• Journal of the Korean Ceramic Society
• /
• v.33 no.11
• /
• pp.1245-1252
• /
• 1996

The charcteristics for the copper-contained spinel ferrites such as NiCu-and ZnCu ferrites with various copper content are investigated in this study which can provide a explanation for the behavior of copper in sintering at a low temperatuer. The bulk density and the grain size for these sintered ferrites were increased with the larger amount of copper in compositions. In microstructure of copper-contained spinel ferrites copper exists in the grain boundary which is sintering process. Electrical resistivity and frequency range with maximum Q-facor of NiCu-or ZnCu ferrites were decreased as increasing of copper content in ferrite composition.

• Journal of Magnetics
• /
• v.16 no.2
• /
• pp.134-139
• /
• 2011

Magnetic properties of highly zinc-substituted manganese ferrites are discussed on the basis of cation distribution. High throughput neutron powder diffractometry indicates that the prepared samples possess a nearly normal spinel structure, where the substitution of nonmagnetic zinc ions mainly causes the dilution of magnetic ions in the A-sublattice and consequently affects bond-randomness in the B-sublattice. On the other hand, the estimated occupancy of manganese ions in the B site indicates that random anisotropy effects due to local Jahn-Teller distortions gradually weaken with the substitution. Bulk magnetometry indicates that the substitution smears the transition from a paramagnetic phase to a soft-magnetic phase. Furthermore, at lower temperatures, such a soft-magnetic phase is destabilized and a magnetic glassy state appears. These features of the magnetic properties of dilute spinel ferrites are discussed from the viewpoint of the above-mentioned various types of disorders.

• Journal of the Korean Ceramic Society
• /
• v.39 no.12
• /
• pp.1119-1123
• /
• 2002

Nanostructured spinel NiZn ferrites were prepared by the sol-gel method from metal nitrate raw materials. Analyses by X-ray diffraction and scanning electron microscopy showed the average particle size of NiZn ferrite was under 50 nm. The single phase of NiZn ferrites was obtained by firing at 250${\circ}C$, resulting in nanoparticles exhibiting normal ferrimagnetic behavior. The nanostructured $Ni_{1-X}Zn_XFe_2O_4$ (x=0.0∼1.0) were found to have the cubic spinel structure of which the lattice constants ${\alpha}_2$ increases linearly from 8.339 to 8.427 ${\AA}$ with increasing Zn content x, following Vegard's law, approximately. The saturation magnetization $M_s$ was 48 emu/g for x=0.4 and decreased to 8.0 emu/g for higher Zn contents suggesting the typical ferrimagnetism in mixed spinel ferrites. Pure NiZn ferrite phase substituted by Cu was observed before using the additive but hematite phase was partially appeared at $Ni_{0.2}Zn_{0.2}Cu_{0.6}Fe_2O_4$. On the other hand, the hematite phase in this NiZn Cu ferrite was disappeared after using the additive of acethyl aceton with small amount. The saturation magnetization Ms of $Ni_{0.2}Zn_{0.8-y}Cu_yFe_2O_4$(y=0.2∼0.6) as measured was about 51 emu/g at 77K and 19 emu/g at room temperature, respectively.

• Journal of the Korean Ceramic Society
• /
• v.14 no.2
• /
• pp.78-81
• /
• 1977

The effects of variation in composition and the addition of small amount of the rare-earth oxides La2O3, CeO2 and Sm2O3 on the magnetic properties of Mn-Zn system ferrites, 0.5MnO.0.5ZnO.(1＋0.1X) Fe2O3(X=-1, 0, 1, 2), were investigated in the range of frequencies of 0.1~100 kHz. It was shown that the magnetic permeability of the specimens with the composition Mn 0.5 Zn 0.5 Fe2O4 was maximum in the Mn-Zn system ferrites, and that the addition of a small amount of the rare-earth oxides to the composition 0.5 MnO.0.5ZnO.0.9 Fe2O3 caused the sharp increase of magnetic permeability and the decrease of the loss factors.

• Journal of the Korean Ceramic Society
• /
• v.31 no.1
• /
• pp.62-68
• /
• 1994

It is compared the structures of the S-block in the Ba-Co-Zn Y-type hexagonal ferrites (Ba2Co2-xZnxFe12O22, x=0~2) and the Co-Zn spinel ferrites (Co1-xZnxFe2O4, x=0~1) expressed by a hexagonal axis system (space group R3m). The structures have been refined with a Rietveld analysis of the powder X-ray diffraction pattern with high precision (Rwp<0.13, RI<0.03). The overal dimension of the S-block is slightly different from the 1/3 of a hexagonal spinel unit cell as follow: 1.6~2.0% longer c-axis, 1.3~1.6% shorter a-axis and about 1% smaller volume. Upto Zn:Co=1:1 in the Ba-Co-Zn Y-type hexagonal ferrites, the zinc substitute primarily the tetrahedral sites in the S-block. Beyond that the zinc seems to go into the T-block as well.

• Journal of the Korean Magnetics Society
• /
• v.3 no.3
• /
• pp.173-178
• /
• 1993

We have calculated the reduced spontaneous magnetization in different environments and average value as func¬tion of reduced temperature of the magnetic ions(Fe) for A(tetrahedral) and B(octahedral) sites in spinel ferrites $AB_{2}O_{4}$ using A-O-B superexchange interaction. The reduced spontaneous magnetization and average value by A-O-B superexchange interaction are compared with that by A-B direct interaction. To contrast A-O-B superexchange interaction with A-B direct interaction, $M\"{o}ssbauer$ spectra from previous two interactions are obtained.

• Applied Chemistry for Engineering
• /
• v.22 no.2
• /
• pp.185-189
• /
• 2011

In this work, nano-sized M-ferrites (M=Co, Ni, Cu, Zn) for the decomposition of carbon dioxide were synthesized by the chemical co-precipitation. From the thermogravimetric analysis, it was clear that the maximum weight loss of each sample took place below $350^{\circ}C$. High temperature calcination resulted in more systematic crystallines, smaller specific surface area and larger particle size. An analysis by FTIR in the range of $375{\sim}406cm^{-1}$ revealed the presence of chelates at the octahedral site, which implies the formation of spinel structure in the ferrites. The current work showed that a $500^{\circ}C$ is the optimum heat treatment temperature of metal ferrites for $CO_2$ decomposition reaction.

• Proceedings of the Korean Magnestics Society Conference
• /
• 2007.05a
• /
• pp.52.1-52.1
• /
• 2007

• Proceedings of the Korean Ceranic Society Conference
• /
• 2000.10a
• /
• pp.30.2-30
• /
• 2000

• Proceedings of the Korean Ceranic Society Conference
• /
• 2002.10a
• /
• pp.152.1-152
• /
• 2002