• Title/Summary/Keyword: Solution state structure

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Cyclometalated Platinum(II) Complexes Derived from a Chiral Pyridine Ligand: Synthesis, Structure, and Catalytic Activity

  • Yoon, Myeong-Sik;Ryu, Do-Wook;Kim, Jeong-Ryul;Ramesh, Rengan;Ahn, Kyo-Han
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.2045-2050
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    • 2007
  • The reactions of mercury(II) chloride with O3S2-donor macrocyclic ligands with (L1) and without (L2) dibenzosubunit afforded respective exo- (1) and endo-coordinated (2) complexes depending on the ring rigidity of the ligands. From the X-ray crystal structures and comparative NMR studies for the complexes 1 and 2, it is confirmed that the resulting species with different coordination modes exist not only in solid state but also in solution state.

Analysis of a three-dimensional FEM model of a thin piezoelectric actuator embedded in an infinite host structure

  • Zeng, Xiaohu;Yue, Zhufeng;Zhao, Bin;Wen, S.F.
    • Advances in materials Research
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    • v.3 no.1
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    • pp.237-257
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    • 2014
  • In this paper, we adopted a two-dimensional analytical electro-elastic model to predict the stress distributions of the piezoelectric actuator in 3D case. The actuator was embedded in an elastic host structure under electrical loadings. The problem is reduced to the solution of singular integral equations of the first kind. The interfacial stresses and the axial normal stress in both plane stress state and plane strain state were obtained to study the actuation effects being transferred from the actuator to the host. The stress distributions of the PZT actuator in different length and different thickness were analyzed to guarantee the generality. The validity of the present model has been demonstrated by application of specific examples and comparisons with the corresponding results obtained from the Finite Element Method.

Design of Friction Dampers installed at a Multi-Story Building under Seismic Load (지진하중을 받는 다층 건물에 설치된 마찰감쇠기 설계)

  • Seong, Ji-Young;Min, Kyung-Won
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.24 no.4
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    • pp.457-462
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    • 2011
  • In this study, a simplified design procedure for friction dampers of a multi-story structure in order to reduce seismic response is proposed. To get insight for control effect of the structure with friction dampers is difficult, because of a nonlinear characteristic by a friction damper. Since a control force of a friction damper is influenced by coupling velocity between floors, adjoining modes are coupled. Thus structural response are derived by assuming steady-state response in resonance. As it is impossible that an exact solution is obtained for seismic load, first, a closed form solution can be achieved under harmonic vibration. Second, to convert a three-story building into a single-degree-of-freedom(SDOF) structure, modal analysis is performed. Third, an equivalent damping ratio is derived with utilizing closed form solution. And response reducing factor is proposed by it. Finally, friction force of a damper is designed for using response reducing factor, and then designed dampers are verified for seven seismic data. The nonlinear analysis results confirm the validity of the proposed procedure.

NUMERICAL ANALYSIS OF THERMAL STRATIFICATION IN THE UPPER PLENUM OF THE MONJU FAST REACTOR

  • Choi, Seok-Ki;Lee, Tae-Ho;Kim, Yeong-Il;Hahn, Dohee
    • Nuclear Engineering and Technology
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    • v.45 no.2
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    • pp.191-202
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    • 2013
  • A numerical analysis of thermal stratification in the upper plenum of the MONJU fast breeder reactor was performed. Calculations were performed for a 1/6 simplified model of the MONJU reactor using the commercial code, CFX-13. To better resolve the geometrically complex upper core structure of the MONJU reactor, the porous media approach was adopted for the simulation. First, a steady state solution was obtained and the transient solutions were then obtained for the turbine trip test conducted in December 1995. The time dependent inlet conditions for the mass flow rate and temperature were provided by JAEA. Good agreement with the experimental data was observed for steady state solution. The numerical solution of the transient analysis shows the formation of thermal stratification within the upper plenum of the reactor vessel during the turbine trip test. The temporal variations of temperature were predicted accurately by the present method in the initial rapid coastdown period (~300 seconds). However, transient numerical solutions show a faster thermal mixing than that observed in the experiment after the initial coastdown period. A nearly homogenization of the temperature field in the upper plenum is predicted after about 900 seconds, which is a much shorter-term thermal stratification than the experimental data indicates. This discrepancy may be due to the shortcoming of the turbulence models available in the CFX-13 code for a natural convection flow with thermal stratification.

A unified solution for vibration analysis of plates with general structural stress distributions

  • Yang, Nian;Chen, Lu-Yun;Yi, Hong;Liu, Yong
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.8 no.6
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    • pp.615-630
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    • 2016
  • Complex stress distributions often exist in ocean engineering structures. This stress influences structural vibrations. Finite Element Methods exhibit some shortcomings for solving non-uniform stress problems, such as an unclear physical interpretation, complicated operation, and large number of computations. Analytical methods research considers mainly uniform stress problems, and often, their methods cannot be applied in practical marine structures with non-uniform stress. In this paper, an analytical method is proposed to solve the vibration of plates with general stress distributions. Non-uniform stress is expressed as a special series, and the stress influence is inserted into a vibration equation that is solved through decoupling to obtain an analytical solution. This method has been verified using numerical examples and can be used in arbitrary stress distribution cases. This method requires fewer computations and it provides a clearer physical interpretation, so it has advantages in some qualitative research.

An Improved Continuous Integral Variable Structure Systems with Prescribed Control Performance for Regulation Controls of Uncertain General Linear Systems (불확실 일반 선형 시스템의 레귤레이션 제어를 위한 사전 제어 성능을 갖는 개선된 연속 적분 가변구조 시스템)

  • Lee, Jung-Hoon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.66 no.12
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    • pp.1759-1771
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    • 2017
  • In this paper, an improved continuous integral variable structure systems(ICIVSS) with the prescribed control performance is designed for simple regulation controls of uncertain general linear systems. An integral sliding surface with an integral state having a special initial condition is adopted for removing the reaching phase and predetermining the ideal sliding trajectory from a given initial state to the origin in the state space. The ideal sliding dynamics of the integral sliding surface is analytically obtained and the solution of the ideal sliding dynamics can predetermine the ideal sliding trajectory(integral sliding surface) from the given initial state to the origin. Provided that the value of the integral sliding surface is bounded by certain value by means of the continuous input, the norm of the state error to the ideal sliding trajectory is analyzed and obtained in Theorem 1. A corresponding discontinuous control input with the exponential stability is proposed to generate the perfect sliding mode on the every point of the pre-selected sliding surface. For practical applications, the discontinuity of the VSS control input is approximated to be continuous based on the proposed modified fixed boundary layer method. The bounded stability by the continuous input is investigated in Theorem 3. With combining the results of Theorem 1 and Theorem 3, as the prescribed control performance, the pre specification on the error to the ideal sliding trajectory is possible by means of the boundary layer continuous input with the integral sliding surface. The suggested algorithm with the continuous input can provide the effective method to increase the control accuracy within the boundary layer by means of the increase of the $G_1$ gain. Through an illustrative design example and simulation study, the usefulness of the main results is verified.

A Finite Impulse Response Fixed-lag Smoother for Discrete-time Nonlinear Systems (이산 비선형 시스템에 대한 유한 임펄스 응답 고정 시간 지연 평활기)

  • Kwon, Bo-Kyu;Han, Sekyung;Han, Soohee
    • Journal of Institute of Control, Robotics and Systems
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    • v.21 no.9
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    • pp.807-810
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    • 2015
  • In this paper, a finite impulse response(FIR) fixed-lag smoother is proposed for discrete-time nonlinear systems. If the actual state trajectory is sufficiently close to the nominal state trajectory, the nonlinear system model can be divided into two parts: The error-state model and the nominal model. The error state can be estimated by adapting the optimal time-varying FIR smoother to the error-state model, and the nominal state can be obtained directly from the nominal trajectory model. Moreover, in order to obtain more robust estimates, the linearization errors are considered as a linear function of the estimation errors. Since the proposed estimator has an FIR structure, the proposed smoother can be expected to have better estimation performance than the IIR-structured estimators in terms of robustness and fast convergence. Additionally the proposed method can give a more general solution than the optimal FIR filtering approach, since the optimal FIR smoother is reduced to the optimal FIR filter by setting the fixed-lag size as zero. To illustrate the performance of the proposed method, simulation results are presented by comparing the method with an optimal FIR filtering approach and linearized Kalman filter.

New Fictitious Play Procedure For Solving Blotto Games (Blotto 게임을 풀기위한 새로운 근사해법 절차)

  • Lee, Jea-Yeong;Lee, Moon-Gul
    • Journal of the military operations research society of Korea
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    • v.31 no.1
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    • pp.107-121
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    • 2005
  • In this study, a new fictitious play (FP) procedure is presented to solve two-person zero-sum (TPZS) Blotto games. The FP solution procedure solves TPZS games by assuming that the two players take turns selecting optimal responses to the opponent's strategy observed so far. It is known that FP converges to an optimal solution, and it may be the only realistic approach to solve large games. The algorithm uses dynamic programming (DP) to solve FP subproblems. Efficiency is obtained by limiting the growth of the DP state space. Blotto games are frequently used to solve simple missile defense problems. While it may be unlikely that the models presented in this paper can be used directly to solve realistic offense and defense problems, it is hoped that they will provide insight into the basic structure of optimal and near-optimal solutions to these important, large games, and provide a foundation for solution of more realistic, and more complex, problem

Effects of Dynamic Soil Behaviour on Wave-Induced Seabed Response

  • Cha, D.H.;Jeng, D.S.;Rahman, M.S.;Sekiguchi, H.;Zen, K.;Yamazaki, H.
    • International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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    • v.5 no.1
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    • pp.1-13
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    • 2002
  • In this paper, an analytical solution for the wave-induced seabed response in a porous seabed is derived. Unlike previous investigations with quasi-static soil behaviour, dynamic soil behaviour is considered in the new solution. The basic one-dimensional framework proposed by Zienkiewicz et al (1980) is extended to two-dimensional cases. Based on the analytical solution derived, the effects of dynamic soil behaviour on the wave-induced seabed response are examined. The boundary of quasi-static soil behaviour and dynamic soil behaviour is clarified, and formulated for engineering practice.

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Zn$_2SiO_4$ : Mn Phosphor Particles Prepared by Spray Pyrolysis Process

  • Kang, Yun-Chan;Park, Hee-Dong;Lim, Mi-Ae
    • Journal of Information Display
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    • v.2 no.4
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    • pp.57-62
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    • 2001
  • Green-emitting $Zn_2SiO_4$:Mn phosphor particles having a spherical shape and high luminescence intensities under VUV were prepared by spray pyrolysis process under severe preparation conditions. The type of precursor solutions affected the morphology and luminescence characteristics of the prepared particles. The particles prepared from the clear solution by laboratory-scale process had spherical shape and dense morphology, while the particles prepared from the severe preparation conditions had rough surface and collapsed structure. However, the particles prepared from the colloidal solution utilizing fumed silica were spherical in shape and filled morphology at the severe preparation conditions of high flow rate of carrier gas, high concentration of solution, and large reactor size. The prepared $Zn_2SiO_4$:Mn phosphor particles with complete spherical shape had higher photoluminescence intensity than that of the commercial product prepared by solid state reaction.

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