• Title/Summary/Keyword: Solution viscosity

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Solution Properties of ${\gamma}$-Polyglutamic Acid Produced by Alkalophilic Alcaligenes sp. (호 알칼리성 Alcaligenes sp.가 생산하는 ${\gamma}$-Polyglutamic Acid의 용액 특성)

  • 이신영;강태수김갑수
    • KSBB Journal
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    • v.10 no.4
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    • pp.386-392
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    • 1995
  • The high viscous ${\gamma}$-polyglutamic acid(${\gamma}$-PGA) from alkalophilic Alcaligenes sp. was purified and its solution property was investigated. The intrinsic viscosities for Na+ form and H+ form of ${\gamma}$-PGA were 31.1 and 0.38d$\ell$/g, respectively. The viscosity of H+-PGA was not influenced by pH or salts while that of Na+-PGA was influenced. The intrinsic viscosity of Na+-PGA solution decreased remarkably at the alkaline or acidic pH and showed the sharp decrease when salts were added. ${\gamma}$-PGA exhibited the property of the polyelectrolyte showing the .sharp decrease of intrinsic viscosity by the addition of NaCl, and intrinsic viscosity of dilute solution with the low concentration of NaCl was exponentially dependent on temperature and its temperature dependency increased with increasing NaCl concentration. The chain stiffness, coil overlap parameter and critical concentration of Na+-PGA were 0.08, 5.25 and 0.07g/d$\ell$, respectively.

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Pump Performance Analyses with High Viscosity Fluids (고점성용 펌프의 성능해석)

  • Roh, Hyung-Woon;Suh, Sang-Ho;Kim, Dong-Joo;Kim, Young-Dae
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.367-370
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    • 2003
  • In this study the effects of fluid viscosity on the pump performances of a conventional centrifugal pump were experimentally studied. The study aimed to compare the pump characteristics for water and high viscosity fluids. The Working fluids are water, aqueous sugar solution and glycerin solution. The pump characteristics of total head and efficiency with high viscosity fluids were different. The performance curves of efficiency for the sugar and glycerin solutions were decreased up to 8.1% and 12.9% than that of water.

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VISCOSITY METHODS OF APPROXIMATION FOR A COMMON SOLUTION OF A FINITE FAMILY OF ACCRETIVE OPERATORS

  • Chen, Jun-Min;Zhang, Li-Juan;Fan, Tie-Gang
    • East Asian mathematical journal
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    • v.27 no.1
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    • pp.11-21
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    • 2011
  • In this paper, we try to extend the viscosity approximation technique to find a particular common zero of a finite family of accretive mappings in a Banach space which is strictly convex reflexive and has a weakly sequentially continuous duality mapping. The explicit viscosity approximation scheme is proposed and its strong convergence to a solution of a variational inequality is proved.

Efficiency of Water Mist Suppression System Containing Viscosity Agent to Extinguish Wood Cribs Fire (증점제를 함유한 미분무수의 목재화재 소화효과)

  • Kim, Min Hyung;Shin, Changsub
    • Journal of the Korean Society of Safety
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    • v.29 no.4
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    • pp.78-84
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    • 2014
  • Viscosity agents were added to water to improve extinguishing performance of low pressure water mist suppression system on wood cribs fire, and a small scale wood cribs fire experiment was conducted to measure the extinguishing performance. CMC and agar were used for viscosity agent and as the amount of viscosity agent enlarges, it showed the increase of the viscosity of aqueous solution and the decrease of the fluidity. On wood cribs fire experiment, the extinguishing efficiency was improved with supplemental viscosity agent as it enhanced the adhesive time of aqueous solution on the wood, and therefore expanded the contact time of fire surface. The surface tension of aqueous solution was decreased with the addition of agar which to be assumed as an increase factor of extinguishing efficiency. By the extinguishing experimental result, the most effective extinguishing agent was CMC 0.6 wt.%, with the flame suppression time and the extinguishing time were reduced by 70s and 93s respectively at this concentration.

The Effect of Sample Handling on the Rheological Measurement of Regenerated Silk Fibroin Formic Acid Solution using Parallel Plate Geometry

  • Cho, Hee-Jung;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.22 no.1
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    • pp.5-10
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    • 2011
  • The effect of sample handling condition on the rheological measurement of regenerated silk fibroin formic acid solution using parallel plate geometry was investigated. In case of loading method, the loading by pouring sample solution resulted in the best reproducibility of rheological measurement. Loading with spoon showed a high variance of viscosity value at low shear rate region ($0.01{\sim}1sec^{-1}$) while loading with syringe exhibited a low reproducibility of viscosity at high shear region ($1{\sim}100sec^{-1}$) with a disappearance of shear thinning phenomenon. It was revealed that the sample loading with small extra amount lead to the most reproducible result. The sample loading with the exact amount for the measuring plate resulted in a lack of reproducibility of high shear viscosity, while the loading with large extra volume produced a limited consistency of low shear viscosity. It was turned out that 3 min. of waiting time before measurement was the optimum condition for reliable result. When the waiting time was less than 1 min., the low shear viscosity was obtained with a lack of consistency. On the other hand, the sample solution started drying when the waiting time increased up to 5 min.

Probe Diffusion and Viscosity Properties in Dimethyl Sulfoxide Solution of Poly(vinyl alcohol) with High Degree of Hydrolysis (고검화도의 폴리(비닐 알코올)/디메틸설폭사이드 용액에서의 점성도 특성과 탐침입자의 확산)

  • Eom, Hyo-Sang;Park, Il-Hyun
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.415-423
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    • 2010
  • Poly(vinyl alcohol)(PVA) with high degree of hydrolysis of above 98% was dissolved in dimethyl sulfoxide(DMSO), and the shear viscosity was measured up to $C{\simeq}0.14\;g/mL$ in the semi-dilute solution regime. Next, as probe particle, polystyrene(PS) latex was introduced into this matrix system and its delayed diffusion due to polymer concentration was investigated by means of dynamic light scattering. When the solution viscosity of PVA/DMSO was plotted against the reduced concentration $C[{\eta}]$, which is scaled by the intrinsic viscosity, the molecular weight dependence was strongly appeared at C$[{\eta}]$ >2. Some heterogeneties in polymer solution were considered as its source. Contrary, the diffusion of probe particle in the matrix solution was observed as a single mode motion at whole concentration range but its ratio of its diffusion coefficient at solution to that at solvent, D/Do did not show any molecular weight dependence at all. However, the application limit of the stretched exponential function was disclosed at C$[{\eta}]$ >2.5.

Preparation and Rheological Properties of Chitin and Chitosan -2. Effects of shear rate, temperature, concentration and salts on the viscosity of chitosan solution- (갑각류 외피의 유효이용을 위한 Chitin 및 Chitosan의 제조와 물성학적 특성에 관한 연구 -2. Chitosan 용액의 점도에 미치는 전단속도, 온도, 농도 및 염의 영향-)

  • LEE Keun-Tai;PARK Seong-Min;BAIK Oon-Doo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.4
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    • pp.397-400
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    • 1995
  • Effects of rheological parameters, such as shear rate, temperature, concerntration, salts on the apparent viscosity of chitosan(deacetylation degree: $84\%$, Mw: 267,000) dissolved in acetate buffer(pH 4.5) were investigated. Rheologiral properties of chitosan solution from cuticle of red snow crab (Chinonecetes japonicus) are as follows. $0.5\%$ chitosan in 0.1M acetate buffer (pH 4.5) solution showed Bingham flow having hysteresis loop. It's flow equation was $\sigma=0.757+19.6_\gamma(r^2=0.99)$. The viscosity of chitosan solution is exponentially increased with its concentration, and showed Arrhenius dependence with respect to the temperature $(10^{\circ}C-40^{\circ}C).$ When various salts were added to chitosan solution, the viscosity decreased as the concentration of counterion increased. But the type ot counterions itself does not have any significant effects on the viscosity.

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Dilute Solution Properties of Biopolymer Produced by Alkali-Tolerant Bacillus sp. (알칼리 내성 Bacillus Sp.에 의한 생물 고분자의 희석용액 특성)

  • Lee, Shin-Young;Kim, Jin-Young
    • Journal of Industrial Technology
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    • v.20 no.A
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    • pp.39-44
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    • 2000
  • Highly viscous biopolymer from alkali-tolerant Bacillus sp. was purified and its solution properties were investigated. The intrinsic viscosities for crude biopolymer and biopolymers purified by dialysis or CPC(cetylpyridinium chloride) treatment were 58.24, 73.60 and 42.18 dL/g, respectively. The intrinsic viscosity of biopolymer showed the maximum value at the neutral pH but it was decreased remarkably at the alkaline or acidic pH. Biopolymer exhibited the property of polyelectrolyte, showing the sharp decrease of intrinsic viscosity by the addition of NaCl. Intrinsic viscosity of dilute solution at the low NaCl concentration was exponentially dependent on temperature and its temperature dependency was increased with NaCl concentrations. The chain stiffness, coil overlap parameter, and critical concentration were 0.09, 5.25 and 0.07g/dL, respectively. Temperature dependency on intrinsic viscosity of biopolymer solution was different each other at $45^{\circ}C$. Flow activation energies at temperatures above $45^{\circ}C$ were constant, while those at temperatures below $45^{\circ}C$ increased with increase of added NaCl concentration.

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Method for Rapid and Accurate Measurement of Chitosan Viscosity

  • No, Hong -Kyoon;Samuel P. Meyers
    • Preventive Nutrition and Food Science
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    • v.4 no.2
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    • pp.85-87
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    • 1999
  • A simple and rapid method to estimate the viscosity of chitosan using laboratory pipettes was developed. The voscosities of nine different chitosan samples, prepared ini 1 % acetic acid at a 1% concentration , were measured with a standard viscometer. Prior to measurement of flow time of 1% chitosan solution with a pipette, twelve pipettes were assorted into three groups with flow times of 4, 5 and 6 sec after measuring passage of 9 ml of 1% acetic acid througth a 10 ml pipette. With each group of pipettes. flow time of 1% chitosan solution was determined by measuring the delivery time of 5 ml of the 10ml solution through a 10 ml pipette. Results of regression analyses revealed high linear relationship(R2=0.9812, 0.9663, and 0.9754) between viscosities calculated with a viscometer and flow times measured with 4, 5 or 6 sec group pipettes. The viscosity of chitosan could be readily and accurately estimated from these linear regression equation by measuring flow times based on pipette delivery.

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The Effects of viscosity and Osmolality of Enteral Solution on Flow Rates Through Nasogastric Tubes in Vitro (경관급식 유동액의 점도와 삼투압이 체외에서 비장관 튜브를 통한 흐름속도에 미치는 영향)

  • 한경희
    • Journal of Nutrition and Health
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    • v.26 no.6
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    • pp.793-803
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    • 1993
  • This study was designed to measure viscosity, osmolality and in vitro flow rates via nasogastric tubes for 6 types of commercially available and 9 hospital-blenderized enteral solutions and to examine the effect of viscosity and osmolaility of enteral formula on the flow rates in gravity drip administration. Each solution was infused through 18, 16, 14, 12 French sizes of silicone rubber tube. Flow rates were measured six times at $25^{\circ}C$ using formula bags and drip sets hung at a uniform height on a intravenous drip stand with tube uniformly positioned in collecting container. Viscosity ranged widely from 16.0 to 195.5 cps with mean, 64.61$\pm$64.42 for hospital-blenderized formula while mean viscosity of commercial formula was 7.60$\pm$4.84 cps. Mean osmolality of commercial formula and hospital-blenderized formula were 370$\pm$100.80, 540.33$\pm$89.37 mOsm/kg respectively. There was negative relationship between viscosity of formula and flow rates through tubes but no significant relationship between flow rates and osmolalty. Some of hospital-blenderized formula was too viscous to be infused througth tube with gravity drip administration and the recipe of formula requires to be modiifed. On the other hand, commercial formula with the low viscosity flows too rapidly with large bore size tubes. Smaller size of tube must be selected for hyperosmolar solution to decrease possible side effects associated with tube feeding. Two kinds of regression equations for flow rates obtained according to viscosity and tube sizes were also presented for the purpose of practical uses. In conclusion, this study emphasizes that viscosity of fomula, osmolality, patient's tolerance and comfort, caloric density should be considered in the selection of tubes for gravify drip administration.

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