• Title/Summary/Keyword: Stability and stabilization

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The Effect of Solvents on the Formation of Complexes of Benzene with Iodine and with Iodine Monochloride (벤젠과 요오드 또는 일염화요오드 사이의 錯物에 대한 용매의 영향)

  • Choi, Sang-Up;Lee, Bu-Yong
    • Journal of the Korean Chemical Society
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    • v.9 no.4
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    • pp.161-168
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    • 1965
  • The effect of solvents on the stabilities of the $C_6H_6{\cdot}I_2$ complex and the $C_6H_6{\cdot}ICl$ complex has been investigated through ultraviolet spectrophotometric measurements. The equilibrium constants obtained at room temperature for the formation of $C_6H_6{\cdot}I_2$ complex are 0.090, 0.216 and 0.328$ lmole^{-1}$ in chloroform, cyclohexane and n-hexane, respectively. The corresponding equilibrium constants at room temperature for $C_6H_6{\cdot}ICl$ complex are 0.125, 0.676 and 0.689 $lmole^{-1}.$ These results indicate that the stabilities of the two complexes increase with decreasing dielectric constants of the solvents used, the increase in stability being more rapid in the $C_6H_6{\cdot}ICl$ complex than in the $C_6H_6{\cdot}I_2$ complex. This may support the conclusion that the dative ionic structures, $C_6H_6^+{\cdots}I_2^-$ and/or ($C_6H_6I)^+{\cdots}Cl^-,$ play important roles on the reasonance stabilization of both the $C_6H_6{\cdot}I_2$ complex and the $C_6H_6{\cdot}ICl$ complex, the roles being more important in the latter complex than in the former complex.

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An Analytical Study on the Behavior of Slab Structure Considering the Remodeling (리모델링 공사를 고려한 슬래브 구조물의 거동에 관한 해석적 연구)

  • Choi, Hoon;Joo, Hyung-Joong;Lee, Seung-Sik;Yoon, Soon-Jong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.2
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    • pp.106-112
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    • 2010
  • Due to the improvement and stabilization of the social environment, construction market in the urban region is under shrinking. According, researches to lengthen the service life of the existing building structures are under the way through the remodeling or maintenance of deteriorated structures other than the new constructions. Similar situations are widely discussed in the domestic building construction market and the social importance of the remodeling of the existing building structures is increased. Although the structural stability of the building is uncertain due to the frequent repairing and structural changing, the remodeling works are usually conducted. In general, documents such as drawings and calculations for the design of the deteriorated structure to be remodeled are not kept. Accident at the remodeling site frequently occur because of the lack of thorough understanding of changed situations such as loadings, loading paths, changing of the mechanical properties of material, etc. In this paper, using the finite element analysis method, we investigated the structural behaviors of slab in the remodeling building and the results are applied to remodeling construction, and the appropriateness of the remodeling works are evaluated.

Cancellation of Phase Noise in 1.4 GHz RF Signal Transferred to a Remote Site through 13 km Fiber (13 km 광섬유를 통하여 원격지로 전송된 1.4 GHz RF 신호의 위상잡음 제거)

  • Lee, Won-Kyu;Park, Chang-Yong;Mun, Jong-Chul;Yu, Dai-Hyuk
    • Korean Journal of Optics and Photonics
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    • v.21 no.3
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    • pp.103-110
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    • 2010
  • A fiber-phase-noise compensating system was constructed for a 1.4 GHz reference frequency transferred through a 13-km-long fiber spool. The transfer instability was dependent on the temperature variation of the compensating system. With the room temperature variation stabilized within $0.3^{\circ}C$, the transfer instability was $4.6{\times}10^{-14}$ at 0.8 s of average time and $2.5{\times}10^{-16}$ at 1000 s of average time with the fiber phase noise compensated. However, with the room temperature changed by $3.5^{\circ}C$, the transfer instability was $6.8{\times}10^{-14}$ at 1.2 s of average time and $3.0{\times}10^{-15}$ at 1000 s of average time. From this result, the temperature stability condition for the experimental setup could be determined to obtain a transfer instability of $10^{-16}$ at 1000 s of average time.

Studies in Biomechanical Properties on Brain-spinal Cord Response Mechanism by Human Posture Control Ability (자세조절능력에 따른 뇌-척수 신경 반응기전의 역학적 해석)

  • Yoo, Kyoung-Seok
    • 한국체육학회지인문사회과학편
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    • v.58 no.6
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    • pp.449-459
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    • 2019
  • The purpose of this study is to identify how postural mechanics affects postural control on balance and stability by using frequency analysis technique from the kinematic data acquired during the one leg standing posture. For this purpose, the experimental group consisted of two groups, the normal group (n=6) and the national Gymnastics group (n=6). Displacement data of CoP were analyzed by frequency analysis of rambling (RM) and trembling (TR) by FFT signal processing. As a results, there was a significant difference in evaluating the stabilization index between the two groups with the eyes open and closed one leg stnading (p <.05). The cause of the difference was found to be the output of the maximum amplitude of RM (f1) and TR (f2) (p <.05). In particular, in the low frequency RM of 8-9 Hz, which is a natural frequency of signal wave involved in postural feedback feedback, the main frequency appeared to be performs the exercise mechanism of stable brain posture control. And in the high frequency TM of 120-135 Hz, it is considered that the adaptation of the reflective muscle response is minimized to minimize posture shaking. In conclusion, this study provides evidence for the intrinsic main frequencies according to the postural control ability which affects the CNS in one leg standing.

Effect of Korean Red Ginseng on the Stability of the Tight Junction of Intestinal Epithelial Cells (홍삼에 의한 Caco-2 단세포층 간극의 안정화)

  • Shon, Dong-Hwa;Kim, Mi-Hye;Kim, Young-Chan;Kim, Sung-Soo
    • Korean Journal of Food Science and Technology
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    • v.42 no.3
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    • pp.335-342
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    • 2010
  • Bioactive components involved in the tight junction stabilization of intestinal epithelial cells from Korean red ginseng were studied by analyzing transepithelial electrical resistance (TEER) values of the Caco-2 cell monolayer between the apical and basolateral sides for 96 hr. The treatment with less than $20\;{\mu}g/mL$ of the Korean red ginseng extract to the apical side of Caco-2 cell monolayer gave higher TEER values than the control. However, the treatment with more than $130\;{\mu}g/mL$ of the Korean red ginseng extract drastically decreased the TEER values, and these effects were not due to its cytotoxicity. When fractions of low molecular weight compounds, polysaccharides, proteins, saponins, and polyphenols derived from Korean ginseng were applied to the apical side of the Caco-2 cell monolayer, polyphenols showed high tight junction stabilizing activity and saponins showed low activity, but the others showed no significant activity. These results suggest that Korean red ginseng might be useful for the prevention of food allergy by stabilizing the tight junction of intestinal epithelial cells leading to hindering absorption of food allergens.

Corrosion Stability of Iron Artifacts after Treating with Water Treatment (수처리제를 사용한 철제유물의 부식 안정성 연구)

  • Jeong, Ji Hae
    • Journal of Conservation Science
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    • v.33 no.5
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    • pp.381-390
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    • 2017
  • Desalination is the main focus of the stabilization of iron artifacts. However, drawbacks such as re-corrosion are noted due to the uncertainty in the elimination of the corrosive factors and artifacts. Several studies have been carried out on the effects of corrosion inhibitors to overcome these shortcomings. In this study, the effects of type 3 water treatment on corrosion inhibitors were investigated. Surfaces of samples that contained film corrosion inhibitors on their surfaces were analyzed. The results revealed that the surface rust was removed from the sample of type 1 No. 2 that was mainly composed of phosphate. The average weight reduction rates of re-corrosion samples were 0.58, 0.03, and 0.07% for type 1 No. 2, type 2 No. 2, and type 3 No. 2 respectively. The changes in the $Cl^-$ ion, a corrosive agent were found to be 28.60, -4.08, and -1.94 ppm for type 1 No. 2, type 2 No. 2, and type 3 No. 2 respectively. The water-treated films were analyzed by X-ray photoelectron spectroscopy (XPS). It was found that type 2 No. 2 had less Fe the basis metal, than that in type 3 No. 2 indicating much better film. Moreover, Si content was higher in type 2 No. 2, based on the silicate content, than in type 3 No. 2. They are speculated to be the reason or the formation of a better film. Type 1 No. 2, which is mainly composed of phosphate, would be inappropriate as a metal artifact conservation treatment. It was determined that type 2 No. 2 and type 3 No. 2 water treatments, which are mainly composed of silicate, provided excellent corrosion inhibiting effects. Corrosion inhibitors could be used as emergency treatment agents during the excavation of iron artifacts.

A Study on the Chemical Resistance Performance of Injection Type Leakage Repair Materials used in Crack Parts of Concrete Structures under the Contaminated Groundwater Environment (오염된 지하수 환경 하의 콘크리트 구조물 균열부위에 사용되는 주입형 누수보수재료의 화학저항성능 시험평가 연구)

  • Kim, Soo-Yeon;Yoo, Jae-Yong;Kim, Byung-Il;Oh, Sang-Keun
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.5
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    • pp.411-419
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    • 2019
  • Underground concrete structures are constructed under a geographical environment called underground and exposed to various environments that promote deterioration. Among them, groundwater promotes deterioration of underground concrete structures due to contaminated water from the ground. In this study, the chemical resistance performance test evaluation of five different receptors for a total of 15-type leakage repair materials of five series was conducted to determine the chemical stability of the leakage repair material used in the crack area. The results show a general increase and decrease in most chemical receptors, but the biggest increase and decrease was shown in acrylic systems, which were found in sodium chloride and sodium hydroxide, and epoxy was found in hydrochloric acid. The cement system is showing a lot of increase and decrease in sodium chloride. It is expected that the results of these studies will be used as a basis for chemical stabilization in the development of new materials.

A Study for Automotive Lamp Manufacturing System Control Composing Ultra melting Process (초음파 접합 공정을 합성한 자동차용 램프 생산시스템 제어에 관한 연구)

  • Lee, Il-Kwon;Kook, Chang-Ho;Kim, Seung-Chul;Kim, Ki-Jin;Han, Ki-Bong
    • Journal of the Korean Institute of Gas
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    • v.18 no.1
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    • pp.46-51
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    • 2014
  • The purpose of this paper is to study of the vehicle lamp manufacturing system composing ultrasonic waves connection process. Making lamp assembly plant, it was produced in the separate process as the injection molding, ultrasonic waves bonding, annealing in the constant temperature, lamp assembling and packing. But the improvement method producing the lamp was added with one-step process by one automation technique. As a result, welding with ultrasonic waves process, the method decreased the energy consumption and noise during ultrasonic waves welding. Therefore, this method used the mathematics modeling for checking validity, it selected the stability and suitable controller using transfer function of plant and bode chart. In this study, the $180^{\circ}$ revolution control system to turn injection part upside down was $M_{eq}\;lcos{\theta}(t)$ because of gravity influence. It effected to unstable condition a system. For solving this problem, it aimed the linearization and stabilization of system by elimination $M_{eq}\;lcos{\theta}(t)$ as applying Free-forward control technique.

The Stabilization of Lactic Acid Bacteria, Bacillus polyfermenticus KJS-2 (유산간균인 Bacillus polyfermenticus KJS-2의 안정화)

  • Kim, Kang-Min;Lee, Jin-Young;Hong, Yong-Geun;Lee, Sang-Kil;Kang, Jae-Seon
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.8
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    • pp.1044-1048
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    • 2008
  • Bacillus polyfermenticus KJS-2 (Bp2) was isolated from $Bispan^{(R)}$, a commercially available probiotics consisting of more than 4 strains. The objective of this study was to investigate the effect of three-layer coating on the stabilty of Bp2. Bp2 was microencapsulated with sodium alginate using an air atomizer. The Bp2 loaded pellets were also coated with HFP-chitosan and HPMCP for oral delivery system. When compared to the uncoated Bp2, the survival of the three-layer coated Bp2 increased to approximately 63% (p<0.01) in a 30% ethanol solution, 54% (p<0.05) in an artificial gastric juice (pH 2), and 53% (p<0.05) in the bile acid (pH 5). When coated beads were stored at $100^{\circ}C$ and $130^{\circ}C$, Bp2 in coated beads was very stable (p<0.01) compared to uncoated Bp2.

Full mouth rehabilitation of the patient with worn dentition using full-contour monolithic zirconia prostheses at an increased vertical dimension of occlusion: a case report (치아 마모 환자에서 수직고경 증가를 동반하여 단일구조 지르코니아 보철물로 완전구강회복을 시행한 증례)

  • Oh, Kyung-Chul;Chung, Moon-Kyu;Kim, Jee-Hwan;Shim, June-Sung
    • The Journal of Korean Academy of Prosthodontics
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    • v.50 no.3
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    • pp.198-203
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    • 2012
  • Excessive occlusal wear results in unacceptable damage to the occluding surfaces, and can cause pulpal injury, occlusal disharmony, impaired function, and aesthetic deformity. Patients with severely worn dentition need to be classified as several categories relative to the vertical dimension of occlusion (VDO) and the interocclusal distance for the prosthetic space. When treating patients classified as those who have excessive wear without loss of occlusal vertical dimension but with limited space, we could consider treating them at an increased vertical dimension of occlusion. Treatments at an increased vertical dimension of occlusion may provide stability, given that the amount of its increase was minimal, and a perfected occlusion was achieved after enough stabilization period. A 50-year-old male visited the department of Prosthodontics in Yonsei University Dental Hospital with the chief complaint of worn teeth on lower anterior area. Reconstruction at an increased vertical dimension of occlusion was planned. After the compatibility of the new vertical dimension of occlusion had been confirmed under interim fixed restorations, definitive fixed restorations composed of full-contour monolithic zirconia prostheses were placed. This case presents that a satisfactory clinical result was achieved by restoring the worn dentition at an increased vertical dimension of occlusion with an improvement in esthetics and function.