• Title/Summary/Keyword: Spinning Effect

Search Result 205, Processing Time 0.029 seconds

The Effect of Dissolution Condition on the Yield, Molecular Weight, and Wet- and Electro-spinnability of Regenerated Silk Fibroins Prepared by LiBr Aqueous Solution

  • Cho, Hee-Jung;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
    • /
    • v.20 no.2
    • /
    • pp.99-105
    • /
    • 2010
  • In this paper, the regenerated silk fibroins were dissolved in LiBr aqueous solution with different dissolution temperature and time, and the effects of the dissolution condition on the regeneration yield, molecular weight, wet spinnability, and electrospinnability of regenerated silk fibroin were investigated. The regeneration yield, molecular weight distribution, and wet spinnability of regenerated silk fibroin were nearly affected by the dissolution temperature and time. However, the electrospinning performance of silk fibroin was influenced by the dissolution condition implying the electrospinning of silk fibroin is more sensitive process than the wet spinning in the range tested in this study. While $25^{\circ}C$ of dissolution temperature resulted in a good electrospinnability of regenerated silk fibroin, the electrospinnability was slightly deteriorated when silk fibroin was dissolved at $60^{\circ}C$ for 6 hours. Also, though the fiber diameters of electrospun silk fibroin produced by the dissolution at $25^{\circ}C$ for 6 hours and 24 hours were 443 and 451 nm, respectively, that at $60^{\circ}C$ for 5 min was reduced to 411 nm. The fiber diameter was more decreased to 393 nm when the dissolution time increased up to 6 hours at $60^{\circ}C$.

Effect of Thermal Pressing Temperature on the Mechanical and Material Properties of Electro-spun Polyacrylonitrile Nano-fibrous Separator (열압착 온도가 전기방사 Polyacrylonitrile 분리막의 기계적 강도 및 물성치에 미치는 영향)

  • Kim, Minchoel;Ko, Tae Jo;Arifeen, Waqas Ul;Dong, Ting
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.18 no.4
    • /
    • pp.109-116
    • /
    • 2019
  • The mechanical deformation of a battery separator causes internal short-circuiting of the cathode - anode, which directly affects the explosion/ignition of batteries. To increase the mechanical properties of the separator fabricated by electro-spinning, use of a thermal pressing method is inevitable. Therefore, this research aims to maximize the mechanical strength of a porous separator by finding the proper thermal press temperatures given to Electro-spun Polyacrylonitrile (PAN) nanofibers. The different thermal press temperatures $25^{\circ}C$, $50^{\circ}C$, $75^{\circ}C$, and $100^{\circ}C$ were applied to the electro-spun fiber at 30 MPa pressure for one hour. The higher the temperature, the higher the resultant tensile strength; however, a higher temperature also lowered the strain and porosity. Thus, the membrane thermal pressed at $50^{\circ}C$ showed the best mechanical properties and the second highest porosity. Using the data, $50^{\circ}C$ was judged as the best thermal pressing temperature in terms of performance.

Response of rotational parameter in the stagnation point with motile microorganism: Unsteady nanofluid

  • Mohamed A. Khadimallah;Imene Harbaoui;Sofiene Helaili;Abdelhakim Benslimane ;Humaira Sharif ;Muzamal Hussain;Muhammad Nawaz Naeem;Mohamed R. Ali;Aqib Majeed;Abdelouahed Tounsi
    • Advances in concrete construction
    • /
    • v.15 no.4
    • /
    • pp.241-249
    • /
    • 2023
  • The unsteady mixed convection Casson type MHD nanofluid flow in the stagnation point with motile microorganism around a spinning sphere is investigated. Time dependent flow dynamics is considered. Similarity transformations have been employed to transfer the governing partial differential structure into ordinary differential structure. The impact of distinct parameters is examined via tables and graphs. The impact of rotational parameter (spin) on profiles of velocity profiles, temperature and concentration is revealed for unsteady mixed convection Casson type MHD nanofluid flow. It is observed that it is clear that rotational parameter has a great effect on non-dimensional primary velocity component but rotational parameter has a slight impact on non-dimensional secondary velocity component. The validity of the current investigation is authorized through comparing the existing outcomes with previous published literature.

Evaluation of the Effect of Flocculator Rotation Direction in Floccualation Basin on Hydrodynamic Behavior using CFD (CFD를 이용한 플록큐레이터 회전방향에 따른 플록형성지 유동 평가)

  • Cho, Young-Man;Yoo, Soo-Jeon;Roh, Jae-Soon;Kim, taek-Jun;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.31 no.5
    • /
    • pp.364-370
    • /
    • 2009
  • With time, the stable management of turbidity is becoming more important in the water treatment process. So optimization of flocculation is important for the improvement of the sedimentation efficiency. we evaluated the hydrodynamic behavior in the rotation direction (clock-wise, counterclock-wise) of the flocculator in the flocculation basin using Computational Fluid Dynamics (CFD). The results of the CFD simulation, in cases where flocculators rotate in a clockwise direction, a stronger flow is formed near the surface of the water where the rotating direction and current of flow correspond. The variance and standard deviation of the flux are about 8.5 and 2.9 respectively. In contrast, in the case of a counterclockwise direction, a stronger flow is formed near the bottom of the basin. The variance and standard deviation of the flux are about 5.3 and 2.3, respectively. The effluent flux is affected more by the third flocculator spin than the first and second flocculator spins. The third flocculator spinning in the counterclockwise direction is better for the uniform flow of the sedimentation basin than the third flocculator spinning in the clockwise direction

Measurement of Isoelectric Point of Betaine Zwitterionic Surfactant by QCM(Quartz Crystal Microbalance) (QCM(Quartz Crystal Microbalance)을 이용한 Betaine 양쪽성 계면활성제의 등전점 측정)

  • Kim, Ji Sung;Park, Jun Seok;Lim, Jong Choo
    • Korean Chemical Engineering Research
    • /
    • v.47 no.1
    • /
    • pp.31-37
    • /
    • 2009
  • A zwitterionic surfactant shows not only detergency but also mildness effect since it shows characteristics of a nonionic or an anionic surfactant above an isoelectric point, while showing characteristics of a cationic surfactant below an isoelectric point. Therefore, a zwitterionic surfactant can serve as a dual function surfactant by a single molecule through the interconversion of cleaning and softening effects depending on pH variations of the aqueous solution. In this study, physical properties of betaine surfactant such as CMC, surface tension, interfacial tension, contact angle and viscosity were measured and phase behavior study was performed. Also dual function characteristics of betaine zwitterionic surfactant were investigated by measuring an isoelectric point using QCM(quartz crystal microbalance) and zeta potential measurement. The CMC of betaine surfactant was near $10^{-4}mol/L$ and the surface tension at CMC was about 32 mN/m. The interfacial tension between 1 wt% aqueous solution and n-decane measured by spinning drop tensiometer at pH 2~10 resulted in an increase in interfacial tension until pH 5 and a decrease with pH after 5 and equilibration time showed the similar trend with an increase in pH. The isoelectric point of betaine surfactant measured by QCM experiment was found to exist between 3.0 and 3.3, which is the same as the result determined by zeta potential measurement.

CNT-BASED FIELD EMISSION X-RAY SOURCE

  • Kim, Hyun Suk;Lee, Choong Hun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.433-433
    • /
    • 2016
  • Carbon nanotubes (CNT) emitter has widely become an attractive mechanism that draws growing interests for cold cathode field emission. CNT yarns have demonstrated its potential as excellent field emitters. It was demonstrated that a small focal spot size was achieved by manipulating some electrical parameters, such as applied bias voltage at the mesh gate, and electrostatic focal lenses, geometrical parameters, such as axial distances of the anode, and the electrostatic focal lens from the cathode assembly, and the dimension of the opening of the electrostatic lens. Electrical-optics software was used to systematically investigate the behavior of the electron beam trajectory when the aforementioned variables were manipulated. The results of the experiment agree with the theoretical simulation results. Each variable has an individual effect on the electron beam focal spot size impinging on the target anode. An optimum condition of the parameters was obtained producing good quality of X-ray images. Also, MWCNT yarn was investigated for field emission characteristics and its contribution in the X-ray generation. The dry spinning method was used to fabricate MWCNT yarn from super MWCNTs, which was fabricated by MW-PECVD. The MWCNT yarn has a significant field emission capability in both diode and the triode X-ray generation structure compared to a MWCNT. The low-voltage-field emission of the MWCNT yarn can be attributed to the field enhancing effect of the yarn due to its shape and the contribution of the high-aspect-ratio nanotubes that protrude from the sides of the yarn. Observations of the use of filters on the development of X-ray images were also demonstrated. The amount of exposure time of the samples to the X-ray was also manipulated. The MWCNT yarn can be a good candidate for use in the low voltage field emission application of X-ray imaging.

  • PDF

Effect of quenching rate and crystallization behavior on the magnetic properties of annealed Nd-Fe-B ribbons (Melt-spun Nd-Fe-B 리본의 자기적 특성에 미치는 급속응고속도 및 결정화 거동의 영향)

  • 이경섭;서수정
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.8 no.4
    • /
    • pp.655-659
    • /
    • 1998
  • The effect of quenching speed of melt-spinning on intrinsic coercivity ($_iH_c$$) of annealed ribbons and the crystallization behavior from amorphous $Nd_{14.73}Fe_{78.67}B_{6.60}$ alloy have been studied. We have found that the intrinsic coecivity for annealed melt-spun ribbon is reduced with increasing of quenching rate. $\alpha$-Fe and $Fe_3B$ were formed as intermediate phases prior to the formation of $Nd_2Fe_{14}B$ phase during crystallization. The $Fe_3B$ is disappeared with crystallization of $Nd_2Fe_{14}B$ phase. But the $\alpha$-Fe phase is retained in fully crystallized ribbon by annealing. The intrinsic coercivity loss of annealed ribbon with increasing of quenching speed is believed to be due to existence of soft magnetic phase $\alpha$-Fe in annealed ribbons.

  • PDF

Effect of Insect Growth Regulators on Development and Physiology of the Silkworm, bombyx mori, L. I. Effect of fenoxycarb, juvernile hormone Analog, on larval growth, pupation and cocoon characters by oral application (곤충성장조절제(IGR)가 누에의 발육생리에 미치는 영향 I. Fenoxycarb가 누에의 유충기 발육과 용화에 미치는 영향)

  • 김삼은;황석조
    • Journal of Sericultural and Entomological Science
    • /
    • v.37 no.2
    • /
    • pp.121-126
    • /
    • 1995
  • The effects of oral application of fenoxycarb, the commercial formulation Insegar, to the selected developmental stages of the silkworm, Bombyx mori, was investigated. An oral application of the chemical to the silkworm from the 2nd- to the 5th-instar larvae delayed the larval development upto more than 40 days and increased the larval body weight in the range of 1.1 to 1.7 folds. When the chemical was orally applied to the final instar larvae, spinning and pupation were prevented, and consequently permanent larvae occurred. The weight of a cocoon and its shell of silkworm(bombyx, mori, L) increased following the application of fenoxycarb to the 2nd- and the 3rd-instar larvae.

  • PDF

The Effects of Washing and Drying on the Dimensional Stability of Woven Fabrics with and without Spandex (세탁 및 건조과정에 의한 스판덱스 혼방 직물의 변형 비교)

  • Yun, Changsang;Ko, Yerin;Song, Gyeong Hee;Shin, Hyodam;Park, Chung Hee
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.41 no.3
    • /
    • pp.458-467
    • /
    • 2017
  • There is increased interest in clothes dryers and garments made of spandex-blend woven fabrics; however, there is limited information available for the laundering and drying these clothes. This study investigates the effects of washing and drying on shrinkage, skewness, and wrinkle for woven fabrics with and without spandex. When spandex with good elastic recovery was blended, the deformed shape from washing and drying improved skewness and wrinkle by easily returning to its original shape. However, these properties had a negative effect on shrinkage in terms of length and area change. When the influence of clothes maintenance was classified, the drying process had the biggest influence of 58%, followed by spinning-rinsingwashing. Tumble drying, in which the fabric is exposed to mechanical force and heat for a long period, had more negative effects on the dimensional stability than line drying. The spandex blend had the effect of preventing skewness and wrinkle in garments, but it was also shown to accelerate shrinkage by garment maintenance cycles. It was important to control drying in order to reduce shrinkage during the maintenance process; consequently, this had the greatest influence on the dimensional stability of fabrics. Therefore, line drying was more advantageous for spandex-blend fabrics than tumble drying in terms of management for shrinkage, skewness, and wrinkle.

Study on the Quality Development of Flax Fiber Yarns(I) ―Effects on the Scouring Methods― (아마섬유 방적사의 품질고급화에 대한 연구(I) -정련방법에 대한 영향-)

  • Jeon, Han Yong;Lee, Young Mi;Choi, Chang Nam;Yoo, Dong Il;Lee, Chang Heon;Kook, Yoon Hwan
    • Textile Coloration and Finishing
    • /
    • v.8 no.1
    • /
    • pp.64-72
    • /
    • 1996
  • To develop a scouring method for the high-grade quality and the high value added of flax for spinning, it was measured and analyzed weight loss and degree of injury with change of scouring concentration, time, temperature and pH. We got the f ollowing results; Firstly, in case that flax was scoured at a fixed condition, the weight loss and degree of injury of scoured flax under the no-cutting condition were lower than that of scoured flax under the cutting condition. Secondly, when flax was scoured with $Na_{2}CO_{3}$, it was obtained that the higher weight loss and degree of injury and weight loss with the increase of scouring time and condition. The degree of injury was lower than any other under the treatment condition of 4% $Na_{2}CO_{3}$concentraion for 2 hours. Finally, when alkaline scoured flax was rescoured by pectinase, enzyme activation effect was the most active under the treatment condition of pH 4 for 2 hours. The scouring effect was better than that of alkaline scouring only.

  • PDF