• Tribology and Lubricants
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• 제15권2호
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• pp.131-140
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• 1999

This study dealt with some problems occurred in spectrometric oil analysis that has been popularly used for a machine condition monitoring in various fields of industry. One of the problems is that spectrometric technique could not analyze contaminants of large particle (larger than 10 $\mu\textrm{m}$) in lubricating oils. This limitation caused a serious problem in analyzing lubricated machine conditions since wear debris of large size represents better critical machine conditions. In this work, this problem was found to be solved by using a filtration method prior to spectrometric analysis. Another problem could be that spectrometric analysis is incapable of identifying contaminants. This nay mislead the result seriously in practice. This problem was surveyed by analyzing both various types of industrial lubricants and laboratory simulation tests, and the solutions to the problem were suggested in this work.

• 한국식품영양과학회지
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• 제3권1호
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• pp.53-68
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• 1974

The thiohydantoin derivative derived from amino acid was used for the stepwise sequence analysis of peptide or protein from the carboxyl termini. Recently, SUZUKI reported the mass spectrometric identification about a part of these compounds. In this paper, was described the mass spectrometric identification of thiohydantoins derived from 20 amino acids. Mass spectra were obtained with a mass spectrometer, JEOL model JMS-06H and samples were introduced with a direct inlet probe. The molecular ion peaks and fragment ion peaks were identified easily, because these peaks appeared differently every amino acids and specially, it was easy discrimination between leucine and isoleucine. It is suggested that mass spectrometry was one of the useful methods to identify thiohydantoins derived from amino acids.

• Nuclear Engineering and Technology
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• 제29권4호
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• pp.327-335
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• 1997

The correlation of isotope composition of uranium, plutonium and neodymium with the burnup in M uranium dioxide fuel has been investigated experimentally. The total and fractional($^{235}$ U) burnup were determined by Nd-148 and, U and Pu mass spectrometric method respectively. The isotope compositions of these elements, after their separation from the fuel samples were measured by mass spectrometric. The content of the elements in the irradiated fuel ore determined by isotope dilution mass spectrometric method using $^{233}$ U, $^{242}$ Pu and $^{150}$ Nd as spikes. The content of plutonium in the irradiated fuel was expressed by the correlation with uranium isotopes. The correlations between isotope compositions themselves and the total and fractional burnup ore compared with those calculated from ORIGEN2 code.

• 윤활유협회보
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• 7호
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• pp.4-7
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• 1984

• Nuclear Engineering and Technology
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• 제55권7호
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• pp.2366-2372
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• 2023

Are borate and silicate glasses suitable for working as shieling materials against fast neutrons? To correctly answer the above question, some silicate, and borate-based glasses were fabricated and irradiated with various doses of fast neutrons varied between 1.73 and 12.10 MGy. The color and hardness of the fabricated glasses were affected by the fast neutron fluence where the transparent glasses turned colored as well as the hardness of the fabricated glasses was decreased. The gamma-ray spectrometric analysis shows a high activity concentration produced in the barium borate glasses due to the formation of radioisotopes Ba-131 and Ba-133 reaches to 5.92E+05 Bq and 4.25E+03 Bq, respectively for sample Cd-5 Batch 3. Additionally, the gamma-ray spectrometric analysis for the sodium silicate glasses shows low activity concentrations emitted from isotopes formed due to the activation of Y₂O₃-associated impurities. These activities are low compared to that emitted by barium borate-based glasses.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.51.2-51.2
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• 2015

Understanding interfacial phenomena has been one of the main research issues not only in semiconductors but only in life sciences. I have been trying to meet the atomic scale surface and interface analysis challenges from semiconductor industries and furthermore to extend the application scope to biomedical areas. Optical imaing has been most widely and successfully used for biomedical imaging but complementary ion beam imaging techniques based on mass spectrometry and ion scattering can provide more detailed molecular specific and nanoscale information In this presentation, I will review the 27 years history of medium energy ion scattering (MEIS) development at KRISS and DGIST for nanoanalysis. A electrostatic MEIS system constructed at KRISS after the FOM, Netherland design had been successfully applied for the gate oxide analysis and quantitative surface analysis. Recenlty, we developed time-of-flight (TOF) MEIS system, for the first time in the world. With TOF-MEIS, we reported quantitative compositional profiling with single atomic layer resolution for 0.5~3 nm CdSe/ZnS conjugated QDs and ultra shallow junctions and FINFET's of As implanted Si. With this new TOF-MEIS nano analysis technique, details of nano-structured materials could be measured quantitatively. Progresses in TOF-MEIS analysis in various nano & bio technology will be discussed. For last 10 years, I have been trying to develop multimodal nanobio imaging techniques for cardiovascular and brain tissues. Firstly, in atherosclerotic plaque imaging, using, coherent anti-stokes raman scattering (CARS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) multimodal analysis showed that increased cholesterol palmitate may contribute to the formation of a necrotic core by increasing cell death. Secondly, surface plasmon resonance imaging ellipsometry (SPRIE) was developed for cell biointerface imaging of cell adhesion, migration, and infiltration dynamics for HUVEC, CASMC, and T cells. Thirdly, we developed an ambient mass spectrometric imaging system for live cells and tissues. Preliminary results on mouse brain hippocampus and hypotahlamus will be presented. In conclusions, multimodal optical and mass spectrometric imaging privides overall structural and morphological information with complementary molecular specific information, which can be a useful methodology for biomedical studies. Future challenges in optical and mass spectrometric imaging for new biomedical applications will be discussed.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1508-1512
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• 2004

A gas chromatography/mass spectrometric (GC/MS) method has been developed for the determination of trace mono-n-butyltin (MBT), di-n-butyltin (DBT), and tri-n-butyltin (TBT) compounds in sediments. Samples were extracted by 10% acetic acid in methanol containing 0.03% tropolone and were then derivatized for GC/MS analysis. Ethylation by sodium tetraethylborate and phenylation by sodium tetraphenylborate were evaluated as a derivatization reaction of the organotins in sample extract. n-Hexane was added into reaction media in the beginning of the reaction for the continuous extraction of derivatized organotins. Ethylation requires less than 2 hours to get proper derivatization yields for MBT, DBT, and TBT altogether and produces relatively low amounts of side reaction products. Compared to ethylation, phenylation requires much longer time but provides relatively lower yield and produces considerable amounts of side reaction products. Therefore, the ethylation reaction was applied for the analysis of organotin compounds in sediment. An isotope dilution mass spectrometric (IDMS) method based on GC/MS has been applied to the accurate determination of DBT compounds in the sediments. The IDMS results from the analyses of sediment samples showed a reasonable repeatability and a good agreement with the values obtained by IDMS based on liquid chromatography/induced coupled plasma/mass spectrometry.

• 한국시뮬레이션학회논문지
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• 제22권4호
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• pp.139-147
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• 2013

본 논문에서는 질량 분석 방법에 의하여 산출된 단백체 데이터(mass spectrometric proteomic data)의 분류 분석(classification analysis)을 위한 새로운 특성 선택(feature selection) 방법을 제안한다. 이 방법은 i)높은 상관관계를 가지는 중복된 특성을 효과적으로 제거하는 전처리 단계와 ii)토너먼트(tournament) 전략을 사용하여 최적 특성 부분집합(optimal feature subset)을 탐색해 내는 단계로 구성되어 있다. 제안되는 방법을 실제 암진단에 사용되는 공개된 혈액 단백체 데이터에 적용하였으며 널리 사용되는 타 방법과 비교할 때 우수한 성능과 균형된 특이도와 민감도를 달성함을 실증하였다.

• Nuclear Engineering and Technology
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• 제47권7호
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• pp.924-933
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• 2015

The correlation of the isotopic composition of uranium, plutonium, neodymium, and cesium with the burnup for high burnup pressurized water reactor fuels irradiated in nuclear power reactors has been experimentally investigated. The total burnup was determined by Nd-148 and the fractional $^{235}U$ burnup was determined by U and Pu mass spectrometric methods. The isotopic compositions of U, Pu, Nd, and Cs after their separation from the irradiated fuel samples were measured using thermal ionization mass spectrometry. The contents of these elements in the irradiated fuel were determined through an isotope dilution mass spectrometric method using $^{233}U$, $^{242}Pu$, $^{150}Nd$, and $^{133}Cs$ as spikes. The activity ratios of Cs isotopes in the fuel samples were determined using gamma-ray spectrometry. The content of each element and its isotopic compositions in the irradiated fuel were expressed by their correlation with the total and fractional burnup, burnup parameters, and the isotopic compositions of different elements. The results obtained from the experimental methods were compared with those calculated using the ORIGEN-S code.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2398-2402
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• 2009

Ten steroidal compounds as impurities in canrenone were isolated from the enriched mother liquor by using various chromatographic methods. Their structures were elucidated by spectrometric analysis, among which three new compounds were characterized as 3-(3-oxo-7$\alpha$-(ethoxycarbonyl)methyl-17$\beta$-hydroxy-4-androsten-17$\alpha$-yl) propionic acid $\gamma$-lactone (1), 3-(3-oxo-7$\alpha$-ethoxy-17$\beta$-hydroxy-4-androsten-17$\alpha$-yl) propionic acid $\gamma$-lactone (2) and 3-(3-oxo- 5$\beta$-propionic acid-$\gamma$-lactone-6$\beta$,17$\beta$-hydroxy-4-androstan-17$\alpha$-yl) propionic acid $\gamma$-lactone (3).