• Title/Summary/Keyword: Spectroscopy

Search Result 10,559, Processing Time 0.036 seconds

Coherent Absorption Spectroscopy with Supercontinuum for Semiconductor Quantum Well Structure

  • Byeon, Ciare C.;Oh, Myoung-Kyu;Kang, Hoon-Soo;Ko, Do-Kyeong;Lee, Jong-Min;Kim, Jong-Su;Choi, Hyoung-Gyu;Jeong, Mun-Seok;Kee, Chul-Sik
    • Journal of the Optical Society of Korea
    • /
    • v.11 no.3
    • /
    • pp.138-141
    • /
    • 2007
  • We suggest that supercontinuum can be used for absorption spectroscopy to observe the exciton levels of a semiconductor nano-structure. Exciton absorption spectrum of a GaAs/AlGaAs quantum well was observed using supercontinuum generated by a microstructrured fiber pumped by a femtosecond (fs) pulsed laser. Significantly narrower peaks were observed in the absorption spectrum from 11 K up to room temperature than photoluminescence (PL) spectrum peaks. Because supercontinuum is coherent light and can readily provide high enough intensity, this method can provide a coherent ultra-broad band light source to identify exciton levels in semiconductors, and be applicable to coherent nonlinear spectroscopy such as electromagnetically induced transparency (EIT), lasing without inversion (LWI) and coherent photon control in semiconductor quantum structures.

New Research Tool for Understanding of Surfaces - Sum Frequency Generation Vibrational Spectroscopy (표면의 이해를 위한 새로운 연구 방법 - 합 진동수 발생 진동 분광법)

  • Kim, Hak-Jin
    • Journal of the Korean Chemical Society
    • /
    • v.50 no.6
    • /
    • pp.429-439
    • /
    • 2006
  • vibrational spectrum of molecules on surfaces can be measured with high selectivity and sensitivity using sum frequency generation vibrational spectroscopy (SFG-VS). Selectivity and sensitivity of this non-linear spectroscopy have made it an effective experimental tool in surface research. Surface systems studied with SFG_VS are surveyed, and experimental and theoretical background of SFG-VS is briefly reviewed.

Polymerization of Tetraethoxysilane by Using Remote Argon/dinitrogen oxide Microwave Plasma

  • Chun, Tae-Il;Rossbach, Volker
    • Textile Coloration and Finishing
    • /
    • v.21 no.3
    • /
    • pp.19-25
    • /
    • 2009
  • Polymerization of tetraethoxysilane on a glass substrate was investigated by remote microwave plasma using argon with portions of nitrous oxide as carrier gas. Transparent layer like a thickness of 0.5 ${\mu}m$ 3 ${\mu}m$ were obtained, differing in chemical composition, depending on plasma power and treatment time as well as on ageing time. In general the milder the treatment and the shorter the ageing was, the higher was the content of organic structural elements in the layer. We have identified that the chemical structure of our samples composed of mainly Si O and Si C groups containing aliphatics, carbonyl groups. These results were obtained by X ray photon spectroscopy, Fourier transformed infrared spectroscopy, and scanning electron microscope combined with Energy dispersive X ray spectroscopy.

Non-Destructive Evaluation for Material of Thermal Barrier Coatings (단열 코팅재료의 비파괴 평가기법)

  • Lee Chul-Ku;Kim Tae-Hyung
    • Transactions of the Korean Society of Machine Tool Engineers
    • /
    • v.14 no.1
    • /
    • pp.44-51
    • /
    • 2005
  • Material degradation is a multibillion-dollar problem which affects all the industries amongst others. The last decades have seen the development of newer and more effective techniques such as Focused-ion beam(FIB), Transmission electron microscopy(TEM), Secondary-ion mass spectroscopy(SIMS), auger electron spectroscopy(AES), X-ray Photoelectron spectroscopy(XPS) , Electrochemical impedance spectroscopy(EIS), Photo- stimulated luminescence spectroscopy(PSLS), etc. to study various forms of material degradation. These techniques are now used routinely to obtain information on the chemical state, depth profiling, composition, stress state, etc. to understand the degradation behavior. This paper describes the use of these techniques specifically applied to materials degradation and failure analysis.

X-Ray Absorption Spectroscopy: A Complementary Tool for Structural and Electronic Characterization of Solids

  • Jean Etourneau
    • Bulletin of the Korean Chemical Society
    • /
    • v.19 no.1
    • /
    • pp.5-21
    • /
    • 1998
  • The purpose of this paper is to show that X-ray absorption spectroscopy (XANES and EXAFS) is a powerful technique for characterizing both crystalline and amorphous solids from structural (local order) and electronic point of view. The principle of this technique is briefly described by showing the main factors which must be considered for recording and fitting the experimental results. Some non-trivial examples have been selected for demonstrating that XAS spectroscopy is the only technique for bringing a definitive answer as for example: the determination of the local distortion of the $NiO_6$ octahedra in the $Li_{1-z}Ni_{1+z}O_2$ layered oxides and the evidence of the presence of copper pairs in the NASICON-type phosphate $CuZr_2 (PO_4)_3$. Are also reported some significant examples for which XAS spectroscopy is decisive with other characterization methods as (i) Raman spectroscopy for glasses (ii) Mossbauer spectroscopy for $LiNi_{1+z-t}Fe_To_2$ oxides (iii) magnetic measurements for Ce-based intermetallic compounds.

Monitoring Oxidation Behavior of [C70]Fullerene by Ultrasonic Spectroscopy ([C70]풀러렌 산화 반응의 거동에 관한 초음파 분광학적 고찰)

  • Ko, Weon Bae
    • Elastomers and Composites
    • /
    • v.49 no.2
    • /
    • pp.155-159
    • /
    • 2014
  • High resolution ultrasonic spectroscopy was used to observe the oxidation of [$C_{70}$]fullerene with 3-chloroperoxy benzoic acid in 1,2-dichlorobenzene. UV-vis spectroscopy and X-ray diffraction confirmed the resulting roducts of [$C_{70}$]fullerene oxidation.

Qualitative and Quantitative Analysis of Space Minerals using Laser-Induced Breakdown Spectroscopy and Raman Spectroscopy (레이저 유도 분해 분광법과 라만 분광법을 이용한 우주 광물의 정성 및 정량 분석 기법)

  • Kim, Dongyoung;Yoh, Jack J.
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.46 no.6
    • /
    • pp.519-526
    • /
    • 2018
  • In order to analyze space resources, it had to be brought to earth. However, using laser-induced breakdown spectroscopy(LIBS) and Raman spectroscopy, it is possible to analyze qualitative and quantitative analysis of space minerals in real time. LIBS is a spectroscopic method in which a high energy laser is concentrated on a material surface to generate a plasma, and the emitted light is acquired through a spectroscope to analyze the atomic composition. Raman spectroscopy is a spectroscopic method that analyzes the molecular structure by measuring scattered light. These two spectroscopic methods are complementary spectroscopic methods for analyzing the atoms and molecules of unknown minerals and have an advantage as space payloads. In this study, data were analyzed qualitatively by using principal component analysis(PCA). In addition, a mixture of two minerals was prepared and a quantitative analysis was performed to predict the concentration of the material.

Determination of Ethanol in Blood Samples Using Partial Least Square Regression Applied to Surface Enhanced Raman Spectroscopy

  • Acikgoz, Gunes;Hamamci, Berna;Yildiz, Abdulkadir
    • Toxicological Research
    • /
    • v.34 no.2
    • /
    • pp.127-132
    • /
    • 2018
  • Alcohol consumption triggers toxic effect to organs and tissues in the human body. The risks are essentially thought to be related to ethanol content in alcoholic beverages. The identification of ethanol in blood samples requires rapid, minimal sample handling, and non-destructive analysis, such as Raman Spectroscopy. This study aims to apply Raman Spectroscopy for identification of ethanol in blood samples. Silver nanoparticles were synthesized to obtain Surface Enhanced Raman Spectroscopy (SERS) spectra of blood samples. The SERS spectra were used for Partial Least Square (PLS) for determining ethanol quantitatively. To apply PLS method, $920{\sim}820cm^{-1}$ band interval was chosen and the spectral changes of the observed concentrations statistically associated with each other. The blood samples were examined according to this model and the quantity of ethanol was determined as that: first a calibration method was established. A strong relationship was observed between known concentration values and the values obtained by PLS method ($R^2=1$). Second instead of then, quantities of ethanol in 40 blood samples were predicted according to the calibration method. Quantitative analysis of the ethanol in the blood was done by analyzing the data obtained by Raman spectroscopy and the PLS method.