• Title/Summary/Keyword: Sorptivity

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Fundamental Properties of Mortar Utilizing Waste Concrete Power (폐콘크리트 분말을 활용한 모르타르의 기초물성에 관한 연구)

  • Choi, Yun-Wang;Moon, Dae-Joong;Kim, Sung-Su;Kim, Ki-Hyung;Moon, Han-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.620-623
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    • 2004
  • Waste concrete powder(WCP) has been estimated with a great value-added material as by-product of waste concrete manufactured to fine and coarse aggregate for concrete, because it is able to utilized for cement clinker and concrete admixture. In the experimental results for this study, chemical composition of WCP was similar to that of cement, and specific gravity of WCPs were 2.46 and 2.48 due to internal micro-void of WCP. Final setting of paste with WCP was delayed, and flow value of mortar with WCP was tendency to reduced in comparison with that of paste and mortar with only ordinary portland cement as replacement ratio of WCP increased. Furthermore, sorptivity of mortar with WCP was increased as replacement ratio of WCP increased. Compressive strength of mortar with $15\%$ WCP was developed about 27MPa at 28days.

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Kinetics of the water absorption in GGBS-concretes: A capillary-diffusive model

  • Villar-Cocina, E.;Valencia-Morales, E.;Vega-Leyva, J.;Antiquera Munoz, J.
    • Computers and Concrete
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    • v.2 no.1
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    • pp.19-30
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    • 2005
  • We study the kinetics of absorption of water in Portland cement concretes added with 60, 70 and 80% of granulated blast furnace slag (GGBS) cured in water and at open air and preheated at 50 and $100^{\circ}C$. A mathematical model is presented that allows describing the process not only in early ages where the capillary sorption is predominant but also for later and long times where the diffusive processes through the finer and gel pores are considered. The fitting of the model by computerized methods enables us to determine the parameters that characterize the process: i.e., the sorptivity coefficient (S) and diffusion coefficient (D). This allows the description of the process for all times and offers the possibility to know the contributions of both, the diffusive and capillary processes. The results show the influence of the curing regime and the preheating temperature on the behavior of GGBS mortars.

Effect of ultra-fine slag on mechanical and permeability properties of Metakaolin-based sustainable geopolymer concrete

  • Parveen, Parveen;Mehta, Ankur;Saloni, Saloni
    • Advances in concrete construction
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    • v.7 no.4
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    • pp.231-239
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    • 2019
  • The present study deals with the development of metakaolin-based geopolymer concrete (GPC) and thereafter studying the effects of adding ultra-fine slag on its mechanical and permeability characteristics. The mechanical characteristics including compressive, split tensile, flexural strengths and elastic modulus were studied. In addition, permeability characteristics including water absorption, porosity, sorptivity and chloride permeability were studied up to 90 days. The results showed the effective utilization of metakaolin for the development of elevated temperature cured geopolymer concrete having high 3-day compressive strength of 42.6 MPa. The addition of ultra-fine slag up to 15%, as partial replacement of metakaolin resulted in an increase in strength characteristics. Similar improvement in durability properties was also observed with the inclusion of ultra-fine slag up to 15%. Beyond this optimum content of 15%, further increase in ultra-fine slag content affected the mechanical as well as permeability parameters in a negative way. In addition, the relationship between various properties of GPC was also derived.

A study on the application of waste concrete powder as a material for construction (건설용 재료로써 폐콘크리트 미분말의 활용성 연구)

  • Kim, Yong-Jic;Choi, Yun-Wang;Kim, Sang-Chel;Kim, Young-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.88-94
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    • 2012
  • This study is conducted to utilize waste concrete powder made as a by-product manufacturing high quality recycled aggregate. The blaine fineness of the used waste concrete powder was 928 and $1,360cm^2/g$. As the main characteristic of waste concrete powder, it showed an angular type similar to cement, but hydrated products were attached on the surface of particles. In addition, the size of the particles of waste concrete powder was larger than OPC and in terms of chemical components it had higher $SiO_2$ contents. The viscosity of the paste that mixed waste concrete power decreased by 62% at the most, compared to the paste that only used OPC, and the final set time was delayed about two hours. As composition rates of waste concrete powder increased, the flow value decreased by 30% at the most according to the comparison with mortar that only used OPC, and sorptivity coefficients increased by 70%. The compressive strength of mortar decreased by 73% at the most as composition rates of waste concrete powder increased. According to the test results, it is desirable to use waste concrete powder by combining OPC appropriately(below 15%).

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Durability of self compacted concrete containing slag in hot climate

  • Yahiaoui, Walid;Kenai, Said;Menadi, Belkacem;Kadri, El-Hadj
    • Advances in concrete construction
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    • v.5 no.3
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    • pp.271-288
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    • 2017
  • This paper aims to investigate the effects of replacing cement with ground granulated blast furnace slag (GGBFS) in self compacting concrete in the fresh and hardened state. The performance of SCC in moderate climate is well investigated but few studies are available on the effect of hot environment. In this paper, the effect of initial water-curing period and curing conditions on the performance of SCC is reported. Cement was substituted by GGBFS by weight at two different levels of substitution (15% and 25%). Concrete specimens were stored either in a standard environment (T=$20^{\circ}C$, RH=100%) or in the open air in North Africa during the summer period (T=35 to $40^{\circ}C$; R.H=50 to 60%) after an initial humid curing period of 0, 3, 7 or 28 days. Compressive strength at 28 and 90 days, capillary absorption, sorptivity, water permeability, porosity and chloride ion penetration were investigated. The results show that the viscosity and yield stress are decreased with increasing dosage of GGBFS. The importance of humid curing in hot climates in particular when GGBFS is used is also proved. The substitution of cement by GGBFS improves SCC durability at long term. The best performances were observed in concrete specimens with 25% GGBFS and for 28 days water curing.

A Study on the Water-Vapor Sorption of Resin Treated Viscose Rayon - Characterization by the GAB and BET Equations - (수지처리된 비스코스 레이온 섬유의 흡습성에 관한 연구 - BET, GAB식에 의한 해석 -)

  • Lee Mee Sik
    • Journal of the Korean Society of Clothing and Textiles
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    • v.14 no.1 s.33
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    • pp.13-19
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    • 1990
  • The water-vapor sorption isotherms of viscose rayon and of modified viscose rayon were studied to elucidate the change of sorptivity by the DMDHEU resin finish. To determine the sorption isotherms, moisture regains of the samples were measured at various humidities. The sorption isotherms were determined by the BET and GAB multilayer adsorption theories. The adsorption isotherm of the starting rayon was Brunauer Type II while with increasing resin content those of the DMDHEU-treated rayon became progressively more like Type IV. The DMDHEU-treated samples appeared to be hydrophilic due to the hydrophilicity of DMDHEU although moisture regains at higher humidities markedly decreased because of an impediment in swelling by crosslinkings. The $W_{m}$ value and surface area of crosslinked samples increased with increasing resin content. VR-R-6 which was the most heavily crosslinked viscose rayon had the highest $W_{m}$ and surface area values among all the samples. Relative sorption hysteresis was decreased as humidity increased for all samples. The untreated viscose rayon appeared to have a higher value than the DMDHEU-treated rayon.

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Permeability and mechanical properties of binary and ternary cementitious mixtures

  • Sadrmomtazi, Ali;Tahmouresi, Behzad;Amooie, Morteza
    • Advances in concrete construction
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    • v.5 no.5
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    • pp.423-436
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    • 2017
  • Today, pozzolans are widely used in construction for various reasons such as technical and economic efficiency. In this research, in order to evaluate some of important properties of concrete, silica fume and fly ash have been used as a replacement for cement in different mass percentages. Concrete mixtures were made from a water-cement ratio of (0.45) and cured under similar conditions. The main focus of this study was to evaluate the permeability and mechanical properties of concrete made from binary and ternary cementitious mixtures of fly ash and silica fume. In this study permeability of concrete was studied by evaluating the sorptivity, water absorption, water penetration depth, electrical resistivity and rapid chloride permeability (RCP) tests. Mechanical properties of concrete were evaluated with compressive strength, splitting tensile strength and modulus of elasticity. Scanning electronic microscopy (SEM) was used to characterize the effects of silica fume and fly ash on the pore structure and morphology of concrete with cement based matrix. The results indicated that the incorporation of silica fume and fly ash increased the mechanical strength and improved the permeability of concrete.

ROLE OF SOILS IN THE DISPOSAL OF NUCLEAR WASTE

  • Lee, S.Y.
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.3
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    • pp.251-268
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    • 1986
  • Selecting a site for the safe disposal of radioactive waste requires the evaluation of a wide range of geologic, mineralogic, hydrologic, and physicochemical properties. Although highly diverse, these properties are in fact interrelated. Site requirements are also diverse because they are influenced by the nature of the radionuclides in the waste, for example, their half-lives, specific energy, and chemistry. A fundamental consideration in site selection is the mineralogy of the host rock, and one of the most ubiquitous mineral groups is clay minerals. Clays and clay minerals as in situ lithologic components and engineered barriers may playa significant role in retarding the migration of radionuclides. Their high sorptivity, longevity (stability), low permeability, and other physical factors should make them a very effective retainer of most radionuclides in nuclear wastes. There are, however, some unanswered questions. For example, how will their longevity and physicochemical properties be influenced by such factors as radionuclide concentration, radiation intensity, elevated temperatures, changes in redox condition, pH, and formation fluids for extended periods of time? Understanding of mechanisms affecting clay mineral-radionuclide interactions under prevailing geochemical conditions is important; however, the utilization of experimental geochemical information related to physicochemical properties of clays and clay-bearing materials with geohydrologic models presents a uniquely challenging problem in that many assessments have to be based on model predictions rather than on experiments. These are high-priority research investigations that need to be addressed before complete reliance for disposal area performance is made on clays and clay minerals.

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Effect of steel fibres and nano silica on fracture properties of medium strength concrete

  • Murthy, A. Ramachandra;Ganesh, P.
    • Advances in concrete construction
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    • v.7 no.3
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    • pp.143-150
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    • 2019
  • This study presents the fracture properties of nano modified medium strength concrete (MSC). The nano particle used in this study is nano silica which replaces cement about 1 and 2% by weight, and the micro steel fibers are added about 0.4% volume of concrete. In addition to fracture properties, mechanical properties, namely, compressive strength, split tensile strength, and flexural strength of nano modified MSC are studied. To ensure the durability of the MSC, durability studies such as rapid chloride penetration test, sorptivity test, and water absorption test have been carried out for the nano modified MSC. From the study, it is observed that significant performance improvement in nano modified MSC in terms of strength and durability which could be attributed due to the addition pozzolanic reaction and the filler effect of nano silica. The incorporation of nano silica increases the fracture energy about 30% for mix without nano silica. Also, size independent fracture energy is arrived using two popular methods, namely, RILEM work of fracture method with $P-{\delta}$ tail correction and boundary effect method. Both the methods resulted in nearly the same size-independent $G_F$ irrespective of the notch to depth ratio of the same specimen. This shows evidence that either of the two procedures could be used in practice for analysis of cracked concrete structures.

Mechanical and durability properties of fluoropolymer modified cement mortar

  • Bansal, Prem Pal;Sidhu, Ramandeep
    • Structural Engineering and Mechanics
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    • v.63 no.3
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    • pp.317-327
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    • 2017
  • The addition of different types of polymers such as SBR, VAE, Acrylic, etc. in concrete and mortar leads to an increase in compressive, tensile and bond strength and decrease in permeability of polymer modified mortar (PMM) and concrete (PMC). The improvement in properties such as bond strength and impermeability makes PMM/PMC suitable for use as repair/retrofitting and water proofing material. In the present study effect of addition of fluoropolymer on the strength and permeability properties of mortar has been studied. In the cement mortar different percentages viz. 10, 20 and 30 percent of fluoropolymer by weight of cement was added. It has been observed that on addition of fluoropolymer in mortar the workability of mortar increases. In the present study all specimens were cast keeping the workability constant, i.e., flow value $105{\pm}5mm$, by changing the amount of water content in the mortar suitably. The specimens were cured for two different curing conditions. Firstly, these were cured wet for one day and then cured dry for 27 days. Secondly, specimens were cured wet for 7 days and then cured dry for 21 days. It has been observed that compressive strength and split tensile strength of specimens cured wet for 7 days and then cured dry for 21 days is 7-13 percent and 12-15 percent, respectively, higher than specimens cured one day dry and 27 days wet. The sorptivity of fluoropolymer modified mortar decreases by 88.56% and 91% for curing condtion one and two, respectively. However, It has been observed that on addition of 10 percent fluoropolymer both compressive and tensile strength decreases, but with the increase in percentage addition from 10 to 20 and 30 percent both the strengths starts increasing and becomes equal to that of the control specimen at 30 percent for both the curing conditions. It is further observed that percentage decrease in strength for second curing condition is relatively less as compared to the first curing condition. However, for both the curing conditions chloride ion permeability of polymer modified mortar becomes very low.