation of the project, and to activate services other than labor costs, such as support for improving the space for the user's pleasant use.

Removal Characteristics of Nitrogen and Phosphorus by Struvite Crystallization using Converter Slag as a Seed Crystal (제강전로슬래그를 정석재로 이용한 Struvite 정석반응에 의한 질소와 인의 제거특성)

  • Yim, Soo-Bin
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.879-886
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    • 2010
  • This study investigated the removal characteristics of highly concentrated $NH_4$-N and $PO_4$-P by struvite crystallization using converter slag as a seed crystal. The optimal pH range for removal and recovery of $NH_4$-N and $PO_4$-P by struvite crystallization was measured to be 8.0~8.75, in which total removal efficiencies for $NH_4$-N and $PO_4$-P by struvite precipitation and crystallization were 34.3~61.0% and 91.0~96.2%, respectively. The maximum removal efficiencies for $NH_4$-N and $PO_4$-P by struvite crystallization were 29.4% at pH 8.5 and 65.1% at pH 8.0, respectively. The removal efficiency of $NH_4$-N by struvite crystallization decreased with increasing calcium ion concentration. The analysis results of SEM, EDS and XRD exhibited that $NH_4$-N and $PO_4$-P in meta-stable region of struvite crystallization could be eliminated through formation of magnesium ammonia phosphate (MAP) and hydroxyapatite (HAp) on seed crystals by struvite precipitation and crystallization.

Oxygen-deficient Reduced TiO2-X: Surface Properties and Photocatalytic Activity

  • Sinhamahapatra, Apurba;Jeon, Jong-Pil;Yu, Jong-Sung
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.59-75
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    • 2016
  • Reduced or black $TiO_{2-x}$ materials with oxygen-deficiency have been achieved by creating oxygen vacancies and/or defects at the surface using different methods. Fascinatingly, they exhibited an extended absorption in VIS and IR instead of only UV light with bandgap decrease from 3.2 (anatase) to ~1 eV. However, despite the dramatic enhancement of optical absorption in black $TiO_{2-x}$ materials, they have failed to show expected visible light-assisted water splitting efficiency. This was ascribed to the high concentration of the surface defects and/or oxygen vacancies, considered as an electron donor to enhance donor density and improve the charge transportation in black $TiO_2$ can also act as charge recombination centers, which eventually decrease photocatalytic activity. Therefore, a black ot reducd $TiO_2$ material with optimized properties would be highly desired for visible light photocatalysis. In this report, a new controlled magnesiothermic reduction has been developed to synthesize reduced black $TiO_{2-x}$ in the presence $H_2/Ar$ for photocatalytic $H_2$ production from methanol-water system. The material possesses an optimum band gap and band position, oxygen vacancies, and surface defects and shows significantly improved optical absorption in the visible and infrared region. The synergistic effects enable the reduced $TiO_{2-x}$ material to show an excellent hydrogen production ability along with long-term stability under the full solar wavelength range of light and visible light, respectively, in the methanol-water system in the presence of Pt as a co-catalyst. These values are superior to those of previously reported black $TiO_2$ materials. On the basis of all the results, it can be realized that the outstanding activity and stability of the reduced of $TiO_{2-x}$ NPs suggest that a balanced combination of different factors like $Ti^{3+}$, surface defects, oxygen vacancy, and recombination center is achieved along with optimized bandgap and band position during the preparation employing magnesiothermic reduction in the presence of $H_2$. The controlled magnesiothermic reduction in the presence of $H_2$ is one of the best alternative ways to produce active and stable $TiO_2-based$ photocatalyst for $H_2$ production.

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Vascular plant diversity and vegetation of Yokjido Island in Tongyeong-si, Korea (욕지도(통영시)의 식물다양성과 식생)

  • Kim, Jung-Hyun;Jung, Eun-Hee;Lee, Kyeong-Ui;Nam, Chun-Hee;Park, Sung-Ae;Park, Chan-Ho;Nam, Gi-Heum;Lee, Byoung Yoon;Suh, Min Hwan
    • Korean Journal of Plant Taxonomy
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    • v.46 no.1
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    • pp.83-116
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    • 2016
  • This study was carried out to investigate the flora and vegetation of Yokjido Island in Tongyeong-si, Korea. Vascular plants collected six times (from March of 2015 to January of 2016) were identified as 547 taxa in total, including 113 families, 354 genera, 487 species, four subspecies, 50 varieties, four forms and two hybrids. The first records from this region contained 314 taxa. In the flora of this area, endemic Korean species numbered eight taxa, and the red list of vascular plants according to the IUCN valuation basis numbered six taxa. In addition, 86 taxa of floristic regional indicator plants specially designated by the Ministry of Environment are included. Among the species investigated in this survey, 99 taxa were identified as specific species bio-geographically as compared floras of other terrestrial regions; 97 taxa of plants in southern areas and two taxa of limited distribution plants on the Korean Peninsula. In all, 74 naturalized plants were recorded in the investigated area. Samples of the forest vegetation of Yokjido Island were mainly classified as Pinus thunbergii community and the Alus firma community. Vertical structures of the communities were stable, and a DBH-class analysis showed that the dominant tree species would be maintained. If disturbance factors such as thinning could be halted, the composition of woody species and herbaceous species would change.

Improvement of Earthquake-Resistant Performance of R/C Beam-Column Joint Constructed with High-Strength Concrete Subjected to Cyclic Loading (고강도 철근콘크리트 보-기둥 접합부의 내진성능 개선에 관한 실험적 연구)

  • Ha, Gee-Joo;Kim, Jin-Keun;Chung, Lan
    • Magazine of the Korea Concrete Institute
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    • v.4 no.1
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    • pp.135-145
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    • 1992
  • With the increasing tendency to construct high rise reinforced concrete building~i, it is required to use high strength materIals, smaller member sections, and larger reinforcing bars, I t is generally recognized that under severe seismic loads beam column jomts may become more critical structural components than other structural elements. In a ductile momentresistmg reinforced concrete frame, the connection of bearncolumn must be capable of resistll1g the large lateral forces caused by seismic actions, The purpose of this experimental study is to evaluate and ll1vestigate the earthquake resistant perform ance of beam-colurrm subassemblies constructed with high-strength concrete cast by the concrete of com¬pressive strength of 700kg / cm2 subjected to reversed cyclic loadings. New approaches for moving the plastic hinging zone away from the column face and preventing the di¬agonal crack in the joint region are adopted to advance the earthquake-resistant performance of beam-column subassemblies using high-strengh concrete under severe earthquake-type loading. Exper¬imental results indicate that the modified new details which are introduced by intermediate reinforcement in the beam over a specific beam length adjacent to the joint are able to attain the stable hysteretic behavior and the enhancement of earthquake-resistant performance. Keywords: high strength concrete: beam-column Joints; seirnic loads(reversed cyclic loading) : earth¬quake-resistant performance; plastic hinge zone: diagonal crack: intermediate reinforce¬ment ; closed strirrup: hysteretic behavior: enhancement .

The Anatomy of the Uneven Regional Development in the Republic of Korea: Lessons from Experiences of Wealth, Inequality and Regional Development in the United Kingdom and Italy (한국 지역불균등 발전의 해부: 영국과 이탈리아 부, 불균등, 지역발전 경험으로부터 교훈)

  • Jung, Sung-Hoon
    • Journal of the Economic Geographical Society of Korea
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    • v.19 no.2
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    • pp.330-342
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    • 2016
  • The aim of this article is to explore some issues on the uneven regional development in the Republic of Korea. Along with this, case studies on the United Kingdom and Italy are conducted in terms of their wealth, inequality and regional development. In the period of 1995~2003, the UK experienced the intensified uneven regional development and continuous increase of its index due in the main to the delayed revitalization of industrial decline regions, neo-liberalistic local labour market and industrial policies, and institutional instability of regional policies. In the case of Italy, it seemed to experience relatively stable regional convergence. However, this was caused by the continuous decline of major metropolitan areas such as large cities, Milan, Turin, Genoa, to name but a few. The Republic of Korea experienced 'economic growth with spatial and social disparities.' Since 2003 the uneven regional development has intensified. Towards regional convergence, new engines of regional development, the investment in the specialization of small and medium cities, and supportive policies for industrial restructuring regions are required.

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Estimating Tree Shape Ratio by Region for Pinus Densiflora and Larix Kaempferi in Korea (우리나라 소나무 및 일본잎갈나무의 지역별 형상비 추정)

  • Kang, Jin-Taek;Ko, Chi-Ung;Yim, Jong-Su;Lee, Sun-Jeoung;Moon, Ga-Hyun
    • Journal of Korean Society of Forest Science
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    • v.108 no.4
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    • pp.600-609
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    • 2019
  • This study was conducted to highlight the necessity for a stand density control management plan in consideration of the shape ratio of Pinus densiflora and Larix kaempferi in Korea. A total of 2,112 Pinus densiflora samples and 2,030 Larix kaempferi samples were cut, and their diameter at breast height (DBH), height, and clear length were measured for regional shape ratio (height/DBH) comparison and analysis.The shape ratio of Pinus densiflora was 72.3% in the Gangwon district, 64.0% in the central district, and 70.8% on average, indicating a higher percentage of Pinus densiflora in Gangwon than in the central area. Regionally, Yeongju had the highest percentage at 78.4%, with Yeongwol indicating 77.5%. Measured by diameter, results showed a presence of 90.4% for small diameter trees (6-16 cm), 71.7% for medium diameter trees (18-28 cm), and 56.1% for large diameter trees (30 cm). As density increased, the shape ratio of height to tree trunk diameter also increased; below 70% indicated a more stable trunk, while a result above 80% indicated trunks prone to wind hazards and snowstorms, and, therefore, the need for density control in partial areas. The overall shape ratio of Larix kaempferi was 90.6%. Pyeongchang indicated a 108.5% ratio, Yeongju 105.4%, and Danyang 100.5%, respectively.According to diameter class, small diameter trees showed 104.9% occurrence, medium diameter trees 92.7%, and large diameter trees 73.4%. The shape ratio of Larix kaempferi was higher than 80% overall, indicating vulnerability to wind hazards and snowstorms. Therefore, appropriate stand density management is required.