• Current Optics and Photonics
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• v.1 no.4
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• pp.271-277
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• 2017

Based on the extended Huygens-Fresnel principle, the analytical propagation formulae for spectrally partially coherent Gaussian Schell-model pulsed (SPGSMP) beams propagating in turbulent atmosphere have been derived. The influences of the parameters for turbulent atmosphere and SPGSMP beams on the on-axis and off-axis spectral shift and degree of coherence for SPGSMP beams propagating in turbulent atmosphere have been analyzed, using numerical calculations. The obtained results have potential applications for SPGSMP beams in free-space optical communication and laser lidar.

• Bulletin of the Korean Chemical Society
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• v.26 no.11
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• pp.1706-1710
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• 2005

The excited-state intramolecular proton transfer (ESIPT) fluorescence in the 2-(2'-hydroxyphenyl)benzoxazole (HBO) derivatives with different electron donor and acceptor substituents was studied by spectroscopic and theoretical methods. Changes in the electronic transition, energy levels, and orbital diagrams of HBO analogues were investigated by the semi-empirical molecular orbital calculation and were correlated with the experimental spectral position of ESIPT keto emission. It was found that the presence of substituents, regardless of their nature, resulted in the red-shifted absorption relative to HBO. However, the spectral change of the ESIPT fluorescence was differently affected by the nature of substituent: hypsochromic shift with electron donor and bathochromic shift with electron acceptor.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.11 no.6
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• pp.388-395
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• 1986

Dispersion characteristics of shielded single, coupled and edge-offset microstrip structures are investigated by using hybrid mode analysis with Galerkin's method in the spectral domain. Two new basis functions for the longitudinal strip current are proposed and convergence rates of the solutions for the basis functions are compared. Current distribution of the coupled line is obtaind from that of the single line by using shift theorem of the Fourier transform. In addition, effects of off-centered inner strip conductor on dispersion are also discussed Numerical results include various structual parameters and are compared with other available data and good agreements are observed.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2332-2338
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• 2011

In this study, we proposed a new promising idea of utilizing moving window principal component analysis (MWPCA) as a sensitive diagnostic tool to detect the presence of peak position shift. In this approach, the moving window is constructed from a small data segment along the wavenumber axis. For each window bound by a narrow wavenumber region, separate PCA analysis was applied. Simulated spectra with complex spectral feature variations were analyzed to explore the possibility of MWPCA technique. This MWPCA-based detection of the peak shift, potentially coupled with 2D correlation analysis to provide additional verification, may offer an attractive solution.

• Journal of Photoscience
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• v.8 no.3_4
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• pp.113-117
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• 2001

Several styrylquinolium salts were synthesized to investigate their absorption and thermal properties, which had five different p-aminobenzene units and three different counter ions (iodide, perchlorate, and hexafluorophosphorate anion), respectively. Hydroxy, methoxy, and methyl group in the meta position to the amino group led to bathochromic shift, while Ν-ethyl-Ν-chloroethylamino unit instead of Ν,Ν-diethylamino unit resulted in hypsochromic shift. A dye having a methoxy group in the meta position to the amino group had the highest molar extinction coefficient ($\xi$), while a dye carrying chloro group in Ν-alkyl chains had the lowest $\xi$. The type of counter ions had no effect on spectral properties like the maximum absorption wavelength and $\xi$. All styryl dyes had exothermic peaks at decomposition in DSC curves. Among these styryl dyes, S2 series with perchlorate anions showed the strongest exothermic decomposition. From TGA spectra, S3 series with hexafluorophosphorate anions had the best thermal stability and the sharpest threshold at thermal decomposition.

• Journal of the Korean Institute of Telematics and Electronics S
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• v.34S no.2
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• pp.79-93
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• 1997

This paper presents a linear shift-invariant system euqivalent to morphological dilation for a memoryless uniform source in the sense of the power spectral density function, and comares it with dialtion. This equivalent LSI system is found through spectral decomposition and, for dilation and with windwo size L, it is shown to be a finite impulse response filter composed of L-1 delays, L multipliers and three adders. Th ecoefficients of the equivalent systems are tabulated. The comparisons of dilation and its equivalent LSI system show that probability density functions of the output sequences of the two systems are quite different. In particular, the probability density functon from dilation of an independent and identically distributed uniform source over the unit interval (0, 1) shows heavy probability in around 1, while that from the equivalent LSI system shows probability concentration around themean vlaue and symmetricity about it. This difference is due to the fact that dilation is a non-linear process while the equivalent system is linear and shift-ivariant. In the case that dikation is fabored over LSI filters in subjective perforance tests, one of the factors can be traced to this difference in the probability distribution.

• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1825-1831
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• 2006

The influence of solvent viscosity on conformational dynamics of the heme-pocket, a small vacant site near the binding site of myoglobin (Mb) and hemoglobin (Hb), and playing a functionally important role by serving as a station in ligand binding and escape, was studied by probing time-resolved vibrational spectra of CO photodissociated from MbCO and HbCO in $D_2O$, 75 wt% glycerol/$D_2O$, and trehalose at 283 K. Two absorption bands ($B_1$ and $B_2$) of the sample in viscous solvents, arising from CO in the heme pocket, are very similar to those in $D_2O$. Two bands in Mb and Hb under all three solvents exhibit very similar nonexponential spectral evolution ($B_1$ band; blue shifting and broadening, $B_2$ band; narrowing with a negligible shifting), suggesting that in the present experimental time window of 100 ps, the extents of the spectral shift and narrowing is much influenced neither by the viscosity of solvent nor by the quaternary contact of Hb. Spectral evolution can be described by a biexponential function with a fast universal time constant of 0.52 ps and a slow time constant ranging from 13 to 32 ps. For both proteins in all three solvents majority of spectral evolution occurs with the fast universal time constant. The magnitude of the slow rate in the spectral shift of B1 band decreases with increasing solvent viscosity, indicating that it is influenced by global conformational change which is retarded in viscous solvent, thereby serve as a reporter of global conformational change of heme proteins after deligation.

• 제어로봇시스템학회:학술대회논문집
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• 1989.10a
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• pp.427-430
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• 1989

For on-line ARMA spectral estimation, the fast transversal filter algorithm of extended least squares method(ETS FTF) is presented. The projection operator, a key tool for geometric approach, is used in the derivation of the algorithm. ELS FTF is a fast time update recursion which is based on the fact that the correlation matrix of ARMA model satisfies the shift invariance property in each block, and thus it takes 10N+31 MADPR.

• Proceedings of the IEEK Conference
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• 2001.06a
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• pp.233-236
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• 2001

Orthogonal freqency division multiplexing (OFDM) is an attractive technique for achieving high-bit-rate wireless data transmission. However, the potentially large peak-to-average power ratio (PAPR) has limited its application; An OFDM signal with the large PAPR can cause power degradation (In-band distortion) and spectral spreading (Out-of-band distortion) by being clipped passing through a power amplifier. Thus, we propose the combining algorithm of Hadamard transform and phase shift, which is ascribed to the relation between the correlation of the IFFT input sequence function and PAPR. Extensive computer simulations show that the combining algorithm is an effective technique to reduce PAPR.

• Bulletin of the Korean Chemical Society
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• v.19 no.4
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• pp.471-475
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• 1998

Phase shift spectroscopy is applied to Eu(Ⅲ) luminescence from $Eu^{3+}$-exchanged Y zeolite. The phase shift and intensity modulation of luminescence following intensity-modulated excitation are measured as a function of modulation frequency and they are fitted into a double exponential decay. The fast decay component, compared with the slow one, has narrower spectral bandwidth and is emitted from the $Eu^{3+}$ that has more polar and definite environment with higher symmetry and that interacts more easily with hydrated water molecules. The fast decay component is attributed to $Eu^{3+}$ at site Ⅱ' while the slow one to $Eu^{3+}$ at sites Ⅰ' and Ⅰ.