• Title/Summary/Keyword: Spectroscopy

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Detection of Methane and Ethane by Continuous-Wave Cavity Ring-Down Spectroscopy Near 1.67 μm

  • Oh, Myoung-Kyu;Lee, Yong-Hoon;Choi, Sung-Chul;Ko, Do-Kyeong;Lee, Jong-Min
    • Journal of the Optical Society of Korea
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    • v.12 no.1
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    • pp.1-6
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    • 2008
  • We report the simple detection method of the small hydrocarbons, methane and ethane, by continuous-wave cavity ring-down spectroscopy near 1.67 ${\mu}m$ using an external cavity diode laser. The absorption lines of methane between 6002.48 $cm^{-1}$ and 6003.37 $cm^{-1}$ and ethane between 5955.65 $cm^{-1}$ and 5956.4 $cm^{-1}$ have been resolved and employed for the gas detection. The largest absorption cross sections were found to be 6.5$\times10^{-20}cm^2$ and 7.4$\times10^{-21}cm^2$ for methane and ethane, respectively, in each spectral range. The minimum detectable absorption limit of our spectrometer was 4.8${\times}10^{-9}cm^{-1}$/$\sqrt{Hz}$, which corresponds to the detection limits of 3 ppb/$\sqrt{Hz}$ and 27 ppb/$\sqrt{Hz}$ for methane and ethane, respectively. The near-IR continuous-wave cavity ring-down spectroscopic detection method of the small hydrocarbons can be applied for medical diagnosis and environmental monitoring as a fast and convenient method.

The Application of Ultrasonic Spectroscopy System for Phase Transition of Liquid Crystal (액정의 상전이 측정에 대한 초음파 spectroscopy 시스템의 적용)

  • Kim, Jeong-Koo;Lim, Cheong-Hwan
    • Journal of radiological science and technology
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    • v.27 no.4
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    • pp.31-35
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    • 2004
  • A new measuring system for ultrasonic spectroscopy was constructed, utilizing PVDF [poly(vinylidene fluoride)] polymer films as wideband transducers. In a test of its performance, this measuring system was successfully applied to study of the nematic-isotropic phase transition in MBBA(p-methoxybenzylidene-p-n-butylan iline) liquid crystal. We could be confirmed that the phase transition in MBBA is $47^{\circ}C$, which is agree with the exciting optical method. The dependence of frequency on the phase transition was not observed, and but Maximum ultrasonic amplitude is measured for the resonance frequency 2MHz in PVDF transducers, These results shows that the spectroscopy with PVDF transducers takes advantage of studying the transient phenomena. When our apparatus is applied in medical purposes, It will be possible diagnostic for sickle-cell anemia and arterial sclerosis.

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Interaction of Conjugated Conducting Polymer with Ionic Liquids (공액 전도성 고분자와 이온성 액체 간에 상호작용 연구)

  • Kim, Joong-Il;Kim, Do-Young;Kim, In-Tae
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.337-344
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    • 2014
  • In this paper, we have examined the interaction of low bandgap polymer {poly(2-heptadecyl-4-vinylthieno[3,4-d]thiazole)(PHVTT)} with ionic liquids. Further, we have studied the temperature dependent interactions between the ionic liquids [tri-butyl methyl ammonium methyl sulfate ([TBMA][$MeSO_4$]), methyl imidazolium chloride ([MIM]Cl) and butyl methyl imidazolium chloride ([BMIM]Cl)] and polymer using UV-vis spectroscopy, FT-IR spectroscopy, photoluminescence (PL) spectroscopy, as a function of temperature at 21, 28, 32, $37^{\circ}C$. These experimental results suggest that interactions of polymer with ionic liquids ([MIM]Cl, [TBMA][$MeSO_4$]) showed weak interactions by increasing temperature but [BMIM]Cl has no significant effect with increase in temperature.

Real-time wireless marine radioactivity monitoring system using a SiPM-based mobile gamma spectroscopy mounted on an unmanned marine vehicle

  • Min Sun Lee;Soo Mee Kim;Mee Jang;Hyemi Cha;Jung-Min Seo;Seungjae Baek;Jong-Myoung Lim
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2158-2165
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    • 2023
  • Marine radioactivity monitoring is critical for taking immediate action in case of unexpected nuclear accidents at nuclear facilities located near coastal areas. Especially when the level of contamination is not predictable, mobile monitoring systems will be useful for wide-area ocean radiation survey and for determination of the level of radioactivity. Here, we used a silicon photomultiplier and a high-efficiency GAGG crystal to fabricate a compact, battery-powered gamma spectroscopy that can be used in an ocean environment. The developed spectroscopy has compact dimensions of 6.5 × 6.5× 8 cm3 and weighs 560 g. We used LoRa, a low-power wireless protocol for communication. Successful data transmission was achieved within 1.4 m water depth. The developed gamma spectroscopy was able to detect radioactivity from a 137Cs point source (3.7 kBq) at a distance of 20 cm in water. Moreover, we demonstrated an unmanned radioactivity monitoring system in a real sea by combining unmanned surface vehicle with the developed gamma spectroscopy. A hidden 137Cs source (3.07 MBq) was detected by the unmanned system at a distance of 3 m. After successfully testing the developed mobile spectroscopy in an ocean environment, we believe that our proposed system will be an effective solution for mobile real-time marine radioactivity monitoring.