• Title/Summary/Keyword: Spin Rate

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Detection of Radiation Degradation of LDPE by ESR Spectroscopy (전자스핀공명을 이용한 저밀도 폴리에틸렌의 방사선 열화 검지)

  • Kim Ki-Yup;Lee Chung;Ryu Boo-Hyung
    • Journal of the Korean Society of Safety
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    • v.20 no.1 s.69
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    • pp.81-86
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    • 2005
  • This study has investigated radiation degradation of low density polyethylene(LDPE). Samples were irradiated up to 800kGy using a $Co^{60}\;\gamma-ray$ at a dose rate of 5kGy/hr in the presence of air atmosphere at room temperature. After irradiation, storing for 2 weeks, free radical measurement of LDPE has established by electron spin resonance(ESR). ESR measurement showed that free radical concentration(FRC) was increased with radiation dose and decreased with the time. The radical types showed alkyl, allyl, and peroxy radical with the irradiation, these changed to peroxy radical with the time.

APPLICATION OF ALANINE/ESR SPECTRUM SHAPE CHANGE IN GAMMA DOSIMETRY

  • Choi, Hoon;Kim, Jeong-In;Lee, Byung-Ill;Lim, Young-Ki
    • Nuclear Engineering and Technology
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    • v.42 no.3
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    • pp.313-318
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    • 2010
  • Alnine pellets were installed in a nuclear power plant for one or two operation cycles and measured by electron spin resonance (ESR) spectrometers for dosimetry. Dose and "x/y ratio", i.e., satellite peak over main center peak ratio, were measured for the returned alanine dosimeters from the nuclear power plant and compared to the values of reference alanine dosimeters exposed only to gamma rays. The variation of the x/y ratio change depended on the population of radicals from each radiation component with different LET. The gamma dose in a mixed radiation field was estimated by an additive gamma ray irradiation experiment and the measured dose rate at specified locations in the containment building.

Synthesis and Shuttling Behavior of Rotaxanes Consisting of Crown Ether Wheel and Disulfide Dumbbell with Two Ammonium Centers

  • Furusho, Yoshio;Sanno, Ryoko;Oku, Tomoya;Takata, Toshikazu
    • Bulletin of the Korean Chemical Society
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    • v.25 no.11
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    • pp.1641-1644
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    • 2004
  • Several [2]- and [3]rotaxanes bearing some functional groups on their wheel components and spacers with different lengths between two ammonium centers on their dumbbell components were prepared in good yields from dibenzo-24-crown-8-ether derivatives and dumbbell-shaped bis(sec-ammonium salt)s having a centrally located disulfide linkage, by utilizing the reversible thiol-disulfide interchange reaction. The shuttling behaviors of the [2]rotaxanes were investigated by $^1H$ NMR by use of the spin polarization transfer-selective inversion recovery technique. It was found that the change in spacer length in the axle resulted in a drastic change in shuttling rate of the [2]rotaxanes, although the introduction of the functional groups to the wheels did not affect the shuttling behavior at all.

A study on the Etching and electrical Properties of PZT Thin Films (PZT(53/47) 박막의 식각 및 전기적 특성에 관한 연구)

  • 김경태;이성갑;이영희;김창일
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.39-42
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    • 2000
  • The effect of excess Pb contents on the etching of PZT thin films and their electrical properties has been investigated. Ferroelectric PZT(53/47) thin films were prepared by the metal alkoxide-based Sol-Gel method, in which they were spin-coating on P7Ti/Si02/Si substrate using the PZT(53/47) stock solutions with various excess Pb contents. Etching of PZT film was performed using planar inductively coupled Ar/Cl$_2$/BCl$_3$ plasma. The etch rate of PZT film was 2450 $\AA$/min at Ar(20)/BCl$_3$(80) gas mixing ratio and substrate temperature of 8$0^{\circ}C$.

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A Study on the Errors in the Free-Gyro Positioning and Directional System (자유자이로 위치 및 방위시스템의 오차에 관한 연구)

  • Jeong, Tae-Gweon
    • Journal of Navigation and Port Research
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    • v.37 no.4
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    • pp.329-335
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    • 2013
  • This paper is to develop the position error equations including the attitude errors, the errors of nadir and ship's heading, and the errors of ship's position in the free-gyro positioning and directional system. In doing so, the determination of ship's position by two free gyro vectors was discussed and the algorithmic design of the free-gyro positioning and directional system was introduced briefly. Next, the errors of transformation matrices of the gyro and body frames, i.e. attitude errors, were examined and the attitude equations were also derived. The perturbations of the errors of the nadir angle including ship's heading were investigated in each stage from the sensor of rate of motion of the spin axis to the nadir angle obtained. Finally, the perturbation error equations of ship's position used the nadir angles were derived in the form of a linear error model and the concept of FDOP was also suggested by using covariance of position error.

A study on radiation degradation of LDPE by using ESR (ESR을 이용한 저밀도 폴리에틸렌의 방사선 열화에 관한 연구)

  • Kim, Ki-Yup;Kim, Jin-Ah;Lee, Chung;Kim, Pyeong-Jong;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.473-476
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    • 2004
  • This study has investigated radiation degradation of low density polyethylene(LDPE). Samples were irradiated using a $Co^{60}\;\gamma-ray$ and ray up to 800 kGy at a dose rate of 5 kGy/hr in the presence of air atmosphere at room temperature. After irradiation, free radical measurement of LDPE has established by electron spin resonance(ESR). Then, each sample was stored for 2 weeks. ESR measurement showed that free radical concentration(FRC) was increased with radiation dose and changed from alkyl, allyl radical to peroxy radical with time.

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CONDUCTIVE SnO$_2$ THIN FILM FABRICATION BY SOL-GEL METHOD

  • Lee, Seung-Chul;Lee, Jae-Ho;Kim, Young-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.456-460
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    • 1999
  • Transparent conducting tin (IV) oxide thin films have been studies and developed for the electrode materials of solar cell substrate. Fabrication of tin oxide thin films by sol-gel method is process development of lower cost photovoltaic solar cell system. The research is focused on the establishment of process condition and development of precursor. The precursor solution was made of tin isopropoxide dissolved in isopropyl alcohol. The hydrolysis rate was controlled by addition of triethanolamine. Dip and spin coating technique were applied to coat tin oxide on borosilicate glass. The resistivity of the thin film was lower than 0.1Ω-cm and the transmittance is higher than 90% in a visible range.

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$^{13}C$ NMR Studies of Metabolic Pathways Regulated by HSP104 in Saccharomyces cerevisiae

  • 이경희;강수임;Susan Lindquist
    • Bulletin of the Korean Chemical Society
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    • v.19 no.3
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    • pp.295-299
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    • 1998
  • HSP104 protein in Saccharomyces cerevisiae is known to provide thermotolerance when induced by various kinds of stresses, such as a mild heat shock, ethanol, and hypoxia. It helps cells survive at an otherwise lethal temperature. Mechanisms by which HSP104 protein works are yet to be elucidated. In order to understand a molecular basis of thermotolerance due to HSP104 protein induced by a mild heat shock, studies on respiratory pathways were carried out in the wild type as well as in the hsp104 deleted mutant. Especially the degree of 13C-acetate incorporation into glutamate-C4 was examined for both strains using 13C-13C homonuclear spin coupling measurements, since glutamate is in a rapid equilibrium with α-ketoglutarate in the TCA cycle. In addition, the temperature effects on the rate of 13C incorporation are compared with or without HSP104 protein expressed. Finally, the inhibitory effect of HSP104 on the respiration pathway was confirmed by the measurements of oxygen consumption rates for both strains.

A correlation analysis about properties of quiescence magnetar

  • Seo, Jiwoo;Lee, Jaewon;An, Hongjun
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.52.2-52.2
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    • 2021
  • 우리는 quiescent state magnetar의 물리적 특성을 연구하기 위해 복사특성이 잘 알려진 24개의 대상을 선정하였고 가장 어두운 시기(quiescent state)의 Chandra와 XMM-Newton의 X-ray 관측 데이터를 분석하여 복사특성과 시간 특성을 측정하였다. 이 측정을 이용하여 복사특성과 시간 특성 사이의 여러 경우에 대해 상관관계를 분석하였다. 그 결과 기존에 높은 상관관계를 갖는 것으로 알려진 표면 자기장(Bs)과 흑체복사 광도(LBB), Bs와 X-ray photon index (ΓX) 관계를 더 많은 magnetar에 대하여 재확인하였으며, spin-down rate (Ṗ)와 LBB, characteristic age (𝜏c)와 LBB의 새로운 유의미한 관계를 찾았다. 또한 magnetar의 pulsed fraction (PF)과 흑체복사 반경(RBB), PF와 ΓX, 그리고 Ṗ과 ΓX가 서로 상관되어 있다는 단서를 확인하였다.

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Earth Rotation and Earth Tide: Review (지구자전과 지구조석 연구소개)

  • Sung-Ho Na;Yu Yi
    • Geophysics and Geophysical Exploration
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    • v.26 no.4
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    • pp.238-267
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    • 2023
  • Studies on Earth's rotation and tide since the 19th century are briefly summarized. The theories of precession, nutation, polar motion, and periodic/secular changes in the rate of rotation are described individually. In addition, a brief review of the Milankovitch theory - the hypothesis of the relationship between the Earth's spin/orbital rotational state and the ice ages - is given. Finally, Earth's tides and their theoretical models are briefly explained. Some detailed technical content is summarized in the appendices.