• Nuclear Engineering and Technology
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• 제39권6호
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• pp.731-736
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• 2007

Radioactive organic wastes containing acetone, alcohol, and particularly tributyl phosphate (TBP)/dodecane contaminated with uranium are extracted from the PUREX process and the decontamination of related equipment. An evaporation method that utilizes existing DU oxidation apparatuses and ventilation systems and a typical muffle furnace installed with an aspirating system are adopted. A separation method using phosphoric acid especially for the TBP/dodecane waste is also studied and evaluated. The results show that a simple evaporation process is utilizable for wastes containing acetone or alcohol with a lower boiling point. A modified muffle furnace is more appropriate to dispose directly of organic wastes having a higher boiling point, such as TBP/dodecane, without generating a condensed waste solution. It is recommended that, when the uranium concentration of TBP/dodecane waste is much higher than stipulated levels, separation technology should be applied to remove uranium from the mixture. Each type of solvent after separation can then be considered disposable below the regulatory limit in the modified furnace discussed in this study.

• 반도체디스플레이기술학회지
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• 제2권1호
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• pp.25-29
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• 2003

The fluid flow, mass transfer, heat transfer and film thickness variation during the spin coating process are numerically studied. The model is said to be I-dimensional because radial variations in film thickness, concentration and temperature are ignored. The finite difference method is employed to solve the equations that are simplified using the similarity transformation. In early time, the film thinning is due to the radial convective outflow. However that slows during the first seconds of spinning so the film thinning due to evaporation of solvent becomes sole. The time varing film thickness is analyzed according to the wafer spin speed, the various solvent fraction in the coating liquid, and the various solvent vapor fraction in the bulk of the overlying gas during the spin coating is estimated.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.376-376
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• 2011

I-III-VI2 chalcopyrite compounds, particularly copper, indium, gallium selenide(Cu(InxGa1-x)Se2, CIGS), are effective light-absorbing materials in thin-film solar application. They are direct band-gap semiconductors with correspondingly high optical absorption coefficients. Also they are stable under long-term excitation. CIS (CIGS) solar cell reached conversion efficiencies as high as 19.5%. Several methods to prepare CIS (CIGS) absorber films have been reported, such as co-evaporation, sputtering, selenization, and electrodeposition. Until now, co-evaporation is the most successful technique for the preparation of CIS (CIGS) in terms of solar efficiency, but it seems difficult to scale up. CIS solar cells have been hindered by high costs associated with a fabrication process. Therefore, inorganic colloidal ink suitable for a scalable coating process could be a key step in the development of low-cost solar cells. Here, we will present the preparation of CIS photo absorption layer by a solution process using novel metal precursors. Chalcopyrite copper indium diselenide (CuInSe2) nanocrystals ranging from 5 to 20nm in diameter were synthesized by arrested precipitation in solution. For the fabrication of CIS photo absorption layer, the CuInSe2 colloidal ink was prepared by dispersing in organic solvent and used to drop-casting on molybdenum substrate. We have characterized the nanoparticless and CIS layer by XRD, SEM, TEM, and ICP.

• Membrane and Water Treatment
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• 제13권3호
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• pp.139-145
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• 2022

Development in advanced separation processes leads to the significant advancement in polymeric membrane preparation methodology. Therefore, present research investigated the preparation and characterization of cellulose acetate membrane by phase inversion separation method to determine optimized operating parameters. Prepared CA membrane's performance was been analyzed in terms of % rejection and flux. Investigation was conducted to study effect of different parameters such as polymer concentration, evaporation rate, thickness of film, coagulation bath properties, temperature of polymer solution and of the coagulation bath etc. CA membrane was fabricated by taking polymer concentration 10wt% and 11wt% with zero second evaporation time and varying film thickness over non-woven polyester fabric. Effect of coagulation bath temperature (CBT) and casting solution temperature were also been studied. The experimental results from SEM showed that the surface morphology had been changed with polymer r concentration, coagulation bath and casting solution temperature, etc. Lower polymer concentration leads to lower precipitation time giving porous membrane. The prepared membrane was tested for advanced waste water treatment of relevant effluent stream in pilot plant to study flux and rejection behavior of the membrane.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2006년도 하계학술발표대회 논문집
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• pp.743-748
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• 2006

Ren et al. analyzed the performance of the indirect evaporative cooler according to the direction of the flow considering evaporation water flow and wetness. However the effect of NTU of each channel on the performance of the indirect evaporative cooler according to the direction of the flow was not analyzed exactly. In this study the effect of the direction of the flow on the Indirect evaporative cooling performance changing NTU of each channel are investigated theoretically. The cooling process of the indirect evaporative cooler by flow direction is modeled into a set of linear differential equations and solved to obtain the exact solutions to the temperatures of the hot fluid, the moist air, and evaporation water. Based on the exact solution in the case of different NTU of each channel, we study the change of the distribution of the temperature according to each flow direction and at the same time analyze the effect of the flow direction on the cooling performance.

• 한국표면공학회지
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• 제29권6호
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• pp.862-868
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• 1996

Cadmium sulfide is commonly used as the window material for thin film solar cells, and can be prepared by several techniques such as sputtering, spray pyrolysis, close spaced sublimation (CSS), thermal evaporation, solution growth methods, etc. In this study, CdS films were deposited by thermal evaporation, close spaced sublimation, and solution growth methods, respectively, and the effects of the methods on physical properties of polycrystalline CdS deposited on ITO/glass were investigated. Also, the effects of variously prepared CdS thin films on the physical properties of CdTe deposited on the CdS were investigated. The thickness of polycrystalline CdS films was maintained at $0.3\mu\textrm{m}$ except for the solution grown CdS when $0.2\mu\textrm{m}$ thick CdS was deposited. After the deposition, all the samples were annealed at $400^{\circ}C$ or $500^{\circ}C$ in H2 atmosphere. To investigate physical properties of the deposited and annealed CdS thin films, UV-VIS spectro-photometry, X-ray diffractometry (XRD), and Auger electron spectroscopy (AES), and cross sectional transmission electron microscopy(XTEM) were used to analyze grain size, crystal structure, preferred orientation, optical properties, etc. The annealed CdS showed the bandedge transition at 510nm and the optical transmittance high than 80% for all of the variously deposited films. XRD results showed that CdS thin films variously deposited and annealed had the same hexagonal structures, however, showed different preferred orientations. CSS grown CdS had [103] preferred orientation, thermally evaporated CdS had [002], and CdS grown by the solution growth had no preferred orientation. The largest grain size was obtained for the CSS grown CdS while the least grain size was obtained for the solution grown CdS. Some of the physical properties of CdTe deposited on the CdS thin film such as grain size at the junction and grain orientation were affected by the physical properties of CdS thin films.

• 태양에너지
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• 제18권3호
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• pp.185-195
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• 1998

본 연구는 태양열을 이용한 냉난방 공조시스템 개발 중 작동매체인 저농도의 염화리튬(lithium chloride) 용액을 고농도로 변환시키는 재생기의 최적 재생면을 파악하는 데 그 목적이 있다. 염화리튬 용액은 점성이 강하기 때문에 재생기의 상부로부터 하부로 유하될 때 편류(Channeling)현상을 발생하게 된다. 이 편류현상은 재생기에서의 열 및 물질전달을 방해하여 재생량을 감소시킨다. 결국 재생기의 성능, 나아가서는 태양열 이용 냉난방 공조시스템 전체의 성능이 염화리튬용액을 얼마나 균일하게 유하할 수 있는 가에 달렸다고 해도 과언은 아니다. 따라서 본 연구에서는 재생면의 다양한 형태와 구조를 고안해서 실제로 재생면을 제작하여 재생면의 최적 구조를 규명하였다. 실험을 위하여 가로 50cm, 세로 50cm 크기인 간이 재생기를 직접 제작하여 항온항습실에서 실험을 행하였다. 그 결과 평판 위에 높이 4.5mm 폭 10mm의 계단형 구조를 갖는 재생면에서 최대의 재생량을 얻을 수 있었다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1689-1691
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• 2006

DuPont Displays has developed a new solution printing fabrication process for OLED displays, using small molecule OLED materials. The new manufacturing process is more cost-effective and scalable than evaporation of materials through physical masks, and addresses issues associated with ink jet printing. A new material (DB) has been developed for use as a hole-injection layer in OLEDs.

• Journal of Yeungnam Medical Science
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• 제3권1호
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• pp.41-48
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• 1986

사람의 적혈구막으로부터 Band 3를 분리정제하고 이를 liposome 내로 도입시켜 그 결과를 관찰하였다. 적혈구를 약알칼리 저장액으로 용혈시켜 막을 분리한 후, 저이온강도 용액으로 처리하여 Band 4를 추출하였다. Triton X-100 추출액에 p-chloromercuribenzoate를 가하고 sucrose density gradient ultracentrifugation후 fractionation하여 Band 3를 정제하였다. phosphatidyl L-serine과 cholesterol을 1 : 1 molar ratio로 섞고 진공회전 증발기를 사용하여 chloroform을 제거한 후 Triton X-100을 제거한 Band 3용액을 가하고 sonication함으로 liposome(reverse-phase evaporation vesicle)을 만들면서 Band 3를 도입 시켰다 Band 3의 분리정제 및 liposome에 도입되었음은 sodium dodecyl sulfate-polyacrylamide gel 전기영 동 후 coomassie brilliant blue 염색으로 확인할 수 있었다.

• Korean Chemical Engineering Research
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• 제56권4호
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• pp.461-468
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• 2018

Poly-L-lactic acid (PLLA)를 출발물질로 하여 용매증발법에 의해 마이크로스피어를 제조하고, 제조 변수가 형성된 마이크로스피어의 형상 및 평균 입경에 미치는 영향을 살펴보았다. PVA 수용액의 농도가 1~5 wt%로 증가함에 따라 평균입경이 $370{\sim}160{\mu}m$으로 감소하다가 7 wt%에서다시 $240{\mu}m$으로 증가하였다. 그리고 PVA의첨가부피가 10~50 mL로 증가함에 따라 평균 입경은 $370{\sim}220{\mu}m$으로 감소하였다. 또한 교반속도가 500~1,500 rpm으로 증가함에 따라 평균 입경은 $370{\sim}110{\mu}m$으로 감소하였다. 유기용매로써 dichloromethane과 chloroform을 각각 사용한 경우 평균 입경은 큰 차이를 보이지 않았으며, dichloromethane을 사용한 경우 표면에서 공극이 확인되었으나 chloroform을 사용한 경우 매끈한 형상의 구형입자가 얻어졌다.