• Journal of the Mineralogical Society of Korea
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• v.5 no.1
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• pp.6-13
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• 1992

Thermodynamic data of mineral reactions were used to construct a phase diagram for the formation of illite from andalusite at one bar and 325${\circ}C$ in the hydrothermal alteration. Based on chemical compositions, the free energy of formation of illite coexisting with andalusite was calculated by assuming the ideal mixing ina bunary system consisting of muscovite and pyrophyllite components. For illite with structural formula $K_{0.86}Al_{2.93}Si_{3.03}O_{10}(OH)_2$, its free energy of formation is -1147.727 kcal/mole at the condition under consideration. The stability area of illite is more narrow than that of end-member muscovite and prefers lower activity of silica. Illite was formed by hydration of andalusite while pyrophyllite decomposed. Illitization took place preferentially at margin and/or along fractures of andalusite.

• Journal of the Korean Ceramic Society
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• v.44 no.7
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• pp.368-374
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• 2007

CVD-SiC coating has been introduced as a protective layer in TRISO nuclear fuel particle of high temperature gas cooled reactor (HTGR) due to its excellent mechanical stability at high temperature. In order to prevent the failure of the TRISO particles, it is important to evaluate the fracture strength of the SiC coating layer. It is needed to develop a new simple characterization technique to evaluate the mechanical properties of the coating layer as a pre-irradiation step. In present work, direct strength measurement method with the specimen of hem i-spherical shell configuration was suggested. The indentation experiment on a hemisphere shell with a plate indenter was conducted. The fracture strength of the coating layer is related with the critical load for radial cracking of the shell. The finite element analysis was used to drive the semi-empirical equation for the strength measurement. The SiC hemispherical shells were successfully recovered from the section-grinding of TRISO coated particle and successive heat treatment in air. The strength of CVD-SiC coating layer was evaluated from the experimentally measured critical load during the indentation on SiC hemisphere shell. Weibull diagram of fracture strength was also constructed. This study suggested a new strength equation and experimental method to measure the fracture strength of CVD-SiC coating of TRISO coated fuel particles.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.12
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• pp.1483-1487
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• 2013

Water injection pump outputs oil with high pressure during this process, seawater is injected into the well to recover the well pressure and maintain high productivity. A water injection pump has high productivity, and therefore, it serves as a key piece of equipment in marine plants. In this light, water injection pumps are being studied widely in industry. In this study, the rotor dynamics is analyzed to determine the natural frequency according to the bearing stiffness and operation speed change. This study aims to establish the pump reliability through critical speed, stability, and unbalance response analysis.

• Journal of the Korean Geophysical Society
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• v.7 no.2
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• pp.113-120
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• 2004

Hydrochemical characteristics of deep groundwater at Surak-ri, Nonsan-gun, Chungnam Province was explained by major ion concentration, water type, and phase stability diagram. The area is composed of meta-sedimentary rock and quartz pophyry. The 5 boreholes where deep groundwater was sampled and analyzed are located on the meta-sedimentary rocks and drilling depth range of the wells is from 554 m to 928 m. pH, TDS, Na, and SiO2 values are high in the groundwater from meta-sedimentary area intruded by quartz pophyry, while Ca is high in the groundwater from meta-sedimentary area. K and Mg concentrations are low but F concentration is high both groundwater. The content of major anions is in the order of CO3(HCO3)>Cl>SO4(F) in both geology, while that of major cations shows the order of Na>Ca>K(Mg) in meta-sedimentary area intruded by quartz porphyry and a>Na>Mg>Na in meta-sedimentary area. Based on the phase equilibrium in the systems Na2O-Al2O3-SiO2-H2O and K2O-Al2O3-SiO2-H2O, the groundwater is saturated with respect to Quartz and more evolved compared with the natural mineral water. It is concluded that chemical evolution in the groundwater from meta-sedimentary area intruded by quartz porphyry, is nearly saturated with respect to feldspar, while the groundwater from meta-sedimentary area continue to proceed with increasing pH by reaction of feldspar.

• Journal of Korean Society on Water Environment
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• v.27 no.6
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• pp.896-904
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• 2011

The features of the capture reaction of $CO_2$ by ammonia solution have been investigated along with the effect of temperature on the reaction based upon computer program-utilizing calculation and thermodynamic estimation. The stable region of $CO{_3}^{2-}$ was observed to increase with temperature and the change of the stable region of $CO{_3}^{2-}$ with temperature was greater than the temperature variation of the stable region of other carbonate species. The distribution diagram for $NH_4{^+}-NH_3$ system was constructed and the rise of temperature resulted in the decrease of the stability of $NH_4{^+}$ ion, which was thought to be due to the endothermic nature of its acidic dissociation. Considering the introduction of $Ca^{2+}$ ion in the carbon capture reaction by $NH_4{^+}$, the temperature was observed to be important in the determination of the order of reaction between carbonate ion and these cations. The removal process of $CO_2$ gas by ammonia solution was presumed to occur in open system and the temperature variations of the concentration of carbonate system species along with their total concentration were calculated for the proper control and design of the real process.

• Journal of Convergence for Information Technology
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• v.12 no.2
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• pp.142-148
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• 2022

In this paper, the weight reduction design of the yaw gearbox for wind turbine was performed through the finite element analysis method, and the stability was checked by performing the critical speed analysis. The weight reduction product can improve engine efficiency, save parts materials, and earn economic benefits. The yaw gearbox is lightweighted with the goal of achieving a safety rate of 1.3 or higher for wind turbine as indicated by IEC61400-1. In order to reduce the weight of the carrier, a topology optimization method was performed. The safety factor was verified by performing finite element analysis on the carrier. In addition, the housing and carrier were modeled using the finite element method, and the gear train was modeled using MASTA. For the yaw gearbox, the housing and carrier FE model and the gear train model were connected by the partial structural synthesis method to perform the rotational vibration analysis. Vibration excitation sources are mass unbalance and gear mesh frrequemcy, and as a result of the critical speed analysis, it was found that there was no resonance within the operating speed range.

• Proceedings of the Korean Society of Applied Pharmacology
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• 1997.04a
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• pp.116-116
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• 1997

Complex formation of practically insoluble dexamethasone dipropionate (DDP) with ${\beta}$-cyclodextrin (${\beta}$-CD), dimethyl-${\beta}$-cyclodextrin (DMCD), trimethyl-${\beta}$-cyclodextrin (TMCD), 2-hydroxypropyl-${\beta}$-cyclodextrin (HPCD) and sulfobutyl ether ${\beta}$-cyclodextrin (SBCD) in water was investigated by solubility method at various temperatures. Water solubility of DDP was found to be 1.78 $\mu\textrm{g}$/$m\ell$ at 37$^{\circ}C$. Propylene glycol (PG)-water cosolvent increased the solubility of DDP, but the solubilization was not sufficient (8.93 $\mu\textrm{g}$/$m\ell$ in 20% PG). The addition of CD markedly increased the solubility of DDP in water, and A$\sub$L/ type phase solubility diagrams were obtained with ${\beta}$-CD, TMCD, HPCD and SBCD, where the apparent stability constants of the soluble complexes at 25$^{\circ}C$ were determined to be 1388, 216, 1054, and 1992 M$\^$-1/, respectively. However, DMCD remarkably increased the solubility of DDP, and showed an A$\sub$P/ type diagram, suggesting that DMCD forms a soluble complex of high order with DDP. The stability constant for the DDP-DMCD complex at 25$^{\circ}C$ was determined to be 19132 M$\^$-1/. The thermodynamic parameters were calculated for the inclusion complex formation in aqueous solution. CD (1${\times}$10$\^$-2/M) remarkably decreased the partition coefficients of DDP between isopropyl myristate/water in the order of TMCD < ${\beta}$-CD < HPCD < SBCD < DMCD, and in squalane/water system in the order of HPCD < TMCD < ${\beta}$-CD < DMCD < DMCD $\leq$ SBCD. This finding represents that, in a o/w type cream, cyclodextrin complexation with DDP may result in high concentration of DDP in aqueous phase. The permeation of DDP through a cellophane membrane was highly suppressed by the addition of CD, and the degree of suppression was different among CDs, indicating that CD may control the skin permeation of DDP. The dissolution rates of solid dispersions with CDs were much faster than those of drugs alone and corresponding physical mixtures. All DDP-CD solid dispersions exceeded the equilibrium solubility. Consequently these results suggest that complex formation of DDP with CDs may provide useful means to markedly enhance the solubility, and CDs are useful in the semi-solid preparations such as creams and gels for topical application.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.33 no.3
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• pp.110-121
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• 2021

The importance of tidal flats lost due to industrialization has recently received attention, and attention is being paid to the creation of artificial tidal flats and maintenance of natural tidal flats. However, there is still a lack of understanding about the behavioral characteristics of mud, mud, and sand that form tidal flats. Although research on the movement characteristics of mixed soils such as tidal flats has been conducted through field investigations and hydraulic experiments, interest in developing a numerical model based on these results has not yet reached. In this paper, the purpose of this paper is to establish a mixed soil model that can efficiently manage the low quality of the tidal flats. In constructing a model for reproducing the surface movement of mixed soil, the numerical stability of the reproduction and movement of sand and mud constituting the mixed soil in the numerical model should be considered first, so first, the volume of sand and mud constituting the mixed soil A mixed soil model representing the relationship was proposed based on a topographical diagram representing the geometric structure of the mixed soil. In order to consider the dry bulk density of the mixed soil, it was possible to consider the dry bulk density of the mud by introducing the water content of the mud containing water. In addition, it was confirmed that the mud and sand movement calculation according to the slope collapse of the mixed soil was stably performed through the calculation of the slope collapse of the mixed soil through the numerical analysis model to which the proposed mixed soil model was applied.

• Korean Journal of Construction Engineering and Management
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• v.6 no.3 s.25
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• pp.144-155
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• 2005

Since 1950s, the Korean housing market has continually experienced the chronicle lack of housing stock because of lower housing investment in comparison with a population explosion, prompt urbanization and rapid restructuring of family. The Korean housing market have thus been driven not by the pricing model by housing demand-supply chain but by the Korean housing policies focusing on the increase of housing supply and the living stability of the middle or low-income bracket. After all, repetitive economic vicious circle of housing price and the increase of unsold apartments aggravated the malfunction of the Korean housing market. Meanwhile, the Korean construction firms have exacerbated their profitability. Such terrible situations are mainly triggered by the Korean construction firms that weighed on the short-term profits and quick response of the government policy alterations rather than the prospect of housing market Therefore, this research focusing on the dynamics of housing market identified and classified the demand and supply elements that consist not only of housing system structures but also of the environmental elements that affect the structures. Based on the system thinking and traditional theory of consumer's choice, the interactions of these elements were constructed as a causal loop diagram that explains the mutual influences among housing subsystems with feedback loops. This paper describes and discusses about the causes of the dynamic changes in the Korean housing market. This study would help housing suppliers, including housing developers, construction firms, etc., to form a more comprehensive understanding on the fundamental issues that constitute the Korean housing market and thereby increasing their long term as well as minimizing the risk involved in the housing supply businesses.

• Journal of Pharmaceutical Investigation
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• v.41 no.2
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• pp.103-109
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• 2011

The objective of the study was to prepare self-microeulsifying drug delivery system (SMEDDS) incorporating atorvastatin calcium and evaluate its properties and oral bioavailability. Solubility of atorvastatin in various vehicles was determined. Pseudo-ternary phase diagrams were constructed to identify the good self-emulsification region. The droplet size distributions of the resultant emulsions were determined by dynamic light scattering measurement. The mean droplet size of chosen formulation (20% ethyl oleate, 40% tween-80, 40% Carbitol$^{(R)}$) was $23.4{\pm}1.3$ nm. The SMEDDS incorporating atorvastatin calcium appeared to be associated with better performance in dissolution and pharmacokinetic studies, compared with raw atorvastatin calcium. In dissolution test, the release percentage of atorvastatin from SMEDDS mixture could rapidly reach more than 95% within 3 min. Oral $AUC_{0{\rightarrow}8hr}$ values in SD rats was $1994{\pm}335\;ng{\cdot}hr/mL$, which significantly increased (P<0.05) compared with raw atorvastatin calcium. The SMEDDS formulation was relatively stable when stored at $4^{\circ}C$ during 3 months. Our studies illustrated the potential use of SMEDDS for the delivery of hydrophobic compounds, such as atorvastatin, by the oral route.