• Title/Summary/Keyword: Stable process

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The Effect of Misch Metal on the Microstructure of Rapidly solidified Ag-Sn-In Alloys (급속응고한 Ag-Sn-In 합금의 미세조직에 미치는 Misch Metal의 영향)

  • Chang, Dae-Jung;Nam, Tae-Woon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.561-565
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    • 2007
  • Because of a good wear resistance and a stable contact resistance, Ag-CdO is widely used as electrical contact material. But, the Cd-oxide mainly exists as a coarse particle and adversely affected to environment. As a reason, $Ag-SnO_2$ alloy has been developed. The Sn-oxide maintains stable and fine particle even at high temperature. In order to investigate the effect of Misch metal (Mm) additional that affects the formation of the oxide and the formation of fine matrix Ag, we studied the microstructures and properties of Ag-Sn-In(-Mm) material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. The Mm addition makes Ag matrix more fine than no Mm addition. The reason is that the addition of Misch metal decreased a latent heat of fusion of alloy, as a result the rapid solidification effect of alloy is increased. The maximum hardness shows at 0.3 wt%Mm. after that the hardness is decreased until 0.4 wt% Mm, but still larger than no Mm addition alloy. At 0.5 wt% Mm alloy, the precipitation of Misch metal causes a decrease of hardness than no Mm addition alloy.

A study on Improvement of $30{\AA}$ Ultra Thin Gate Oxide Quality (얇은 게이트 산화막 $30{\AA}$에 대한 박막특성 개선 연구)

  • Eom, Gum-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.421-424
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    • 2004
  • As the deep sub-micron devices are recently integrated high package density, novel process method for sub $0.1{\mu}m$ devices is required to get the superior thin gate oxide characteristics and reliability. However, few have reported on the electrical quality and reliability on the thin gate oxide. In this paper I will recommand a novel shallow trench isolation structure for thin gate oxide $30{\AA}$ of deep sub-micron devices. Different from using normal LOCOS technology, novel shallow trench isolation have a unique 'inverse narrow channel effects' when the channel width of the devices is scaled down shallow trench isolation has less encroachment into the active device area. Based on the research, I could confirm the successful fabrication of shallow trench isolation(STI) structure by the SEM, in addition to thermally stable silicide process was achiever. I also obtained the decrease threshold voltage value of the channel edge and the contact resistance of $13.2[\Omega/cont.]$ at $0.3{\times}0.3{\mu}m^2$. The reliability was measured from dielectric breakdown time, shallow trench isolation structure had tile stable value of $25[%]{\sim}90[%]$ more than 55[sec].

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Optimal Design of Slider for Stable Flying Characteristics using $4{\times}1$ Near-field Probe Array

  • Jung, Min-Su;Hong, Eo-Jin;Park, Kyoung-Su;Park, No-Cheol;Yang, Hyun-Seok;Park, Young-Pil;Lee, Sung-Q;Park, Kang-Ho
    • Transactions of the Society of Information Storage Systems
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    • v.2 no.1
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    • pp.65-70
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    • 2006
  • In the information storage development, the trend of the storage device is to increase the recording density. Among such an effort, near-field probe recording is spotlighted as a method of high increasing recording density. For the successfully embodiment of storage device, the actuating mechanism of near-field probe is essentially designed. In this paper, we suggest the slider similar with conventional HDD and design the slider using near-field probe for the purpose of applying the slider in order to control gap between probe and media. The most important object of slider design is to guarantee the flying ability and stability. For achievement of these design objects, we perform two step of optimal design process. The media is supposed to model as random displacement, which is only considered roughness of disk surface. The design slider is analyzed with dynamic state in assumed media. At this process, the optimal model is confirmed to stable flying stability.

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DC Sputtering Process of 2-Dimensional Tungsten Disulfide Thin Films on Soda-Lime Glass Substrates (DC 스퍼터링을 이용한 소다라임 유리 기판상에 2차원 황화텅스텐 박막 형성 공정)

  • Ma, Sang Min;Kwon, Sang Jik;Cho, Eou Sik
    • Journal of the Semiconductor & Display Technology
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    • v.17 no.3
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    • pp.31-35
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    • 2018
  • Tungsten disulfide($WS_2$) thin films were directly deposited by direct-current(DC) sputtering and annealed by rapid thermal processing(RTP) to materialize two-dimensional p-type transition metal dichalcogenide (TMDC) thin films on soda-lime glass substrates without any complicated exfoliation/transfer process. $WS_2$ thin films deposited at various DC sputtering powers from 80 W to 160W were annealed at different temperatures from $400^{\circ}C$ to $550^{\circ}C$ considering the melting temperature of soda-lime glass. The optical microscope results showed the stable surface morphologies of the $WS_2$ thin films without any defects. The X-ray photoelectron spectroscopy (XPS) results and the Hall measurement results showed stable binding energies of W and S and high carrier mobilities of $WS_2$ thin films.

Research of Sea Food Wastewater Treatment using Membrane Filter (Membrane Filter를 이용한 수산물 가공폐수처리에 대한 연구)

  • Han, Dong-Joon
    • Journal of environmental and Sanitary engineering
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    • v.22 no.4
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    • pp.119-130
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    • 2007
  • Sea food wastewater including high concentration of organics and nutrients is hard to treat stably by established traditional activated sludge process. This research is aimed to obey more and more of strengthened the law and to secure stable effluents by using advanced treatment process applied membrane filter in aeration tank for treatment of wastewater from marine products. It must maintain pH of influent over 6.0 to keep up stably biological sludge of advanced treatment process. At 38hr of HRT, removal rates of TBOD and TCOD were 99.9% and 99.4% respectively and TSS also removed with high efficiency. Most organics in the effluent was constituted with soluble type materials, it caused that membrane filter installed aeration tank should remove minute suspended particles. The reactor was operated well to get stable treatment results for operation period, in spite of high loading of organics like that $0.67{\sim}1.67\;kgTBOD/m^3/day$ of organics loading and $0.10{\sim}0.21\;kgBOD_5/kgMLSS/day$ of F/M ratio. At $36{\sim}48hr$ of HRT, removal rates of T-N and T-P were $89.7{\sim}90.7%\;and\;91.5{\sim}96.0%$ respectively. It means this treatment process also work to remove nutrients of high concentration. Upon investigation of advanced treatment's operation factors, optimum SRT was about 30days and average SNR that showed tendency to increase according to increase water temperature was calculated 0.014 gN/g MLVSS/d. SDNR was risen in conformity to increase F/M ratio of Non-aeration tank and investigated as $0.038{\sim}0.051\;gN/gMLVSS/d$.

Effect of the Formation of an Initial Oxide Layer on the Fabrication of the Porous Aluminium Oxide (초기 산화 피막의 형성이 다공성 알루미나 막 제작에 미치는 영향)

  • Park, Young-Ok;Kim, Chul-Sung;Kouh, Tae-Joon
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.79-83
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    • 2008
  • We have investigated the effect of the formation of an initial oxide layer on the fabrication of the porous aluminium oxide. The porous aluminium oxide was fabricated by two-step anodization process with a electropolished aluminium foil. Before the first anodization step, the initial oxide layer with thickness of 10 nm was formed under the applied voltage of 1 V and later the anodization was continued under 40 V using oxalic acid solution. With the formation of the initial oxide layer, the anodization process was stable and the anodization current was constant throughout the process. In case of the absence of the initial oxide layer, the anodization was very unstable and the continuous increase in the anodization current was observed. This indicates the formation of the initial oxide layer on the aluminium surface prevents the burning of the surface due to the nonuniform distribution of the applied electric field, and allows the stable anodization process required for the porous aluminium oxide.

ANALYSIS OF HCCI COMBUSTION CHARACTERISTICS BASED ON EXPERIMENTATION AND SIMULATIONS-INFLUENCE OF FUEL OCTANE NUMBER AND INTERNAL EGR ON COMBUSTION

  • Iijima, A.;Yoshida, K.;Shoji, H.;Lee, J.T.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.137-147
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    • 2007
  • Homogenous Charge Compression Ignition (HCCI) combustion systems can be broadly divided for the process applied to 4-stroke and 2-stroke engines. The former process is often referred to as simply HCCI combustion and the latter process as Active Thermo-Atmosphere Combustion (ATAC). The region of stable engine operation tends to differ greatly between the two processes. In this study, it was shown that the HCCI combustion process of a 4-stroke engine, characterized by the occurrence of autoignition under a high compression ratio, a lean mixture and wide open throttle operation, could be simulated by operating a 2-stroke engine at a higher compression ratio. On that basis, a comparison was made of the combustion characteristics of high-compression-ratio HCCI combustion and ATAC, characterized as autoignited combustion in the presence of a large quantity of residual gas at a low compression ratio and part throttle. The results showed that one major difference between these two combustion processes was their different degrees of susceptibility to the occurrence of cool flame reactions. Compared with high-compression-ratio HCCI combustion, the ignition timing of ATAC tended not to change in relation to different fuel octane numbers. Furthermore, when internal EGR was applied to high-compression-ratio HCCI combustion, it resulted in combustion characteristics resembling ATAC. Specifically, as the internal EGR rate was increased, the ignition timing showed less change in relation to changes in the octane number and the region of stable engine operation also approached that of ATAC.

A Study on the Treatment of Swine Wastewater by Using Intermittently Aerated Activated Sludge Process (간헐폭기법에 의한 돈사 폐수 처리에 관한 연구)

  • Yang, Tae-Du;Lee, Mi-Kyung;Chung, Yoon-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.4
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    • pp.86-96
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    • 1998
  • In this study, an intermittently aerated activated sludge process, modified process from conventional activated sludge process, was developed to treat high strength swine wastewater, which has been blamed as major pollutant for stream pollution. Therefore, the optimum cycle for oxic and anoxic period, SRT, and OLR were studied as design parameters. The effects of different time interval for oxic and anoxic period on nitrification and denitrification were examined by operating two reactors with 60/60min and 60/90min as oxic/anoxic period. Although the reactor with 60/60min showed complete denitrification of $NO_x-N$ generated during oxic period, the reactor with 60/90min showed incomplete nitrification due to the inactivity of nitrifier by accumulated $NH_3-N$ toxicity during anoxic period. Therefore, it is recommended to operate same interval for oxic and anoxic period. In order to determine the optimum cycle for oxic/anoxic period, four different reactors with 30/30, 60/60, 90/90 and 120/120min were examined. The reactor operation with 90/90min was optimum to get the most stable results in this study. However, the optimum cycle for oxic and anoxic period should be changed with characteristics of influent wastewater and operating conditions. According to lie operation results of three reactors with SRT of 15, 20 and 30days. The reactor with 2Odays SRT showed best removal efficiency of T-N. The optimum OLR would be $2.5Kg\;COD/m^3/day$ which showed the most stable nitrification and denitrification. Since characteristics of influent wastewater in the real system has a severe fluctuation, so it is very difficult to determine each interval for oxic and anoxic period. Therefore, ORP curves, describing the change of oxidation/reduction potential in reactor, can be used as a control parameter for automatic control of oxic and anoxic period. In other words, bending point (Nitrate Knee) of ORP curve during anoxic period could be used as a starting point of oxic period.

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MNDO Studies on Intramolecular Proton Transfer Equilibria of Acetamide and Methyl Carbamate$^1$

  • Lee, Ik-Choon;Kim, Chang-Kon;Seo, Heon-Su
    • Bulletin of the Korean Chemical Society
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    • v.7 no.5
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    • pp.395-399
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    • 1986
  • Intramolecular proton transfer equilibria of acetamide and methyl carbamate have been studied theoretically by MNDO MO method. For both substrates, carbonyl-O protonated tautomer was found to be the most stable form, the next most stable one being N-protonated form. Gas phase proton transfers take place by the 1,3-proton rearrangement process and in all cases have prohibitively high activation barriers. When however one solvate water molecule participates in the process, the barriers are lowered substantially and the process proceeds in an intermolecular manner through the intermediacy of the water molecule via a triple-well type potential energy surface; three wells correspond to reactant(RC), intermediate(IC) and product complex(PC) of proton donor-acceptor pairs whereas two transition states(TS) have proton-bridge structure. General scheme of the process can be represented for a substrate with two basic centers(heteroatoms) of A and B as, $$ABH\limits^+\;+\;H_2O\;{\to}\;ABH\limits^+{\cdots}{\limits_{RC}}OH_2\;{\to}\;AB{\cdots}H\limits_{TS}^+{\cdots}{\limits_{1}}OH_2\;{\to}\;AB{\cdots}{\limits_{IC}}H\limits^+OH_2\;{\to}\;BA{\cdots}H\limits_{TS}^+{\cdots}{\limits_{2}}OH_2\;{\to}\;BA H\limits^+{\cdots}{\limits_{PC}}OH_2\;{\to}\;BAH\limits^+\;+\;H_2O$$ Involvement of a second solvate water had negligible effect on the relative stabilities of the tautomers but lowered barrier heights by 5∼6 Kcal/mol. It was calculated that the abundance of the methoxy-O protonated tautomer of the methyl carbamate will be negligible, since the tautomer is unfavorable thermodynamically as well as kinetically. Fully optimized stationary points are reported.

A study on the TDS removal characteristics in aqueous solution using MCDI module for application of water treatment process (정수처리 공정 적용을 위한 MCDI (Membrane Capacitive Deionization) Module의 수용액 내 TDS 제거 특성에 관한 연구)

  • Oh, Changseog;An, Jusuk;Oh, Hyun-Je
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.4
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    • pp.293-300
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    • 2021
  • Recently, various researches have been studied, such as water treatment, water reuse, and seawater desalination using CDI (Capacitive deionization) technology. Also, applications like MCDI (Membrane capacitive deionization), FCDI (Flow-capacitive deionization), and hybrid CDI have been actively studied. This study tried to investigate various factors by an experiment on the TDS (Total dissolved solids) removal characteristics using MCDI module in aqueous solution. As a result of the TDS concentration of feed water from 500 to 2,000 mg/L, the MCDI cell broke through faster when the higher TDS concentration. In the case of TDS concentration according to the various flow rate, 100 mL/min was stable. In addition, there was no significant difference in the desorption efficiency according to the TDS concentration and method of backwash water used for desorption. As a result of using concentrated water for desorption, stable adsorption efficiency was shown. In the case of the MCDI module, the ions of the bulk solution which is escaped from the MCDI cell to the spacer during the desorption process are more important than the concentration of ions during desorption. Therefore, the MCDI process can get a larger amount of treated water than the CDI process. Also, prepare a plan that can be operated insensitive to the TDS concentration of backwash water for desorption.