• Title/Summary/Keyword: Solution processed

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Photo-Electrochemical Properties of $TiO_2$ Electrodes Prepared by Anodic Oxidation (양극산화에 의해 제조된 $TiO_2$ 전극의 광전기화학적 성질)

  • Yong Kook Choi;Soon Ki Lee;Q Won Choi;Jeong Sub Seong;Ki Hyung Chjo
    • Journal of the Korean Chemical Society
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    • v.37 no.12
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    • pp.1010-1018
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    • 1993
  • The titanium oxide thin films were prepared by anodic oxidation. The Photo-electrochemical properties of the electrodes were studied in 1 M NaOH solution. The flat band potentials of $TiO_2$ electrodes prepared by anodic oxidation showed around -0.8V and the values were shifted 0.2V to the positive potential direction that of single crystal $TiO_2$. Reduction potential of oxygen by cyclic voltammetry showed around -0.95V vs. SCE and these reactions were processed totally irreversible. The photocurrent of electrodes were showed shorter wavelength than that of single crystal $TiO_2$ and its current density decreased.

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Influence of Citric Acid on the Pink Color and Characteristics of Sous Vide Processed Chicken Breasts During Chill Storage

  • Kim, Ji-Han;Hong, Go-Eun;Lim, Ki-Won;Park, Woojoon;Lee, Chi-Ho
    • Food Science of Animal Resources
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    • v.35 no.5
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    • pp.585-596
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    • 2015
  • Chicken breast dipped with citric acid (CA) was treated by sous vide processing and stored in a refrigerated state for 0, 3, 6, 9, and 14 d. A non-dipped control group (CON) and three groups dipped in different concentrations of citric acid concentration were analyzed (0.5%, 0.5CIT; 2.0%, 2CIT and 5.0%, 5CIT; w/v). Cooking yield and moisture content increased due to the citric acid. While the redness of the juice and meat in all groups showed significant increase during storage, the redness of the citric acid groups was reduced compared to the control group (p<0.05). The percentage of myoglobin denaturation (PMD) of the CA groups was also increased according to the level of CA during storage. Total aerobic counts, Enterobacteriaceae counts, volatile basic nitrogen and thiobarbituric acid reactive substances (TBARS) were generally lower in the citric acid-treated samples than in untreated ones, indicating extended shelf life of the cooked chicken breast dipped in citric acid solution. The shear force of the 2CIT and 5CIT groups was significantly lower (p<0.05). The findings indicated positive effects in the physicochemical properties and storage ability of sous vide chicken breast at 2% and 5% citric acid concentrations.

Synthesis of Cu-coated Ni-based Bulk Metallic Glass Powders by Gas Atomization and Spray Drying Process

  • Kim, Byoung-Kee;Kim, Yong-Jin;Kim, Jin-Chun
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.936-936
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    • 2006
  • Bulk amorphous materials have been intensively studied to apply for various advanced industry fields due to their high mechanical, chemical and electrical properties. These materials have been produced by several techniques such as mechanical alloying, melt spinning and gas atomization, etc. Among them, the atomization is the most potential technique for commercialization due to high cooling rate during solidification of the melt and mass productivity. However, the amorphous powders still have some limitations because of their low ductility and toughness. Therefore, intensive efforts have to be carried out to increase the ductility and toughness. In this study, the Ni-based amorphous powder was produced by the gas atomization process. And in order to increase the ductile toughness, ductile Cu phase was coated on the Ni amorphous powder by spray drying process. The characteristics of the as-synthesis powders have been examined and briefly mentioned. The master alloy with $Ni_{57}Zr_{20}Ti_{16}Si_2Sn_3$ was prepared by vacuum induction melting furnace with graphite crucible and mold. The atomization was conducted at $1450^{\circ}C$ under the vacuum of $10^{-2}$ torr. The gas pressure during atomization was varied from 35 to 50 bars. After making the Ni amorphous powders, the spray drying was processed to produce the Cu -coated Ni amorphous composite powder. The amorphous powder and Cu nitrate solution were mixed together with a small amount of binder and then it was sprayed at temperature of $130^{\circ}C$ and rotating speed of 15,000 R.P.M.

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Recovery and Utilization of Proteins and Lipids from the Washing Wastewater in Marine Manufacture by Isoelectric Point Shifting Precipition Method -2. Utilization of the Recovered Proteins as the Material of a Processed Food- (수산가공공장폐액의 등전점이동 응집처리에 의한 유용성분재회수이용 -2. 회수단백질의 가공식품소재로서의 이용-)

  • SUH Jae-Soo;CHO Soon-Yeong;SON Kwang-Tae;KIM Jin-Soo;LEE Eung-HO
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.27 no.5
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    • pp.495-500
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    • 1994
  • Mackerel water-soluble protein solution Mackerel meat washing water were concentrated by isoelectric point shifting precipitation process, and the concentrates were utilized as a material for processing of an elastic gel food such as kamaboko. The water-soluble proteins were partly polymerized during the isoelectric point shifting precipitation process. Then, the water soluble protein concentrates were partly substituted for frozen minced Alaska pollack meat in processing of a good quality kamaboko. The maximum substitution percentage for good quality kamaboko manufacturing was concluded to be below $30\%$, according to the criteria of color difference, jelly strength and folding tests using the substituted recovered protein concentrates.

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Volatile Constituents of Processed Squid Product (오징어 가공품의 냄새성분에 관한 연구)

  • Chiaki Koiiumi;Toshiaki Ohshima;Lee, Eung-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.19 no.6
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    • pp.547-554
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    • 1990
  • The precursor substance and volatile components of cooked flavor of squid meat were studied. Volatile components were trapped by simultaneous distillation-extraction method, and these were fractionated into the neutral, basic, phenolic and acidic fraction. Volatile flavor components in these frations were analyzed by GC and GC-MS. 80% methanol solution was the most effective solvent for extraction of the precursor substance for cooked flavor. The neutral and basic fraction, by organoleptic test, seem to have a major effect on squid-like flavor. Forty-four compounds, including 2 hydorcarbons, 10 alcohols, 5 aldehydes, 1 ketone, 1 furan, 3 sulfide compounds, 7 pyrazines, 2 pyridines, 1 amino, 2 phenols and 10 acids, identified as cooked flavor compounds of squid meat.

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A First Synthesis and Physical Properties of Asymmetric Anthracenes-Thiophenes Bridged with Ethylene

  • Hwang, Min Ji;Park, Ji Hee;Jeong, Eun Bin;Kang, Il;Lee, Dong Hoon;Park, Chan Eon;Singh, O.M.;Choi, HoJune;Kim, Yoon-Hi;Yoon, Yong Jin;Kwon, Soon-Ki;Lee, Sang-Gyeong
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3810-3816
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    • 2012
  • Here we report our recent result of a new semiconductor material, which has an asymmetric structure. The synthesized molecules consist of anthracene and thiophene connected by bridged ethylene and substituted with hexyl or dodecyl groups as pendants. The semiconductors were synthesized using a McMurry coupling reaction between anthracene-2-carbaldehyde and corresponding 5-hexyl(or dodecyl)thiophene-2-carbaldehyde. A first investigation of synthesized asymmetry AVHT (9a) and AVDT (9b) for the physical properties showed that they have high oxidation potential and thermal stability. The devices prepared by using AVHT (9a) and AVDT (9b) showed the mobility of $2.6{\times}10^{-2}cm^2/Vs$ and $4.4{\times}10^{-3}cm^2/Vs$, respectively, in solution processed OTFTs.

Micromorphometric change of implant surface conditioned with tetracycline-HCI;HA and oxidized surface (표면처리 시간에 따른 임플란트 미세구조의 변화;HA와 양극산화 표면 임플란트)

  • An, Sang-Ho;Park, Joon-Bong;Kwon, Young-Hyuk;Herr, Yeek;Chung, Jong-Hyuk
    • Journal of Periodontal and Implant Science
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    • v.35 no.4
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    • pp.891-905
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    • 2005
  • The present study was performed to evaluate the effect of tetracycline-HCL on the change of implant surface microstructure according to application time. Implant with pure titanium machined surface. HA-coated surface and TiUniteTM surface were utilized. Implant surface was rubbed with 50mg/ml tetracycline-HCL solution for $\frac{1}{2}min.$, 1min., $1\frac{1}{2}min.$, 2min., and $2\frac{1}{2}min.$ respectively in the test group. Then, specimens were processed for scanning electron microscopic observation. The results of this study were as follows. 1. Both test and control group showed a few shallow grooves and ridges in pure titanium machined surface implants. There were not significant differences between two groups. 2. In HA-coated surfaces, round particles were deposited irregularly. The roughness of surfaces conditioned with tetracycline-HCL was lessened and the cracks were increased relative to the application time. 3. The anodic oxidized surfaces showed the craterous structures. The surface conditioning with tetracycline-HCl didn't influence on its micro-morphology. In conclusion, the detoxification with 50mg/ml tetracycline-HCL must be applied respectively with different time according to various implant surfaces.

Polymeric hole-injection layer for high-efficiency and long-lifetime in organic light-emitting diodes

  • Choi, Mi-Ri;Han, Tae-Hee;Woo, Seong-Hoon;Lim, Kyung-Geun;Yun, Won-Min;Kwon, Oh-Kwan;Park, Chan-Eon;Shin, Hoon-Kyu;Hur, Dal-Ho;Shin, Kyoung-Hwan;Jang, Jyong-Sik;Lee, Tae-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.781-783
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    • 2009
  • We achieved high efficiency and long lifetime in small-molecule organic light-emitting diodes using a blend of polyaniline-based conducting polymer and a perfluorinated ionomer as a hole injection layer (HIL). The HIL formed by single spin coating greatly enhanced the surface work function and thus the hole injection from the anode, which resulted in great improvement in device luminous efficiency. We find that the solution processed HIL outperforms the conventional vacuum-deposited small molecule HIL in terms of the device performance.

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Conductive Carbon Block Filled Composites( II ) - Concentrated on Processabilily - (전도성 카본블랙이 충진된 도전성 고분자 복합재료(II) -가공성을 중심으로 -)

  • Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.34 no.2
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    • pp.113-120
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    • 1999
  • Nobody doubts to say that one of the most important performance polymers is a conductive polymer. The manufacturing process of the commercial conductive polymers has been known by mixing with the conductive materials, but it doesn't noticeably appear of a conductive function. One of the reasons is the lack of comprehension In compounding a carbon black with polymer rosins. This paper involves the understanding of compounding technology of the conductive carbon black filled composite. Our experimental results indicate that the fibrous shaped carbon black was hard to process but appeared of a superior conductivity compared to a stick or a sphelulite shaped carbon black. Therefore, it was processed with a processing oil in compounding, which led to a better processability and a better conductivity. This study was accomplished that the solution process compared to the melting process.

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A Study on CNN based Production Yield Prediction Algorithm for Increasing Process Efficiency of Biogas Plant

  • Shin, Jaekwon;Kim, Jintae;Lee, Beomhee;Lee, Junghoon;Lee, Jisung;Jeong, Seongyeob;Chang, Soonwoong
    • International journal of advanced smart convergence
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    • v.7 no.1
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    • pp.42-47
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    • 2018
  • Recently, as the demand for limited resources continues to rise and problems of resource depletion rise worldwide, the importance of renewable energy is gradually increasing. In order to solve these problems, various methods such as energy conservation and alternative energy development have been suggested, and biogas, which can utilize the gas produced from biomass as fuel, is also receiving attention as the next generation of innovative renewable energy. New and renewable energy using biogas is an energy production method that is expected to be possible in large scale because it can supply energy with high efficiency in compliance with energy supply method of recycling conventional resources. In order to more efficiently produce and manage these biogas, a biogas plant has emerged. In recent years, a large number of biogas plants have been installed and operated in various locations. Organic wastes corresponding to biogas production resources in a biogas plant exist in a wide variety of types, and each of the incoming raw materials is processed in different processes. Because such a process is required, the case where the biogas plant process is inefficiently operated is continuously occurring, and the economic cost consumed for the operation of the biogas production relative to the generated biogas production is further increased. In order to solve such problems, various attempts such as process analysis and feedback based on the feedstock have been continued but it is a passive method and very limited to operate a medium/large scale biogas plant. In this paper, we propose "CNN-based production yield prediction algorithm for increasing process efficiency of biogas plant" for efficient operation of biogas plant process. Based on CNN-based production yield forecasting, which is one of the deep-leaning technologies, it enables mechanical analysis of the process operation process and provides a solution for optimal process operation due to process-related accumulated data analyzed by the automated process.