• Title/Summary/Keyword: Solution-evaporation

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Alternative Method for the Treatment of Chemical Wastes Containing Uranium (우라늄함유 화학폐수의 적정처리 기술)

  • Kim Kil-Jeong;Shon Jong-Sik;Hong Kwon-Pyo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.2
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    • pp.179-186
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    • 2006
  • Chemical wastes are generated from nuclear facilities and R&D laboratories, but the uranium concentration in the final dried cake is evaluated into 11.2 Bq/g, which exceeds the exemption level of 10 Bq/g for each U isotopes, so the cake is categorized into a radioactive waste. Acid dissolution was applied to extract uranium from the waste sludge, and uranium adsorption on the dissolved solution was experimented by using IRN-77 and Diphosil bead. A large amount of resin was required to get above 80% of uranium removal, which was found to be due to a large amount of metal ions simultaneously dissolved from the precipitates with uranium. As an alternative method, acid dissolution is applied to the dewatered wet cake of the sludge, and the natural evaporation method is adopted for the dissolved solution. The uranium concentration of the dissolved solution was estimated to be 6.97E-01 Bq/ml, and the specific activity of the final waste sheets is evaluated to be 4.3 Bq/g. These results lead to the suggestion that the application of acid dissolution to the wet cake and the natural evaporation for the dissolved solution is an effective treatment method for chemical wastes containing uranium.

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A Study on Heat and Mass Transfer in a Vertical Tube Absorber Using LiBr Family Solutions (LiBr계 용액을 사용한 수직관 흡수기의 열 및 물질 전달에 관한 연구)

  • Cho, H.C.;Kim, C.B.;Jeong, S.Y.;Kang, S.W.;Lee, C.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.2
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    • pp.196-206
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    • 1995
  • Experimental investigations on heat and mass transfer characteristics in a vertical tube absorber have been carried out. Three different copper tubes with a length of 1.5m have been tested using LiBr solution and LiBr-$CaCl_2$ solution. The effects of solution flow rate, cooling water temperature, solution inlet temperature and evaporation temperature have been investigated in detail. It is found that heat transfer coefficient increases gradually with the increase of solution flow rate, but decreases rapidly for the flow rates less than 0.02kg/ms. The grooved tube generally shows better heat transfer performances than the smooth tube. LiBr solution shows almost no absorption capability for the cooling water temperatures over $40^{\circ}C$. LiBr-$CaCl_2$ gives less decreasing rate in absorption capability at these temperatures and the heat transfer coefficient becomes less dependent on the types of tubes in use. Considering heat and mass transfer rates, LiBr-$CaCl_2$ solution is found to be more suitable than LiBr solution for air cooled absorber, which operates at higher temperature than water cooled absorber.

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The Evaluation of Heat Flux by Evaporating Droplet on the Hot Surface (고온 표면에 부착된 증발 액적에 의한 열유속 변화 추정)

  • Shin, Woon-Chul;Bae, Sin-Chul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.9
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    • pp.764-771
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    • 2007
  • The objective of the present work is to evaluate the evaporation heat flux of deposited droplet on the hot surface by using of inverse heat transfer technique. On the basis of measured temperature, a integral form solution is determined for the transient temperatures beyond the two positions by using Green's function technique. This method first approximates the temperature data with a half polynomial series of time. we compared this result with constant radius model in single phase regime, nucleate boiling regime, film boiling regime respectively. this paper performed the experiments as following conditions: (a)the surface temperature is within the range between $80^{\circ}C\;and\;160^{\circ}C$ in the conduction, (b) droplet diameter are 2.4 and 3.0mm. (c) surface roughness is $0.18{\mu}m$.

An experimental study on the mixing of evaporating liquid spray with duct flow (덕트 유동에서 증발을 수반하는 액상 스프레이의 혼합 특성에 대한 실험적 연구)

  • Kim, Young-Bong;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.93-96
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    • 2005
  • High temperature furnace such as Steam power plant and incinerator contribute considerable part of NOx generation and face urgent demand of De-NOx system. Reducing agents are necessary to use De-NOx system. In this study mixing caused by direct injection of reducing agent solution spray into flue gas duct was measured. Carbonated water was used as tracer and simulated agent because ammonia as a reducing agent is not proper to experiment. Mixing and evaporation must occur simultaneously and quickly enough to achieve desirable efficiency. To achieve that, the angle of attack of static mixer and the location is simulated and $CO_2$ concentration is measured.

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Investigation on Behavior of HAN-based Propellant Droplet at High Temperature (고온에서 HAN 계열 추진제 액적의 거동에 대한 연구)

  • Hwang, Chang Hwan;Baek, Seung Wook;Han, Cho Young;Kim, Su Kyum;Jeon, Hyung Yeol
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.329-332
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    • 2012
  • The droplet behavior of 83.9 wt.% HAN water solution was investigated experimentally with various ambient temperature and nitrogen environment. At the initial stage of evaporation under thermal decomposition temperature of HAN, gradual decreasing of droplet diameter was observed. After that, the droplet started to expand due to the internal pressure build up by water nucleation inside the droplet. The micro explosion was observed at higher temperature than the decomposition temperature of HAN and the remaining droplet showed similar behavior of single composition droplet. The decreasing rate was augmented as the ambient temperature increasing.

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Derivation of Cubic and Hexagonal Mesoporous Silica Films by Spin-coating

  • Pan, Jia-Hong;Lee, Wan-In
    • Bulletin of the Korean Chemical Society
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    • v.26 no.3
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    • pp.418-422
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    • 2005
  • By introducing spin-coating method to the evaporation induced self-assembly (EISA) process, a simple and reproducible route in controlling the mesophase of silica thin films has been developed for the first time in this work. When a comparatively solvent-rich Si-sol (The atomic ratio of TEOS : F127 : HCl : $H_2O$ : EtOH = 1 : 0.006 : 0.2 : 9.2 : 30) was used as coating solution, the mesophase of resultant silica films was selectively controlled by adjusting the spin-on speed. The cubic mesophase has been obtained from the coating at a low rpm, such as 600 rpm, while the 2-D hexagonal mesophase is formed at a high rpm, such as 2,500 rpm. At a medium coating speed, a mixture of cubic and hexagonal mesophase has been found in the fabricated films. The present results confirm that the evaporation rate of volatile components at initial step is critical for the determination of mesopore structures during the EISA process.

A Study on Development of PLD Process for PM OLED Device Manufacture (PM OLED 디바이스 제작을 위한 PLD 공정 개발에 관한 연구)

  • Lee, Eui-Sik;Lee, Byoung-Wook;Kim, Chang-Kyo;Hong, Jin-Su;Park, Sung-Hoon;Moon, Soon-Kwun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.264-266
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    • 2005
  • Manufacture of OLED device used thermal evaporation method. However thermal evaporation method has many defect as thermal damage of substrate, difficult of dopant rate control and low utilization of organic materials. so we suggest PLD(Pulsed Laser Deposition) method that solution of these problems. PLD method has many advantage as without thermal damage, easy indicate of deposition rate per one pulse and good utilization of organic materials. In this paper we apply the PLD method for manufacture of device so we present high efficiency device manufacture using PLD method that has good deposition uniformity, surface rough and deposition rate.

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A numerical analysis of precipitation recharge in the region of monsoon climates using an infiltration model

  • Koo, Min-Ho;Kim, Yongje
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.163-167
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    • 2003
  • Based on the transient finite difference solution of Richards' equation, an infiltration model is developed to analyze temporal variation of precipitation recharge in the region of monsoon climates. Simulation results obtained by using time series data of 20-year daily precipitation and pan evaporation indicate that a linear relationship between the annual precipitation and the annual recharge holds for the soils under the monsoon climates with varying degrees of the correlation coefficient depending on the soil types. A sensitivity analysis reveals that the water table depth has little effects on the recharge for the sandy soil, whereas, for the loamy and silty soils, rise of the water table at shallow depths causes increase of evaporation by approximately 100㎜/yr and a corresponding decrease in recharge. A series of simulations for two-layered soils illustrate that the amount of recharge is dominantly determined by the soil properties of the upper layer, although the temporal variation of recharge is affected by both layers.

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The Experimental Study of Early Fuel Evaporation Characteristics Gasoline Engine Using Glow-Plug (Glow-Plug를 이용한 가솔린 연료의 조기증발 특성 실험 연구)

  • 문영호;김진구;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.2
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    • pp.1-10
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    • 2001
  • In order to reduce hydrocarbon emissions of spark ignition engine, it is important not only to improve catalyst conversion efficiency but also to reduce direct engine out hydrocarbon emissions, during cold starting and warm up process. Tjerefore many researchers have been attracted to develop an early fuel evaporator (EFE) by introducing a ceramic heater for a solution of engine out hydrocarbon emissions in SI engine. But, the performance of the EFE in MPI engine to reduce the exhaust emissions and to improve the cold startability has nat been clarified yet. The purpose of this study is to evaluate the feasibility of a glow plug for EFE.

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Distribution of the Concentration of Fuel Vapor in DI Gasoline Sprays Under Evaporation Condition (증발 조건에서 직분식 가솔린 분무의 증기 농도의 분포)

  • Hwang, S.C.;Choi, D.S.;Cha, K.J.;Kim, D.J.
    • Journal of ILASS-Korea
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    • v.4 no.4
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    • pp.1-8
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    • 1999
  • The concentration and spatial distribution of vapor phases in DI (Direct Injection) gasoline spray were measured quantitatively by exciplex fluorescence method. Fluorobenzene and DEMA (diethylmethylamine) in a solution of hexane were used as the exciplex-forming dopants. The fluorescence intensity of vapor phase were obtained by ICCD camera with the appropriate filter The relationship between fluorescence intensity and vapor concentration was induced fer the purpose of a quantitative analysis. The 2-D vapor/liquid images of fuel spray were captured under the evaporation condition, and the spatial distribution of vapor concentration was obtained. The spatial distribution of liquid phase had hollow-cone shape. And the vapor phase was widely distributed in the whole spray. The behavior of vapor phase was significantly affected by second flow such as entrainment, vortex, while that of liquid phase was scarcely affected.

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