• 제목/요약/키워드: Spectroscopic temperature

검색결과 320건 처리시간 0.024초

RF 플라즈마 및 전기장의 흑색종 (G361 melanoma) 세포에 대한 사멸 효과 (The Effects of an RF Plasma and Electric Fields on the Death of G361 Melanoma Cells)

  • 손채화;김규천;이해준
    • 전기학회논문지
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    • 제56권11호
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    • pp.1972-1977
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    • 2007
  • Micro plasma has been recently studied to investigate the effects on various cells. We study a micro-plasma produced by a plasma needle that is operated with RF power and its effects on G361 melanoma cells. The micro plasma size ranges from sub-mm to several mm at a few watts of RF power. For the bio-medical treatment, low-temperature plasma is obtained and gas temperature is controlled within several tens of degrees $(^{\circ}C)$ in order not to disturb cell activities. Elementary spectroscopic studies to obtain plasma characteristics are presented for Ar and He plasma with different frequencies of RF power. Also the preliminary results of the micro plasma effects on G361 melanoma cells are presented. It was observed that the irradiation of micro plasma induces cell death through the deprivation of tyrosine phosphorylation in the G361 cells.

DC magnetron 방법과 RF 스퍼터링 방법으로 제작된 Nickel Oxide 박막의 특성 연구 (A study of Nickel Oxide thin film deposited by DC magnetron and RF sputtering method)

  • 최광남;박준우;백숭호;이호선;곽성관;정관수
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2007년도 하계종합학술대회 논문집
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    • pp.441-442
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    • 2007
  • We deposited nickel oxide(NiO) thin films on silicon(Si) substrates at Room temperature and $500^{\circ}C$ using a nickel target by reactive DC and RF sputtering. In addition, we anneal to NiO thin films deposited at room temperature. Using spectroscopic eillipsometry, we obtained optical characteristics of every films. We discussed relations of the optical and structural properties of NiO thin films with the oxygen flow rate, substrate temperature and annealing temperatures. Refraction was decreased and defect was increased when NiO thin films was annealed. We also analyzed the electrical characteristics of NiO films which deposited DC and RF sputtering method.

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Spectroscopic and Morphological Investigation of Co3O4 Microfibers Produced by Electrospinning Process

  • Baek, J.H.;Park, J.Y.;Hwang, A.R.;Kang, Y.C.
    • Bulletin of the Korean Chemical Society
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    • 제33권4호
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    • pp.1242-1246
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    • 2012
  • The Co oxide microfibers were synthesized using the electrospinning process and formed $Co_3O_4$ microfibers after being calcined at high temperatures. The calcination temperature influenced the diameters, morphology, crystalline phase, and chemical environment of the fibers. The surface morphology of the obtained fibers was examined by using the scanning electron microscope (SEM). As the calcination temperatures increased from room temperature to 873 and 1173 K, the diameters of the cobalt oxide fibers decreased from 1.79 to 0.82 and 0.32 mm, respectively. The structure of the fibers was investigated with X-ray diffraction (XRD) and transmission electron microscopy (TEM). The calcined $Co_3O_4$ fibers had crystalline face-centered cubic (fcc) structure. The X-ray photoelectron spectroscopy (XPS) results revealed that increasing the calcination temperature promoted the formation of $Co^{2+}$ and $Co^{3+}$ species.

Synthesis of Core-Modified Porphyins and Studies of Their Temperature-dependent Tautomerism

  • 이창희;김한재;윤대위
    • Bulletin of the Korean Chemical Society
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    • 제20권3호
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    • pp.276-280
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    • 1999
  • The different core-modified porphyrins 21-thia-23-carba-12-aza-5,10-dimesityl-15,20-diphenylporphyrin (6), and their N(12)-methyl derivatives (8) were synthesized by acid-catalyzed [3+1] condensation of the corresponding 16-thia-5,10-dimesityltripyrromethanes and 2,4-bis[(α-hydroxy-α-phenyl)methyl]pyrrole. Spectroscopic evidence indicates the existence of two different tautomeric forms at room temperature in porphyrin (6). A third form of tautomer was observed when the temperature was lowered to 223 K. The most stable tautomer is one in which the nitrogenic proton resides outside the core of the macrocycle. The ratio of the three different tautomers (outer N-H/ two inner N-H, i.e. 6/12/13) was 1/l/0.5 in the case of (6) while the ratio of 1/l/0.3 was observed in the case of (10). In the case of 21-oxa-23-carba-12-aza-5,10,15,20-tetraphenylporphyrin (7), the only stable tautomeric form observed by 1H NMR was the one that nitrogenic proton resides inside the core on

Spectroscopic properties of Er3+/Yb3+ co-doped fluorophosphate glasses for NIR luminescence and optical temperature sensor applications

  • Linganna, K.;Agawane, G.L.;In, Jung-Hwan;Park, June;Choi, Ju H.
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.236-243
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    • 2018
  • A series of $Er^{3+}/Yb^{3+}$ co-doped fluorophosphate glasses with varying $YbF_3$ concentration were prepared by a high temperature melt quenching technique. Absorption and emission cross-sections were determined by using the McCumber theory. The larger emission cross-section ($9.86{\times}10^{-21}cm^2$) and longer fluorescence lifetime (12.37 ms) were obtained for the $^4I_{13/2}{\rightarrow}^4I_{15/2}$ transition of ABS3Er4Yb glass. The sensitivity and temperature of the maximum sensitivity were evaluated by the fluorescence intensity ratio method from the measured upconversion spectra. The results were discussed and compared to the other reported glasses.

쪽 생잎즙액에 의한 견염색에 관한 연구 (Dyeing of Silk by the use of fresh leaves of Indigo plant)

  • 정인모
    • 한국잠사곤충학회지
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    • 제42권1호
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    • pp.36-41
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    • 2000
  • The indigo dyeing on silk was carried out by the use of fresh leaves juice of polygonum tinctorium. By means of spectroscopic analysis, it is proved that indoxyl are present in the juicese due to the enzymatic reducing of indican contained in the leaves. In case of fresh leaf dyeing, K/S value of dyed fabric was higher at 25$\^{C}$ than at 35$\^{C}$ of the dyeing temperature, its colour fastness aganist washing, perspiration and ligt ranged from 4 to 5 grade.

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아르곤4P준위 광방출 분석법(OES)을 이용한 플라즈마의 전자온도 및 준안정 밀도 측정

  • 이영광;이민형;정진욱
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2007년도 춘계학술대회
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    • pp.104-108
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    • 2007
  • This paper reviews a simple model and spectroscopic method for extracting plasma electron temperature and argon metastable number density. The model is based on the availability of experimental relative emission intensities of only four argon lines that originate from 4p argon level. In this method, Maxwell-Boltzman distribution for EEDF is assumed and the calculation relies on the accuracy of the cross section. Therefore OES have to be compared with Langmuir probe to establish their practical validity.

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Preparation and Physical Characterizations of Superparamagnetic Maghemite Nanoparticles

  • Yoon, Sunghyun
    • Journal of Magnetics
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    • 제19권4호
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    • pp.323-326
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    • 2014
  • Superparamagnetic maghemite nanoparticles were prepared by chemical co-precipitation, followed by a temperate oxidation stage, and investigated using FE-SEM, XRD, TGA, VSM, and M$\ddot{o}$ssbauer spectroscopy. Through SEM image and XRD analysis, its average particle size was found to be 13.9 nm. While VSM magnetic measurement showed typical superparamagnetic behavior at room temperature, M$\ddot{o}$ssbauer spectroscopic investigation revealed that non-vanishing magnetic hyperfine structure were retained. Cation distribution estimated from M$\ddot{o}$ssbauer spectroscopy confirmed the formation of maghemite nanophase in the sample.

ISOTOPIC-SPECTRAL DETERMINATION OF CARBON IN HIGH PURITY INORGANIC MATERIALS

  • Lee, V.N.;Nemets, V.M.
    • 분석과학
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    • 제8권4호
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    • pp.477-480
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    • 1995
  • Isotopic-spectral method [I] was applicated for determination of carbon in silicate materials (pure silica, guartz glasses, geological probs etc.). Isotopic heterogeneous balancing of carbon in gaseous phase and solid samples was carried out at the temperature of $1500-1900^{\circ}K$. Spectroscopic measuring of isotope concentration in a balanced gas was made using the electron-vibrational band heads of CO molecules excited in HF discharge. Limits of detection of carbon concentrations appear to be $n^*10^{-6}$.

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