• Title/Summary/Keyword: Solution state structure

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Characterization of Yttrium Doped Zinc Oxide Thin Films Fabricated by Spin-coating Method (스핀코팅법에 의해 제조되어진 Yttrium이 도핑된 ZnO 막의 특성)

  • Kim Hyun-Ju;Lee Dong-Yun;Song Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.457-460
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    • 2006
  • Y doped zinc oxide (YZO) thin films were deposited on F doped $SnO_2$ (FTO) glass substrate by sol-gel method using the spin-coating system. A homogeneous and stable solution was prepared by dissolving acetate in the solution added diethanolamine as sol-gel stabilizer. YZO films were obtained after preheated on the hot-plate for 5minute before each coating; the number of coating was 3 times. After the coating of last step, annealing of YZO films performed at $450^{\circ}C$ for 30 minute. In order to confirming of a ultraviolet ray interruption and down-conversion effects, optical properties of YZO films, transmission spectrum and fluorescent spectrum were used. Also, for understanding the obtained results by experiment, the elestronic state of YZO was calculated using the density functional theory The results obtained by experiment were compared with calculated structure. The detail of electronic structure was obtained by the discrete variational Xa (DV-Xa) method, which is a sort of molecular orbital full potential method. The density of state and energy levels of dopant element were shown and discussed in association with optical properties.

Fast analytical estimation of the influence zone depth, its numerical verification and FEM accuracy testing

  • Kuklik, Pavel;Broucek, Miroslav;Kopackova, Marie
    • Structural Engineering and Mechanics
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    • v.33 no.5
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    • pp.635-647
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    • 2009
  • For the calculation of foundation settlement it is recommended to take into account so called influence zone inside the subsoil bellow the foundation structure. Influence zone inside the subsoil is the region where the load has a substantial influence on the deformation of the soil skeleton. The soil skeleton is pre-consolidated or over consolidated due to the original geostatic stress state. An excavation changes the original geostatic stress state and it creates the space for the load transferred from upper structure. The theory of elastic layer in Westergard manner is selected for the vertical stress calculation. The depth of influence zone is calculated from the equality of the original geostatic stress and the new geostatic stress due to excavation combined with the vertical stress from the upper structure. Two close formulas are presented for the influence zone calculation. Using ADINA code we carried out several numerical examples to verify the proposed analytical formulas and to enhance their use in civil engineering practice. Otherwise, the FEM code accuracy can be control.

SOC Sustaining Strategy for HEV through State-machine Control (하이브리드 차량의 SOC 유지전략 방법)

  • Byun, Sang-Min;Kim, Beom-Soo;Cha, Suk-Won
    • New & Renewable Energy
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    • v.4 no.4
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    • pp.65-71
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    • 2008
  • Considering the world's environmental problem, HEVs are projected as one of the solution. The keys of the HEV cruise control are expanding the use of electric motor and operating the internal combustion engine in the efficient region. This paper presents a new structure of SOC sustaining model where state-machine control is used. The proposed model defines battery charging and discharging as states and SOC of the battery as control variables. In this paper, we introduce various methods in deterministic rule-based control for HEV and describe a new SOC sustaining controller used by state-machine.

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A study on the Manufacture of the CuO Powder from Copper Chloride Solution by Spray Pyrolysis Process (분무열분해법에 의한 구리염화물 용액으로부터 CuO 분말 제조에 관한 연구)

  • Yu, Jae-Geun;Park, Hui-Beom
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.58-67
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    • 2002
  • In this study copper chloride(CuCl$_2$) solution was used as raw material to produce the fine copper oxide powder which has less than 1 $\mu\textrm{m}$ average particle size and has uniform particle size distribution by spray pyrolysis process. In the present study, the effects of reaction temperature, the injection speed of solution and air, the nozzle tip size and the concentration of raw material solution on the properties of produced powder were studied. The structure of the powder became much more compact with increasing the reaction temperature regardless of copper concentration of the raw material solution. The particle size of the powder increased accordingly with increasing the reaction temperature in case of 30 g/$\ell$ copper concentration of the solution. The particle size of the powder increased accordingly, and the surface structure of the powder became more porous with increasing the copper concentration of the raw material solution. When copper concentration in raw material solution was more than 100 g/$\ell$, all produced powder was CuCl regardless of reaction temperatures. When copper concentration in solution was below 30 g/$\ell$ and reaction temperature was higher than 90$0^{\circ}C$, CuO was the main phase. The surface of the powder tended to become porous with increasing the injection speed of solution. Particle size was increased and the surface of the powder showed severely disrupted state with increasing the nozzle tip size. The particle size was decreased and the particle size distribution was more uniform with increasing the air pressure through the nozzle.

On covariance control theory for linear discrete systems via inverse solution of the Lyapunov matrix equation (Lyapunov 행렬방정식의 역해를 이용한 선형 이산시스템의 공분산제어)

  • Kim, Ho-Chan;Choi, Chong-Ho;Kim, Sang-Hyun
    • Proceedings of the KIEE Conference
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    • 1998.07b
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    • pp.443-445
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    • 1998
  • In this paper, an alternate method for state-covariance assignment for SISO(single input single output) linear systems is proposed. This method is based on the inverse solution of the Lyapunov matrix equation and the resulting formulas are similar in structure to the formulas for pole placement. Further, the set of all assignable covariance matrices to a SISO linear system is also characterized.

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Shear-induced structure and dynamics of hydrophobically modified hydroxy ethyl cellulose (hmHEC) in the presence of SDS

  • Tirtaatmadija, Viyada;Cooper-white, Justin J.;Gason, Samuel J.
    • Korea-Australia Rheology Journal
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    • v.14 no.4
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    • pp.189-201
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    • 2002
  • The interaction between hydrophobically modified hydroxyethyl cellulose (hmHEC), containing approximately 1 wt% side-alkyl chains of $C_{16}$, and an anionic sodium dodecyl sulphate (SDS) surfactant was investigated. For a semi-dilute solution of 0.5 wt% hmHEC, the previously observed behaviour of a maximum in solution viscosity at intermediate SDS concentrations, followed by a drop at higher SDS concentrations, until above the cmc of surfactant when the solution resembles that of the unsubstituted polymer, was confirmed. Additionally, a two-phase region containing a hydrogel phase and a water-like supernatant was found at low SDS concentrations up to 0.2 wt%, a concentration which is akin to the critical association concentration, cac, of SDS in the presence of hmHEC. Above this concentration, SDS molecules bind strongly to form mixed micellar aggregates with the polymer alkyl side-chains, thus strengthening the network junctions, resulting in the observed increase in viscosity and elastic modulus of the solution. The shear behaviour of this polymer-surfactant complex during steady and step stress experiments was examined In great detail. Between SDS concentrations of 0.2 and 0.25 wt%, the shear viscosity of the hmHEC-polymer complex network undergoes shear-induced thickening, followed by a two-stage shear-induced fracture or break-up of the network. The thickening is thought to be due to structural rearrangement, causing the network of flexible polymers to expand, enabling some polymer hydrophobic groups to be converted from intra- to inter-chain associations. At higher applied stress, a partial local break-up of the network occurs, while at even higher stress, above the critical or network yield stress, a complete fracture of the network into small microgel-like units, Is believed to occur. This second network rupture is progressive with time of shear and no steady state in viscosity was observed even after 300 s. The structure which was reformed after the cessation of shear is found to be significantly different from the original state.

Effect of addition of methanol on rheological properties of silk formic acid solution

  • Bae, Yu Jeong;Um, In Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.40 no.1
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    • pp.28-32
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    • 2020
  • Recently, many studies have been undertaken on the wet spinning and electrospinning of silk because wet-spun fibers and electrospun webs of silk can be applied in the biomedical and cosmetic fields owing to the good biocompatibility of silk. The rheological properties of silk solution are important because they strongly affect the spinning performance of the silk solution and the structures of resultant fibrous materials. Therefore, as a preliminary study on the effect of solvent composition on the rheological properties of silk fibroin (SF) solution and structure of the resultant film, in the reported work, methanol was added to the SF formic acid solution. A small amount of methanol (i.e. 2%) added to the SF formic acid solution significantly altered the rheological properties of the solution: its shear viscosity increased by 10 folds at low shear and decreased on increasing the shear rate, demonstrating shear thinning behavior of the SF solution. Dynamic tests for the SF solution indicated that the addition of 2% methanol altered the viscous state of the SF formic acid solution to elastic. However, the molecular conformation (i.e. β-sheet conformation) of the regenerated SF film cast from formic acid remained unchanged on the addition of 2% methanol.

Biochemical and Structural Analysis of Hormone-sensitive Lipase Homolog EstE7: Insight into the Stabilized Dimerization of HSL-Homolog Proteins

  • Nam, Ki-Hyun;Park, Sung-Ha;Lee, Won-Ho;Hwang, Kwang-Yeon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.9
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    • pp.2627-2632
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    • 2010
  • Hormone sensitive lipase (HSL) plays a major role in energy homeostasis and lipid metabolism. Several crystal structures of HSL-homolog proteins have been identified, which has led to a better understanding of its molecular function. HSL-homolog proteins exit as both monomer and dimer, but the biochemical and structural basis for such oligomeric states has not been successfully elucidated. Therefore, we determined the crystal structure of HSL-homolog protein EstE7 from a metagenome library at $2.2\;{\AA}$ resolution and characterized the oligomeric states of EstE7 both structurally and biochemically. EstE7 protein prefers the dimeric state in solution, which is supported by its higher enzymatic activity in the dimeric state. In the crystal form, EstE7 protein shows two-types of dimeric interface. Specifically, dimerization via the external ${beta}8$-strand occurred through tight association between two pseudosymmetric folds via salt bridges, hydrogen bonds and van der Waals interactions. This dimer formation was similar to that of other HSL-homolog protein structures such as AFEST, BEFA, and EstE1. We anticipate that our results will provide insight into the oligomeric state of HSL-homolog proteins.

Multi-stage approach for structural damage identification using particle swarm optimization

  • Tang, H.;Zhang, W.;Xie, L.;Xue, S.
    • Smart Structures and Systems
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    • v.11 no.1
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    • pp.69-86
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    • 2013
  • An efficient methodology using static test data and changes in natural frequencies is proposed to identify the damages in structural systems. The methodology consists of two main stages. In the first stage, the Damage Signal Match (DSM) technique is employed to quickly identify the most potentially damaged elements so as to reduce the number of the solution space (solution parameters). In the second stage, a particle swarm optimization (PSO) approach is presented to accurately determine the actual damage extents using the first stage results. One numerical case study by using a planar truss and one experimental case study by using a full-scale steel truss structure are used to verify the proposed hybrid method. The identification results show that the proposed methodology can identify the location and severity of damage with a reasonable level of accuracy, even when practical considerations limit the number of measurements to only a few for a complex structure.

In-cell nuclear magnetic resonance spectroscopy for studying intermolecular interactions

  • Sugiki, Toshihiko;Lin, Yuxi;Lee, Young-Ho
    • Journal of the Korean Magnetic Resonance Society
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    • v.23 no.1
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    • pp.33-39
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    • 2019
  • Studies on the interactions of proteins with partner molecules at the atomic resolution are essential for understanding the biological function of proteins in cells and for developing drug molecules. Solution NMR spectroscopy has shown remarkably useful capability for investigating properties on the weak to strong intermolecular interactions in both diluted and crowded solution such as cell lysates. Of note, the state-of-the-art in-cell NMR method has made it possible to obtain atomistic information on natures of intermolecular interactions between target proteins with partner molecules in living cells. In this mini-review, we comprehensively describe the several technological advances and developments in the in-cell NMR spectroscopy.