• Title/Summary/Keyword: Spectrum peak

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On the UV and IR Spectra of Dioxane Lignin from Bamboo Culm (죽재(竹材) Dioxane Lignin의 UV, IR Spectrum에 대하여)

  • Moon, Chang-Kuck;Jo, Jong-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.4
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    • pp.26-31
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    • 1987
  • The ultraviolet and infrared spectra of dioxane lignin from bamboo were investigated. 1. Spectrum curve type considerably resembled that of wood lignin. There were 3 absorption peak positions at 210nm(max. peak), at 260-270nm(shallow mini. peak), at 280nm(lower max. peak) as in the wood lignin spectra. 2. The lower minimum peak near at 280 nm is the typical peak of lignin. This peak does not exist exactly at 280 nm but from 282nm to 285nm in this bamboo UV spectra. The absorption intensities are equal in this region and the peak is not sharp. 3. The absorption band of aromatic nucleus is near at wave number $1550cm^{-1}$ in the IR spectra of bamboo lignin. The intensity at about 1040-$1130cm^{-1}$ and at about 1230-$1275cm^{-1}$ were similar in the hardwood lignin but reverse to that of softwood lignin spectrum.

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A Fast Parameter Estimation of Time Series Data Using Discrete Fourier Transform (이산푸리에변환과 시계열데이터의 고속 파라미터 추정)

  • Shim, Kwan-Shik;Nam, Hae-Kon
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.55 no.7
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    • pp.265-272
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    • 2006
  • This paper describes a method of parameter estimation of time series data using discrete Fourier transform(DFT). DFT have been mainly used to precisely and rapidly obtain the frequency of a signal. In a dynamic system, a real part of a mode used to learn damping characteristics is a more important factor than the frequency of the mode. The parameter estimation method of this paper can directly estimate modes and parameters, indicating the characteristics of a dynamic system, on the basis of the Fourier transform of the time series data. Real part of a mode estimates by subtracting a frequency of the Fourier spectrum corresponding to 0.707 of a magnitude of the peak spectrum from a peak frequency, or subtracting a frequency of the power spectrum corresponding to 0.5 of the peak power spectrum from a peak frequency, or comparing the Fourier(power) spectrum ratio. Also, the residue and phase of time signal calculate by simple equation with the real part of the mode and the power spectrum that have been calculated. Accordingly, the proposed algorithm is advantageous in that it can estimate parameters of the system through a single DFT without repeatedly calculating a DFT, thus shortening the time required to estimate the parameters.

Improvement of Mass Spectral Detection Performance by Pre-correction of Peak Position Error (피크위치오차 사전 보정을 통한 질량 스펙트럼 검출 성능 개선)

  • Lee, Young Hawk;Heo, Gyeongyong;Choi, Hun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.23 no.6
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    • pp.666-674
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    • 2019
  • In the mass spectrum of the mass spectrometer, the spectrum of the low peak adjacent to the spectrum having the high peak value is connected to each other and thus the separation is difficult. This inter-spectral overlap causes degradation of the mass spectral detection performance and resolution. In this paper, we propose a method to improve the mass spectrum detection performance and peak accuracy of residual gas analyzer. The type discrimination according to the characteristics of the ion signal block and the pre-correction for the peak position error can separate and detect the spectrum of the low peak connected to the adjacent spectra. To verify the performance of the proposed method, we compared the proposed method with the conventional method in simulations using actual ion signals obtained from the mass spectrometer under development.

Extracting Frequency-Frequency Correlation Function from Two-Dimensional Infrared Spectroscopy: Peak Shift Measurement

  • Kwak, Kyung-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3391-3396
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    • 2012
  • Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

Characteristics of Transmittance Spectrum of Korean Red Ginseng Using VIS/NIR (가시광선 및 근적외선을 이용한 홍삼의 투과스펙트럼 특성)

  • 손재룡;이강진;최규홍;김기영;강석원;최동수;장익주
    • Journal of Biosystems Engineering
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    • v.29 no.4
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    • pp.329-334
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    • 2004
  • This study was conducted to investigate the characteristics of transmittance spectrum of Korean red ginseng using VIS/NIR spectroscopy. The results of this study were as follows; Light intensity affected the characteristics of the spectrum. For over 40% light intensity, the first and second peaks appeared at 700nm and 1,100nm, respectively. For the 20% light intensity, the first and second peaks appeared at 800nm and 1,100nm, respectively. Thus, the typical color characteristics of halogen lamp were similar to each other if over 40% of maximum light intensity power, otherwise it was not. Transmittance spectrum showed different characteristics at different portions of red ginseng. Normal red ginseng showed strong intensity at the first peak around 700nmbecause of reddish internal tissue. However, an internal white core red ginseng showed weak peak-intensity due to whitish internal tissue. There was no significant difference in the second peak at 800nm for the different internal qualities. Third peak at 900nm showed somewhat difference by internal qualities but it was difficult to find significant trend. To separate the differences of the internal qualities, intensity differences between peaks were used. It was possible to classify normal red ginseng by the differences of "peak 1 -peak 2" and "peak 1 - peak 3". In addition, shift of the first and the third peaks in the spectrum could separate normal red ginseng from others.ginseng from others.

A Comparative Study on the Methods Estimating Wave Directional Spectrum (파향스펙트럼 추정법의 비교 연구)

  • 오병철;심재설
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.2 no.3
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    • pp.119-127
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    • 1990
  • Wave directional spectrum estimation methods for irregular waves were considered in this study. Until now, the Longuet-Higgins Method (LHM) initiated by Longuet-Higgins et al. (1963) has been widely used, but resolutions of the estimation were found to be low. Kobune's Maximum Entropy Method (MEM) for the estimation of wave directional spectrum, bas-ed on the entropy Principle showed higher resolutions comparing with the LHM . If the wave directional spectrum is of Delta functions, the MEM is exact in its estimation. It was also found that for a unimodal spectrum, if the Mitsuyasu's spreading coefficient is above 5, the estimation resolutions were high. In bimodal spectrum, as the angle difference between the two peaks increased, the resolution improved. The energy seems to transfer to the smoother peak in the smoothing of peak's peakedness. LHM has a tendency to estimate bimodal spectrum as a unimodal spectrum ; thus, except for its computational speed, the resolution of LHM falls far below that of MEM.

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On the UV Spectra of AcBr Lignins from Softwoods grown in Mt. Jiri (지리산산(智異山産) 침엽수재(針葉樹材) AcBr Lignin의 UV Spectra에 대(對)하여)

  • Jo, Jong-Soo;Moon, Chang-Kuck
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.3
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    • pp.35-40
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    • 1984
  • The ultraviolet absorption spectra of AcBr lignin (Acetyl Bromide lignin) from 10 species grown in Mt. Jiri were determined. There were 3 peak positions, at 249nm (max peak), at 267-268 nm (shallow min. peak) and at 280 nm (lower max. peak). The Bjorkman lignin and lignin sulfonic acid spectra had shoulders, but the AcBr lignin had not them. Average absorbances and absorptivities of the AcBr lignins at peak positions were $0.367{\pm}0.0015$, $24.56{\pm}0.0535$, at 249 nm, $0.278{\pm}0.0016$, $18.50{\pm}0.0569$, at 267-268 nm and $0.306{\pm}0.0016$, $20.42{\pm}0.0627$ at 280 nm, respectively.

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An Efficient Peak Detection Algorithm in Magnitude Spectrum for M-FSK Signal Classification (M-FSK 변조 신호 분류를 위한 효율적인 진폭 스펙트럼의 첨두 검출 방법)

  • Ahn, Woo-Hyun;Seo, Bo-Seok
    • Journal of Broadcast Engineering
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    • v.19 no.6
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    • pp.967-970
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    • 2014
  • An efficient peak detection algorithm in magnitude spectrum is proposed to distinguish the M-frequency shift keying(FSK) signals from other digitally modulated signal. In addition, recognition of the modulation order estimation of FSK signals is also studied based on the fact that the magnitude spectrum of FSK signals reveals the number of peaks equal to the modulation order. When no a priori information about the signals, we utilize the histogram of the magnitude spectrum to determine the threshold which is important factor in peak detection algorithm. The simulation results show high probability of classification under 500 symbols and signal-to-noise ratio(SNR) higher than 4dB.

Fast Estimation of Low Frequency Parameter for Real-Time Analysis in Wide Area Systems (광역계통의 실시간해석을 위한 고속 저주파수 파라미터 추정)

  • Kim, Eun-Ju;Shim, Kwan-Shik;Kim, Yong-Gu;Kim, Eui-Sun;Nam, Hae-Kon;Lim, Young-Chul
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.6
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    • pp.1078-1086
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    • 2009
  • This paper presents a Fourier based algorithm for estimating the parameters of the low frequency oscillating modes. The proposed methods estimates various parameters(frequency, damping factor, mode magnitude, phase) by fitting Fourier spectrum and phase with a damped exponential cosine function. Dominant frequency is selected by taking frequency corresponding to the peak spectrum, and damping factor is estimated using the left/right spectra of Fourier spectrum. In addition, mode magnitude is calculated by the normalized peak spectrum, and phase is estimated from spectrum phase. Also, we introduce an accuracy index in order to determine the accuracy of the estimated parameters, and the index is calculated using the deviations of the peak spectrum and the left/right spectra. The parameter estimation methods proposed in this paper include very simple arithmetical processes, so the algorithms are simple and the calculation speed is very fast. The proposed methods are applied to test functions with two dominant modes. The results show that the proposed methods are highly applicable to low frequency parameter estimation.

Wavelet Analysis of Swells in the East Sea (동해 너울에 대한 웨이블릿 분석)

  • Kim, Tae-Rim;Lee, Dong-Young
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.20 no.6
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    • pp.583-588
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    • 2008
  • Swell data observed in the East Sea in February, 2008 were analyzed using wavelet method. The wavelet analyzed results show detailed time series variation of wave group, peak frequency and spectrum. The comparison of time averaged wavelet spectrum with fourier spectrum turn out to be very similar in terms of spectrum shape and peak frequency evolution but the peak frequency wave energy and the significant wave height show discrepancies. Wavelet analysis can detect the change of spectrum in time as well as in frequency and very efficient to study transient and irregular phenomena such as freak waves and abnormal swells in the ocean. More analysis with more wave data are needed for future application.