• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2000.11a
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• pp.55-60
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• 2000

현재 석탄화력발전 분야에서 석탄의 효율적인 이용을 목적으로 Pressurized Fluidized Bed Combined cycle(PFBC)과 Integrated Gasification Combined cycles(IGCC) 둥이 연구개발되고 있다. 특히, 가압유동층 복합발전 시스템은 석탄의 직접연소 방식으로 가격경쟁력이 있고, 신뢰성이 우수하며, 환경 친화적인 발전기술이다.(중략)

• Proceedings of the Korean Ceranic Society Conference
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• 2003.04a
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• pp.204.1-204
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• 2003

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2007.11a
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• pp.246-249
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• 2007

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.124.2-124
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• 2003

• Proceedings of KOSOMES biannual meeting
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• 2017.04a
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• pp.206-206
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• 2017

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.11a
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• pp.61-66
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• 1999

화석 연료중 석탄을 가장 경제적이고, 환경친화적으로 이용하는 신발전기술로 석탄가스 복합발전(IGCC)이 있으며, 이러한 신발전 기술의 핵심은 석탄가스화와 석탄가스 중에 있는 불순물을 제거하는 정제 기술이다. 현재 저온정제와 기존의 복합발전 시스템을 이용한 1세대 IGCC는 상용단계에 있으며 열효율은 40% 전후이다. 이런 IGCC의 발전 단가를 줄이고 열효율을 45%이상 증가시켜 타 발전기술과 경쟁력을 갖추기 위해서는 고온고압에서 석탄가스 중에 있는 불순물을 제거하는 고온정제기술(hot gas cleanup)은 필수적이다.(중략)

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.05a
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• pp.33-38
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• 1999

CCT(Clean Coal Technology)의 응용분야인 IGCC, PFBC 및 MCFC 등 석탄을 이용한 새로운 발전기술에 활용될 것으로 예견되는 고온건식 탈황기술은 고온(35$0^{\circ}C$~$650^{\circ}C$)과 고압(약 20기압)상태에서 금속 산화물로 된 고체흡수제(고온건식 탈황제)를 이용하여 반응기(유동층, 고속유동층 및 고정층과 이동층 반응기 등)에서 흡수와 재생반응을 통하여 석탄가스중에 있는 H$_2$S 등 황화물을 효율적으로 제거하는 기술이다.(중략)

• Clean Technology
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• v.9 no.4
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• pp.179-187
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• 2003

The technology of fluidized bed to use dry sorbent can be new technology that reduce the operating cost and make efficient operation. Therefore, this study investigated $CO_2$ control by dry sorbents with operating variables in a fluidized bed, compared with fixed bed for $CO_2$ adsorption capacity and pressure drop, and presented the $CO_2$ adsorption capacity of activated carbon, molecular sieve 5A, molecular sieve 13X, and activated alumina. As the results of this study, the basic data could be achieved for operation of fluidized bed process, and fluidized bed process presented relatively high $CO_2$ adsorption capacity and low pressure drop with the increase of gas velocity. In addition, molecular sieve 5A showed 1.1~3.0-fold later breakthrough point and 1.1~2.7-fold higher adsorption capacity than the other dry sorbents.

• Journal of Energy Engineering
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• v.5 no.2
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• pp.123-130
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• 1996

Reduction, sulfidation, and regeneration reactions were performed using domestic and Australian iron ore in order to develop a desulfurizing sorbent for the high temperature desulfurization process that is one of major processes in the integrated coal gasification combined cycle (IGCC) system. A TGA (Thermogravimetric Analysis) reactor and a fixed-bed reactor were used. Some basic kinetic information was obtained from BET surface area measurements, SEM photos, cyclic reactions, reaction temperature changes and TGA curves of the sorbents. The rates of both desulfurization and regeneration increased with increasing reaction temperature in the range of 500-700$^{\circ}C$.

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.80-85
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• 2016

The carbon dioxide adsorption behavior of silica with a large specific surface area and pore volume functionalized with aminosilane compounds via in-situ polymerization and functionalization method were investigated. The organosilanes include amino functional group capable of adsorbing carbon dioxide. Elemental analyzer, in situ FT-IR and thermogravimetric analyzer were used to characterize the sorbents and to determine their $CO_2$ adsorption behavior. Comparison of different aminosilane loading in the support revealed that polyaminosilane functionalization of 70% of the pore volume in the support was better in terms of the adsorption capacity and amine efficiency than that of 100% of the pore volume of the support. Furthermore, the sorbents showed a higher adsorption capacity at an adsorption temperature of $75^{\circ}C$ than at $30^{\circ}C$ due to the thermal expansion of synthesized polyaminosilanes inside the pore of silica. The N-[3-(trimethoxysilyl)propyl]ethylenediamine (2NS) sorbent with 70% of the pore volume functionalized showed the highest adsorption capacity of 9.2 wt% at $75^{\circ}C$.