• Title/Summary/Keyword: Spontaneous Combustion

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Investigation on the Self-ignition of High-pressure Hydrogen in a Tube between Different Inner Diameter (튜브 직경에 따른 고압 수소의 자발 점화 현상에 대한 연구)

  • Kim, Sei Hwan;Jeung, In-Seuck;Lee, Hyoung Jin
    • Journal of the Korean Society of Combustion
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    • v.23 no.1
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    • pp.36-43
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    • 2018
  • Numerical simulations and experiments are performed to investigate the flame development inside tubes with different diameters at the same burst pressure. It is shown that generation of a stable flame play a role in self-ignition. In the smaller tube, multi-dimensional shock interaction is occurred near the diaphragm. After flame of a cross-section is developed, stable flame remains for a moment then it grows having enough energy to overcome the sudden release at the exit. Whereas shock interaction generate complex flow further downstream for a larger tube, it results in stretched flame. This dispersed flame has lower average temperature which makes it easily extinguished.

A DNS Study of Ignition Characteristics of Lean PRF/Air Mixtures under HCCI Conditions (HCCI 조건에 일어나는 희박 PRF/공기 혼합물의 점화특성에 관한 직접수치모사 연구)

  • Luong, Minh Bau;Yoo, Chun Sang
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.153-156
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    • 2012
  • Direct numerical simulations (DNSs) of ignition of lean primary reference fuel (PRF)/air mixtures under homogeneous charge compression ignition (HCCI) conditions are performed using 116-species reduced chemistry. The influence of variations in the initial temperature field, imposed by changing the variance of temperature, and the fuel composition on ignition of lean PRF/air mixtures is studied using the displacement speed analysis.

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An Experimental Study on Expansion of Operation Range by Lean Boosting for a HCCI H2 Engine (희박과급에 의한 수소 예혼합 압축착화 기관의 운전영역 확장에 관한 실험적 연구)

  • Ahn, Byunghoh;Lee, Jonggoo;Lee, Jongmin;Lee, Jongtai
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.6
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    • pp.573-579
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    • 2013
  • Hydrogen engine with homogeneous charged compression ignition can achieve high efficiency by high compression ratio and rapid chemical reaction rates spatially. However, it needs to expansion of the operation range with over-all load conditions which is very narrow due to extremely high pressure rise rate. The adoption of the lean boosting in a HCCI $H_2$ engine is expected to be effective in expansion of operation range since minimum compression ratio for spontaneous ignition is decreased by low temperature combustion and increased surround in-cylinder pressure. In order to grasp its possibility by using lean boosting in the HCCI $H_2$ engine, compression ratio required for spontaneous ignition, expansion degree of the operation range and over-all engine performance are experimentally analyzed with the boosting pressure and supply energy. As the results, it is found that minimum compression ratio for spontaneous ignition is down to the compression ratio(${\varepsilon}$=19) of conventional diesel engine due to decreased self-ignition temperature, and operation range is extended to 170% in term of the equivalence ratio and 12 times in term of the supply energy than that of naturally aspirated type. Though indicated thermal efficiency is decreased by reduced compression ratio, it is over at least 46%.

Simultaneous Synthesis and Sintering of Titanium Carbide by HPCS(High Pressure-Self Combustion Sintering) (고압연소 소결(HPCS)법에 의한 탄화티타늄(TiC)의 합성 및 소결)

  • 김지헌;최상욱;조원승;조동수;오장환
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.473-482
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    • 1997
  • Titanium carbide(TiC) has a poor sinterability due to the strong covalent bond. Thus, it is generally fabricated by either hot pressing or pressureless-sintering at elevated temperature by the addition of sintering aids such as nickel(Ni), molybdenum(Mo) and cobalt(Co). However, these sintering methods have the following disadvantages; (1) the complicated process, (2) the high energy consumption, and (3) the possibility of leaving inevitable impurities in the product, etc. In order to reduce above disadvantages, we investigated the optimum conditions under which dense titanium carbide bodies could be synthesized and sintered simultaneously by high pressure self-combustion sintering(HPCS) method. This method makes good use of the explosive high energy from spontaneous exothermic reaction between titanium and carbon. The optimum conditions for the nearly full-densification were as follows; (1) The densification of sintered body becomes high by increasing the pressing pressure from 400kgf/$\textrm{cm}^2$ upto 1200 kgf/$\textrm{cm}^2$. (2) Instead of adding the coarse graphite or activated carbon, the fine particles of carbon black should be added as a carbon source. (3) The optimum molar ratio of carbon to titanium (C/Ti) was unity. In reality, titanium carbide body which were prepared under optimum conditions had relatively dense textures with the apparent porosity of 0.5% and the relative density of 98%.

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Low-temperature Synthesis of (TiC+Al2O3) Reinforced Al Matrix Composite Based on Self-combustion Reaction (자발연소반응을 이용한 (TiC+Al2O3)/Al 복합재료의 저온합성)

  • Lee, Jung-Moo;Kim, Su-Hyeon;Cho, Young-Hee;Kim, Je-Woo;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.1001-1004
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    • 2011
  • The formation of TiC and $Al_2O_3$ particles based on the self-combustion reaction of the $Al-TiO_2-C-CuO$ system in an Al alloy melt was investigated. With an adequate amount of CuO in the system, a spontaneous reaction occurred within the Al alloy melt at $850^{\circ}C$ and thereafter was self-maintained, producing an Al matrix composite reinforced with thermodynamically stable TiC and $Al_2O_3$ particles. TiC and $Al_2O_3$ particles contributed to a considerable increase in the strength and stiffness, demonstrating the feasibility of this method as a practical application for structural parts.

Experimental Study on the Spontaneous Ignition of Corn Oil Adsorbed on Towels (타올에 흡착된 반건성유인 옥수수유의 자연발화에 대한 실험적 연구)

  • Kim, Kyoung-Su;Choi, Yu-Jung;Yoo, Sam-Yeol;Jeong, Phil-Hoon;Choi, Jae-Wook
    • Journal of the Society of Disaster Information
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    • v.18 no.3
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    • pp.574-580
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    • 2022
  • Purpose: As corn oil is semi-drying oil, it has more double bonds than non-drying oil and is easier to combine with oxygen. In addition, among the causes of spontaneous ignition, accidents caused by oil-soaked cloths due to oxidative heat are gradually increasing. Therefore, the purpose of this study is to understand the characteristics of spontaneous combustion according to the number of towels and the amount of corn oil at 65℃. Method: After setting the test temperature to 65℃, 25ml, 50ml, 75ml of corn oil per towel was sprayed. The central temperature of the sample rises above the set temperature. It was determined, and when the central temperature of the sample became similar to the set temperature, it was determined as non-igniting. Result: After evenly distributing 25ml of corn oil per towel, as a result of the experiment, 5 towels did not ignite, and 10 and 15 towels ignited. Also, as a result of an experiment using 50ml and 75ml of corn oil per towel, spontaneous ignition occurred when the number of towels was 5, 10, or 15 sheets. Conclusion: Even a small amount can cause a fire if the conditions for spontaneous ignition are met.

Research on Overheating Prediction Methods for Truck Braking Systems (화물차의 제동장치에서 발생하는 과열 예측방안 연구)

  • Beom Seok Chae;Young Jin Kim;Hyung Jin Kim
    • Smart Media Journal
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    • v.13 no.6
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    • pp.54-61
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    • 2024
  • Recently, due to the increase in domestic and international online e-commerce platforms and the increase in container traffic at domestic ports, the operating ratio of large trucks has increased, and the number of truck fires is continuously increasing. In particular, spontaneous combustion is the most common cause of truck fires. Various academic approaches have been attempted to prevent truck fires, but due to the lack of research on the spontaneous tire ignition phenomenon that occurs during braking, this research directly designed and manufactured an experimental device to establish an environment similar to the braking system of a truck. A non-contact temperature sensor was installed on the brake device of the experimental device to collect temperature data generated from the brake device. Based on the data collected from the temperature sensor of the brake device and the temperature sensor on the tire surface, the ARIMA model among the time series prediction models was used to Appropriate parameters were selected to suit the temperature change trend, and as a result of comparing and analyzing the measured and predicted data, an accuracy of over 90% was obtained. Based on this, a plan was proposed to reduce the rate of fires in trucks by providing real-time warnings and support for truck drivers to respond to overheating phenomena occurring in the braking system.

A Study on the Stability of Rich/Lean Methane Premixed Flame (과농/희박 메탄 예혼합화염의 안정성에 관한 연구)

  • Lee, Won-Nam;Seo, Dong-Kyu
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.2
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    • pp.170-177
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    • 2005
  • The fuel-lean premixed flame has been considered one of the most efficient ways to reduce $NO_X$ emission during a combustion process. However, it is difficult to achieve stable fuel-lean premixed flames over the wide range of equivalence ratios: therefore, the application of fuel-lean flames to a practical combustion system is rather limited. In this study, the stability characteristics of fuel-lean flames stabilized by fuel-rich flames are investigated experimentally using a slot burner as a part of the basic research for practical application such as lean burn engines. Spontaneous emission of radical species were examined to understand the stability mechanisms of rich-lean premixed flames. The presence of fuel-rich flames could significantly lower the lean limit of fuel-lean flames. The stability of a fuel-lean flame is enhanced with the increase of fuel flow rate in a fuel-rich flame; how ever, it is not sensitive to the equivalence ratio of fuel-rich flames in the range of 1.2-2.4. The mechanisms of stable rich-lean premixed flames could be understood based on the characteristics of triple flame.

Surface Characteristics and Spontaneous Combustibility of Coal Treated with Non-polar Solvent under Room Temperature (상온에서의 용매 처리를 통한 저등급 석탄의 표면물성 및 자연발화 특성 변화)

  • Jo, Wan Taek;Choi, Ho Kyung;Kim, Sang Do;Yoo, Ji Ho;Chun, Dong Hyuk;Rhim, Young Joon;Lim, Jeong Hwan;Lee, Si Hyun
    • Korean Chemical Engineering Research
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    • v.51 no.5
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    • pp.609-614
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    • 2013
  • This study investigated the spontaneous combustion behavior of solvent-treated low rank coals. Indonesian lignite (a KBB and SM coal) and sub-bituminous (a Roto coal) were mixed with non-polar 1-methyl naphthalene (1MN) either by mechanical agitation or ultrasonication. The property change associated with 1MN treatment was then analyzed using proximate analysis, calorific value analysis, Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy and moisture re-adsorption test. Susceptibility to spontaneous combustion was evaluated using crossingpoint temperature (CPT) measurement along with gas analysis by GC. A FT-IR profile showed that oxygen functional groups and C-H bonding became weaker when treated by 1 MN. XPS results also indicated a decrease of the oxygen groups (C-O-, C=O and COO-). Increased hydrophobicity was found in the 1MN treated coals during moisture readsorption test. A CPT of the treated coals was ${\sim}20^{\circ}C$ higher than that of the corresponding raw coals and the ultrasonication was more effective way to enhance the stability against spontaneous combustion than the agitation. In the gas analysis less CO and $CO_2$ were emitted from 1MN treated coals, also indicating inhibition of pyrophoric behavior. The surface functional groups participating in the oxidation reaction seemed to be removed by the ultrasonication more effectively than by the simple mechanical agitation.

Numerical Study on Ignition Delay Time of CH4 as CO/H2 Addition in MILD Combustion (MILD 연소 환경에서 CO/H2 첨가에 따른 CH4의 점화 지연 시간의 해석적 연구)

  • Kim, Donghee;Huh, Kang Y.;Lee, Youngjae
    • Journal of the Korean Institute of Gas
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    • v.25 no.2
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    • pp.1-12
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    • 2021
  • MILD(Moderate or Intense Low-oxygen Dilution) combustion has attracted attention as the clean thermal energy technology due to the lower emissions of unburnt carbon and NOx. MILD combustion aims to enlarge the combustion reaction zone using the spontaneous ignition phenomenon of the reactants. In this study, the ignition delay time of CH4 according to the initial temperature of reactants and the addition of CO, H2 was investigated using a numerical approach. Ignition delay time became shorter as the increases of initial temperature and H2 addition. But, CO addition to the fuel increase the ignition delay time. In case of H2 addition to the fuel, the ignition delay time decreased because the higher fraction of HO2 promotes the decomposition of methyl radical(CH3) and produce OH radical. However, in case of CO addition to the fuel, ignition delay time inceased because a high proportion of HCO consumes H radical. There was no significant effect of HCO on the reduction of ignition delay time. Also, the increase rates of NO emissions by the addition of CO and H2 were approximately 7% and 1%, respectively. A high proportion of NCO affects the increase in NO production rate.