• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2002년도 제35회 춘계학술대회
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• pp.248-254
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• 2002

The most controversial topics in plasma sprayed ceramic coating system are recently mechanical properties such as bond strength, cohesive strength, toughness and so on. Determination of bond strength of coatings is one of the most important problems. In the industry, the bond strength of coating system has been estimated by Pull-off test(ASTM standard C633-79). But, without a fixed jig and specimen, it is impossible to obtain the bond strength. Therefore, it is necessary to study the critical fracture load on interface of the coating by indentation test. Because the critical fracture load plays an important role in evaluating the bond strength for plasma sprayed ceramic coating system. So, we have estimated critical fracture load in plasma sprayed ceramic coating system, and it was shown that inverse relationship between the cross-section hardness of coating and the critical fracture load(Pc). In case of the high load(1kgf, 2kgf) in $Al_{2}O_{3}+13%TiO_{2}$, it was found that the critical point(Pco), which the coating was broken on.

• 한국축산시설환경학회지
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• 제19권1호
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• pp.19-24
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• 2013

This study is to promote domestic environmentally appropriately conditions for the range 60~70 m, the development of the small and medium-sized sprayer ability measurement that can be used as a general-purpose paddy fields, orchards, and not consolidated areas. The sprayer designed and manufactured that can spraying effectively distance to within 60~70 m. Distribution of sprayed pesticides were obtained and analyzed by measuring the weight. Performance analysed using the buckets were placed horizontally 12.5 m, 70 m vertical intervals by $5m{\times}2.5m$, so total 68 buckets were placed. Total amounts of sprayed quantity was $2,000{\ell}$ and maximum spray distance was about 70 m. Reasonably sprayed region was 5 m~10 m vertically symmetrical. Showed a lot of spraying water in 5 m~40 m distance, and in 45~60 m tended to spraying water decreased slightly. Maximum spraying distance was 70 m.

• 한국구조물진단유지관리공학회 논문집
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• 제18권1호
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• pp.128-137
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• 2014

내화뿜칠재는 주로 철골구조물 위에 시공하여 내화구조기준을 만족하기 위한 것이다. 국내에서는 원자력발전소를 비롯하여 철골구조물에 내화뿜칠재를 시공하여 왔지만, 재료특성 중 중요한 요건인 부착강도기준이 제정되어있지 않았다. 다만, 원자력발전소는 원전의 기준에 따라 부착강도 기준이 있었다. 본 논문에서는 변전소에 시공되는 내화뿜칠재의 부착강도 기준을 정하고자 하였다. 기준설정 방법은 현재 사용되는 제품으로 실험체를 제작하고, 변전소 환경에 따라 열화시키며 부착강도를 측정하고 구조물 내구연한 기간 동안 열화시킨 후 변전소에서 발생하는 충격하중 실험을 통하여 탈락여부를 평가하여 부착강도기준을 설정하였다. 본 논문에서의 부착강도는 시중에서 사용되는 제품을 기준으로 실험한 것으로 최소한의 값이라고 판단된다.

• 동력기계공학회지
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• 제11권1호
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• pp.121-126
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• 2007

This study aims at investigating the effect of heat treatment conditions on the dry sliding wear behavior of thermally sprayed Ni-based self-flux alloy coatings. Ni-based self-flux alloy powders were sprayed onto a carbon steel substrate and then heat-treated at 700, 800, 900 and $1000^{\circ}C$ for 30 minutes in a vacuum furnace. Dry sliding wear tests were performed using sliding speed of 0.4 m/s and applied load of 6 N. AISI 52100 ball(diameter 8 mm) was used as counterparts. Microstructure and wear behavior of both as-sprayed and heat-treated Ni-based self-flux alloy coatings were studied using a scanning electron microscope(SEM), energy dispersive X-ray spectroscopy(EDX), electron probe micro-analysis(EPMA) and X-ray diffraction(XRD). It was revealed that microstructure and wear behavior of thermally sprayed Ni-based self-flux alloy coatings were much influenced by heat treatment conditions.

• Journal of Welding and Joining
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• 제18권5호
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• pp.98-104
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• 2000

Aluminum alloys are being employed in automobile parts as strive to reduce overall vehicle weight to meet demands for improved fuel economy and reduction in vehicle emissions. Al-based composites reinforced with ceramic ($Al_2O_3,\;SiC,\;TiC\;and\;B_4C$) applications in a variety of components in automotive engines, such as liners, where the tribological properties of the material are important. In this study, Al-base composites reinforced with TiC particle powders has been developed for producing plasma spray coatings. The composite plasma spray powders were prepared Al-13Si-3Mg(wt%) alloy with TiC(40, 60 and 80wt%) particles ($0.2~5{\mu}textrm{m}$) by drum type ball milling. The composite powders ($36~76{\mu}textrm{m}$) were sprayed with plasma torch. Plasma sprayed coatings were heat-treated at $500^{\circ}C$ for 3 hours. The wear resistances of the plasma sprayed coatings were found to decrease with increasing TiC content and improved with heat treatment. AlSiMg-40% TiC heat-treated coatings were showed the best wear resistance in this study.

• Journal of Welding and Joining
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• 제18권6호
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• pp.48-54
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• 2000

The corrosion properties of Ni-Cr-W-Mo-B alloy sprayed by the high velocity oxy-fuel spraying (HVOF) was studied as a function of heat treatment by using both potentiodynamic polarization and immersion tests in the H₂SO₄ solution. The mechanical property was also evaluated by a microhardness tester. Microstructural characteristics of te as-sprayed and annealed coatings at 550, 750 and 950℃ have been analyzed by means of OM, XRD, SEM and TEM. The results showed that the corrosion resistance was improved by increasing the annealing temperature. As-sprayed coating had metastable and heterogeneous phases such as amorphous, nanocrystalline and very refined grain and precipitates, which induced a localized corrosion. The localized corrosion occurred preferentially at the unmelted particles which were composed of Ni matrix and Cr, W and Mo riched phase segregated in the boundaries. As annealing temperature was increased, the microstructure had shown some changes - reduction of porosity and s[plat boundary decomposition and crystallization of amorphous/nanocrystalline phases, grain coarsening,, formation and growth of precipitates such as {TEX}$M_{23}C_{6}${/TEX} and {TEX}$M_{7}C_{3}${/TEX}. In addition, the compositional difference between matrix and boundary phases gradually disappeared, which changed the corrosion type from localized corrosion to general corrosion and thus enhanced corrosion resistance.

• 한국진공학회지
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• 제7권s1호
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• pp.171-178
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• 1998

The microstructure and properties of plasma-sprayed coatings depend on a great number of spraying parameters, random factors, which lead to vibration in these spraying parameters, may in some degree influence the microstructure and properties of the coatings. Therefore, the property values appear certain distributions, and the description and comparison of the properties of plasma-sprayed coatings should be performed employing statistical analysis. In this paper, $Cr_3C_2$-Nicr coatings of different thickness were sprayed onto stainless steel using atmosphere plasma system and adopting three kinds of gun translation speeds. Then the microhardness measurements were performed on polished surface of the coatings. Forty readings were taken and statistically analyzed by calculating the characteristic values, estimating and comparing the means, and assessing whether they belonged to the Normal or Weibull Distribution. This study has found that statistical analysis could discriminate influence of spraying parameters and coating design on microhardness of the $Cr_3C_2$-Nicr coatings from random vibration, which showed that the microharness of the $Cr_3C_2$-Nicr coatings were related to gun translation speed coating thickness.

• 한국해양공학회지
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• 제10권2호
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• pp.88-97
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• 1996

The pupose of this study is to improve the mechanical properies and to evaluate the residual stresses of flame-sprayed Alumina ceramic coating layer. The first work in this study is to investigate the effects of strengthening heat treatments on the mechanical properties of coating layer. Strengthening heat treatments for sprayed specimens were carried out in vaccum furnace. The mechanical properties such as microhardness, thermal shock resistance, adhesive strength and erosion resistance were tested for the sprayed specimens after strengthening heat treatments. And it was clear that the mechanical properties of coating layer were much improved by strengthening heat treatments. The second work in this study is to evalute the residual stresses in coating lsyer by numerical analysis. FDM and FEM were used to analyze temperature distribution and residul stresses in coating layer. It was proved that are tensile stresses in coating layer and that residual stresses can be controlled by the appropriate selection of the spraying parameters such as preheat temperature, coating thickness and bond coat thickness.

• 동력기계공학회지
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• 제18권6호
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• pp.58-63
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• 2014

This paper deals with the effects of counterpart materials on the wear behavior of thermally sprayed STS316 coatings. STS316 powders were flame-sprayed onto a carbon steel substrate. Dry sliding wear tests were performed using the applied loads of 15 N. AISI52100, $Al_2O_3$, $ZrO_2$ and $Si_3N_4$ balls were used as counterpart materials. Wear behavior of STS316 coatings against different counterpart materials were studied using a scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDS). The results show that the wear behavior of thermally sprayed STS316 coatings strongly depends on the type of counterpart material. Dominant wear mechanism was similar for all studied materials as failure of adhesion film except for Si3N4 used as counterpart material. In the case of Si3N4 used as counterpart material, dominant wear mechanism was abrasion.

• Journal of Welding and Joining
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• 제15권4호
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• pp.126-135
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• 1997

$H_2/O_2$ 비에 따른 Hybrid HVOF 용사된 $Cr_3C_2$-7wt%(NiCr) 용사층의 특성 및 산화거동 This study was performed to investigate the influence of fuel/oxygen ratio (F/O=3.2, 3.0, 2.8) on the characteristics and the oxidation behavior of the hybrid-HVOF sprayed $Cr_3C_2$-7wt%NiCr coatings. Decomposition and the oxidation of the $Cr_3C_2$was occured during spraying. The degree of transformation from $Cr_3C_2$to $Cr_7C_3$ was increased with decreasing the F/O ratio. The microstructural differences of the as sprayed coating with F/O ratio can not be distinguished, However, large pores were diminished and then the coatings became dense by heat treatment. Microhardness of the as-sprayed specimen which sprayed with F/O=3.0 condition was hightest ($Hv_{300}$=1140) and the hardness was increased to 1500 after heat treatment at $600^{\circ}C$ for 50hrs in air. It was supposed that hardness was increased due to the formation of $Cr_2O_3$ within $Cr_3C_2$/$Cr_7C_3$matrix and the densification of coating layer during heat treatment. Apparent activation energy for oxidation was varied from 21.2 kcal$mol^{-1}K^{-1}$ to 23.8 kcal$mol^{-1}K^{-1}$ with respect to the F/O ratio. The surface morphology was changed to porous and oxide chusters were grown after oxidation $1000^{\circ}C$ for 50 hours by the aggressive evolution of gas phase ($CrO_3$ and$CO_2$). The oxide cluster was composed of Ni and Cr.