• Journal of the Korean Society of Combustion
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• v.8 no.2
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• pp.41-49
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• 2003

Ultrasonic field of 28kHz with sound pressure level 162dB has been employed to agglomerate the fine soot particle produces in a diffusion flame in a chamber. The agglomeration process has been investigated with digital camcorder and analysed in terms of the decrease of number density with exposure time. From the observation of agglomeration process, the initial agglomeration has been carried out during the short time, and it has been dominated by the orthokinetic collision. Thereafter, a slower agglomeration mechanism, driven by acoustic streaming in the chamber takes over and agglomeraters grew to diameters of several millimeters were levitated at the pressure node of the acoustic wave. And, the circular disk shape of large agglomeraters with the rotational and translational motion is observed.

• Journal of Korean Society for Atmospheric Environment
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• v.31 no.3
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• pp.255-268
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• 2015

Single particle soot photometer (SP2) is an advanced instrument capable of real-time measurement of concentration, coating thickness, and size distribution of individual BC particle using laser-induced incandescence. So far, there have been insufficient studies examining the real-time characteristics of BC in Korea. In this study, we examined temporal variations in BC concentration and mass size distribution of BC in volume equivalence diameter at a background site of Aewol, Jeju in May. Average concentration and mass median diameter (MMD) of BC particles measured during the study period (06~ 16 May 2013) were $0.69{\pm}0.48{\mu}g/m^3$ and $196{\pm}17nm$, respectively. The BC concentration measured in Aewol was very similar to that observed in the spring of 2012 in Baengnyeong island, and showed diurnal profiles similar to those in other background areas. MMD of BC ranged from 172 to 222 nm. It was found that the mass size distribution of BC varied depending on the location (ground-based), season, types of air masses, and altitude (aircraft-based).

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.6
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• pp.98-104
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• 2010

An experimental investigation was conducted to analyze the effects of EGR ratio on the combustion, exhaust emissions characteristics and size distributions of particulate matter in a single cylinder diesel engine with common-rail injection system fueled with biodiesel derived from soybean. In order to analyze the combustion, exhaust emissions and measurement of size distributions of particulate matter were carried out under various EGR ratio which was varied from 20~60% and the results were compared to those of results without EGR. The experimental results show that ignition delay was extended and maximum value of rate of heat release (ROHR) was decreased according to increasing of EGR ratio. In addition, oxidies of nitrogen ($NO_x$) emissions were reduced but soot emissions were increased under increasing of EGR ratio. However, under higher EGR ratio region, soot was slightly decreased. And then the particulate size distribution shows that high exhaust gas temperature restrain the formation of soluble organic fraction (SOF) which were beyond the accumulation mode (100~300nm) and lead to increase of nuclei mode particles.

• Journal of ILASS-Korea
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• v.22 no.4
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• pp.197-202
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• 2017

The objective of this study is to investigate the effects of low-temperature combustion (LTC) on the correlations of combustion characteristics and reduction of exhaust emissions in a small DI diesel engine with biodiesel fuel. In order to analyze the combustion, exhaust emission characteristics and distribution of nano size particles for biodiesel were investigated. In addition, to evaluate the effect of LTC on the combustion and emission characteristics, 30 and 50% of cooled-EGR rates were investigated. From these results, it revealed that the influence of LTC on the combustion characteristics showed that the ignition delay significantly increased and reduces peak heat release rate of premixed combustion by lowering reaction rate. With 50% EGR and advanced injection timing, soot and $NO_x$ emissions were simultaneously reduced.

• The Journal of the Korea institute of electronic communication sciences
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• v.8 no.11
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• pp.1617-1624
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• 2013

This paper analyzes the relation between fire shutters and fire spread by conducting fire simulation on inner space with fire shutters. Using Fire Dynamics Simulator (FDS), a commercial fire simulation software, the simulation is done on an ideal inner robby, where fire size and the open/close of fire shutters are varied. Our simulation environment can derive significant fire parameters such as temperature variation of fire room walls and entrances of refuge stairs, variation of carbon dioxide, and soot spread. According to the simulation results, temperature and carbon dioxide distribution in refuge stairs have little dependence on vent open or close, but the part close of fire shutters blocks soot inflow to refuge stairs.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.5
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• pp.61-66
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• 2009

An experimental investigation was conducted to analyze the effects of biodiesel-ethanol and biodiesel-diesel blended fuels on the characteristics of combustion and exhaust emissions, and size distributions of particulate matter in a single cylinder diesel engine. The three types of test fuel were biodiesel and two blended fuels which were added ethanol and diesel by 20 % volume based fraction into biodiesel, respectively. In this study, the injection rate, combustion pressure, exhaust emissions and size distributions of particulate matter were measured under various injection timings and injection pressures. The experimental results show that biodiesel-ethanol blended fuel has lengthened ignition delay and low combustion pressure in comparison with those of biodiesel and biodiesel-diesel blended fuel even if all fuels indicated similar trends of injection rate under equal injection pressures. In addition, the ethanol blended fuel significantly reduced nitrogen oxidies (NOx) and soot emissions. And then the size distribution of particulate matters shows that blended fuels restrain the formation of particles which were beyond the range of 150nm comparison with biodiesel fuel.

• Fire Science and Engineering
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• v.31 no.6
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• pp.8-15
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• 2017

Most fire victims succumb to smoke inhalation, and fire smoke toxicity from interior materials is increasing with increased use of plastics. Large amounts of hazardous effects of smoke are related to deposition of smoke particles in respiratory tracts, and deposition characteristics are influenced by size distribution of particles. Thus, it is essential to know the size distribution of smoke particles from plastics for hazard analysis of fire smoke. In a recent study, it has been shown that size distributions of smoke particles from PP are different from wood in many aspects. In order to know whether other plastics show the same characteristics as PP, size distributions of smoke particles from four plastic materials (LDPE, PA66, PMMA, and PVC) were measured in real time under each fire type with various temperature and oxygen supply. In this study, smoke particles from different plastics were generated uniformly by using steady-state tube furnace method provided in ISO/TS 19700. Their size distributions were measured by using an electrical low pressure impactor (ELPI). Results of measurements showed that size distributions of smoke particles from these four plastic materials were similar to those from PP in many aspects. However, they were distinctively different from those of wood.

• 한국연소학회:학술대회논문집
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• 1997.06a
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• pp.61-68
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• 1997

The morphology and size distribution of chromium oxides and the concentration measurement of atomic arsenic have been studied in laminar diffusion flames. Nitrogen was added to vary flame temperatures in hydrogen flames. Ethene flames were used in order to investigate the potential for interaction between the soot aerosol that is formed in these flames and the chromium aerosol. Two sources of chromium compounds were introduced: chromium nitrate and chromium hexacarbonyl. A detailed investigation of the morphology was carried out by scanning electron microscopy (SEM). The amounts of Cr(VI) and total Cr were determined by a spectrophotometric method and by X-ray fluorescence spectrometry, respectively. Also, LIF was used for the measurement of atomic arsenic, which was excited at 197.2 nm and was detected at 249.6 nm. Results showed that the morphology of the particles varied with the flame temperature and with the chromium source. The particles were characterized by porous structures, cenospheres and agglomerated dense particles when chromium nitrate solution was added to the flames. At low to moderate temperatures, porous sintered cenospheric structures were formed, in some cases with a blow hole. At higher temperatures, an agglomerated cluster which was composed of loosely sintered submicron particles was observed. It was also found that the emission of Cr(VI) from the undiluted $H_2$ flame was more than 10 times larger than in the 50% $H_2$ / 50% $N_2$ flame on a mass basis. Single point LIF measurement of atomic arsenic indicated that arsenic exist only in the low temperature, fuel rich region.

• Asian Journal of Atmospheric Environment
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• v.6 no.4
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• pp.288-303
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• 2012

In this study, real time measurements of particle number size distribution in urban Gwangju, coastal Taean, and industrial Yeosu in Korea were conducted in 2008 to understand the occurrence of ultrafine particle (UFP) (<100 nm) events, the variation of its concentration among different sampling sites, and UFP formation pathways. Also, to investigate seasonal and long-term variation of the UFP number concentration, data were collected for the period of 5 years (2007, 2008, 2010, 2011, and 2012) in urban Gwangju. Photochemical and combustion events were found to be responsible for the formation of UFP in the urban Gwangju site, whereas only photochemical event led to the formation of UFP in the coastal Taean site. The highest UFP concentration was found in industrial Yeosu (the average UFP number fractions were 79, 59 and 58% in Yeosu, Gwangju, and Taean, respectively), suggesting that high amount of gas pollutants (e.g., $NO_2$, $SO_2$, and volatile organic carbon (VOC)) emitted from industries and their photochemical reaction contributed for the elevated UFP concentration in the industrial Yeosu site. The UFP fraction also showed a seasonal variation with the peak value in spring (61.5, 54.5, 50.5, and 40.7% in spring, fall, summer, and winter, respectively) at urban Gwangju. Annual average UFP number concentrations in urban Gwangju were $5.53{\times}10^3\;cm^{-3}$, $4.68{\times}10^3\;cm^{-3}$, $5.32{\times}10^3\;cm^{-3}$, $3.99{\times}10^3\;cm^{-3}$, and $2.16{\times}10^3\;cm^{-3}$ in the year 2007, 2008, 2010, 2011, and 2012, respectively. Comparison of the annual average UFP number concentration with urban sites in other countries showed that the UFP concentrations of the Korean sites were lower than those in other urban cities, probably due to lower source strength in the current site. TEM/EDS analysis for the size-selected UFPs showed that the UFPs were classified into various types having different chemical species. Carbonaceous particles were observed in both combustion (soot and organics) and photochemical events (sulfate and organics). In the photochemical event, an internal mixture of organic species and ammonium sulfate/bisulfate was identified. Also, internal mixtures of aged Na-rich and organic species, aged Ca-rich particles, and doughnut shaped K-containing particles with elemental composition of a strong C with minor O, S, and K-likely to be originated from biomass burning nearby agricultural area, were observed. In addition, fly ash particles were also observed in the combustion event, not in the photochemical event.

• Journal of Environmental Impact Assessment
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• v.28 no.2
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• pp.113-128
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• 2019

The concentration and coating thickness of black carbon (BC) were measured along with fine dust in the fall of 2018, at the Seoul Metropolitan Area Intensive Monitoring Station (SIMS). In fall, the concentration of $PM_{10}$ and $PM_{2.5}$ was $23{\pm}12.6{\mu}g/m^3$ and $12{\pm}5.8{\mu}g/m^3$, respectively, lower than that in other seasons. The BC level, measured using an Aethalometer, was $0.73{\pm}0.43{\mu}g/m^3$, while the levels of elemental carbon (EC) and refractory-BC (rBC), measured by semi-continuous carbon analyzer (SOCEC) and single particle soot photometer (SP2), were $0.34{\pm}0.18{\mu}g/m^3$ and $0.32{\pm}0.18{\mu}g/m^3$, respectively. As such, the concentration level differed according to the measurement method, but its time-series distribution and diurnal variation showed the same trends. The BC concentration at SIMS was primarily affected by automobiles with higher levels of BC during morning and evening commuting times due to increased traffic congestion. rBC, measured by SP2, had a peak concentration and coating thickness of 84 nm and 43 nm, respectively. Notably, the coating thickness had an inverse relationship with particle size.