• Title/Summary/Keyword: Solute Diffusion

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The Analytical Derivation of the Fractal Advection-Diffusion Equation for Modeling Solute Transport in Rivers (하천 오염물질의 모의를 위한 프랙탈 이송확산방정식의 해석적 유도)

  • Kim, Sang-Dan;Song, Mee-Young
    • Journal of Korea Water Resources Association
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    • v.37 no.11
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    • pp.889-896
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    • 2004
  • The fractal advection-diffusion equation (ADE) is a generalization of the classical AdE in which the second-order derivative is replaced with a fractal order derivative. While the fractal ADE have been analyzed with a stochastic process In the Fourier and Laplace space so far, in this study a fractal ADE for describing solute transport in rivers is derived with a finite difference scheme in the real space. This derivation with a finite difference scheme gives the hint how the fractal derivative order and fractal diffusion coefficient can be estimated physically In contrast to the classical ADE, the fractal ADE is expected to be able to provide solutions that resemble the highly skewed and heavy-tailed time-concentration distribution curves of contaminant plumes observed in rivers.

Structure Parameter Change Estimation of a Forward Osmosis Membrane Under Pressurized Conditions in Pressure-assisted Forward Osmosis (PAFO) (가압형 정삼투 시 압력에 따른 정삼투막의 Structure Parameter 변화양상 예측)

  • Kook, Seungho;Kim, Sung-Jo;Lee, Jinwoo;Hwang, Moonhyun;Kim, In S.
    • Membrane Journal
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    • v.26 no.3
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    • pp.187-196
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    • 2016
  • Pressure-assisted forward osmosis (PAFO) process has recently been under spotlight for its potential to improve forward osmosis (FO) process performance by applying low hydraulic pressure on the feed side. Structure parameter, one of the governing factors in estimating water flux and solute flux across FO membranes in the solution-diffusion model (S-D model), determines solute resistivity in FO and PAFO processes. This study aims to estimate the trend of structure parameter change with respect to varying additional hydraulic pressure condition in PAFO.

Effects of Polymer Material and Solvent Properties on the Performance of Organic Solvent Nanofiltration Membranes (고분자 소재와 용매특성에 따른 유기용매 나노여과막 성능 분석)

  • Choi, JiHyun;Kim, Jeong F.
    • Membrane Journal
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    • v.32 no.1
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    • pp.50-56
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    • 2022
  • In this work, the solvent permeation and separation performance of organic solvent nanofiltration (OSN) membranes were evaluated. Particularly, the PuraMem (PM) series developed for nonpolar solvents were analyzed and tested in dead-end filtration system. PM membranes exhibited higher permeance for nonpolar solvents compared to polar solvents, and their rejection data did not follow conventional trends with respect to solute size. The data showed that simple solution-diffusion model is not suitable to describe the OSN membrane behavior, and a better solvent-solute-membrane interaction parameter must be developed.

A COMPUTATIONAL MODEL FOR OSMOSIS PHENOMENA OF CELLS THROUGH SEMI-PERMEABLE MEMBRANES

  • Kim, Im-Bunm;Ha, Tae-Young;Sheen, Dong-Woo
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.13 no.2
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    • pp.123-140
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    • 2009
  • The effect of a solute concentration difference on the osmotic transport of water through the semi-permeable membrane of a simple cell model is investigated. So far, most studies on osmotic phenomena are described by simple diffusion-type equations ignoring all fluid motion or described by Stokes flow. In our work, as the governing equations, we consider the coupled full Navier-Stokes equations which describe the fluid motion and the full transport equation that takes into account of convection and diffusion effects. A two dimensional finite difference model has been developed to simulate the velocity field, concentration field, and semi-permeable membrane movement. It is shown that the cell swells to regions of lower solute concentration due to the uneven water flux through the semi-permeable membrane. The simulation is applied on a red blood cell geometry and the relevant results are presented.

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Growth of GaAs Crystals by synthesis Solute Diffusion Method (합성 용질 확산법에 의한 GaAs결정 성장에 관하여)

  • 문동찬;정홍배;이영희;김선태;최영복
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.1
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    • pp.56-62
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    • 1992
  • The GaAs bulk crystals are grown by the Synthesis Solute Diffusion(SSD) method and its properties are investigated. The crystal growth rate at optimum condition is 0.28 cm/day and their temperature dependence is R(T) = 2.92 x 10S04T exp(-1.548eV/kS1BTT) [cmS02T/day.K]. Etch pits density distribution along radial direction is order of 10S04TcmS0-2T and 10S03TcmS0-2T at the edge and middle of the wafers, respectively, and it increased exponentially along vertical direction of ingot. Moreover,it is uniformly distributed as order of 10S03TcmS0-2T in radial direction of In doped GaAs. The carrier concentration and mobilities are measured to 0.34-2.1 x 10S016T cmS0-3T and 2.3-3.3x10S03T cmS02T/V.sec, respectively.

Impact of Secondary Currents on Solute Transport in Open-Channel Flows over Smooth-Rough Bed Strips (조(粗)·세립상(細粒床)의 연속구조를 갖는 개수로 흐름에서 오염물질 수송에 대한 이차흐름 영향 분석)

  • Kang, Hyeongsik;Choi, Sung-Uk;Kim, Kyu-Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1B
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    • pp.73-81
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    • 2009
  • This paper presents a numerical investigation of the impact of the secondary currents on solute transport in open-channel flows. The RANS model with Reynolds stress model is used for flow modeling, and the GGDH(generalized gradient diffusion hypothesis) model is used to close the scalar transport equation. Using the developed model, the impact of secondary currents on solute transport in open channel flows over smooth-rough strip is investigated. Through numerical experiments, the secondary currents are found to affect the solute spreading, leading a movement of the position of the peak concentration and a skewed distribution of solute concentration. Due to the lateral flow of secondary currents near the free surface, the concentration at the rough strip is found to be larger than that at the smooth strip bed. The solute at the rough strip is more rapidly transported than smooth bed. A magnitude analysis of the solute transport rate in scalar transport equation is also carried out to investigate the effect of secondary currents and scalar flux on the concentration distribution.

Dynamics and Transport of Molecules Studied by Transient Grating Method : Methyl Red in Solution

  • 김선희;김성규
    • Bulletin of the Korean Chemical Society
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    • v.17 no.4
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    • pp.365-373
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    • 1996
  • Time profile of the transient grating signal induced by a nanosecond pulsed laser excitation of methyl red is investigated in alcohols and toluene at several solvent temperatures. The signal decays biexponentially with well-separated time constants; the faster decay is identified as due to thermal diffusion of the solvents and the slower one as mainly due to translational diffusion of the solute. The measured translational diffusion constants of methyl red in toluene are close to a hydrodynamic prediction with a slip boundary condition while those in alcohols are larger by 30% and increase slightly with the size of alcohols. We compare the results with modified hydrodynamic models.

Diffusion Behavior Characteristics of Some Solutes in Surfactant Aqueous Solutions (계면활성제 수용액에서 몇가지 용질의 확산거동 특성)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.1
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    • pp.79-85
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    • 2007
  • The diffusion behavior of phenol, toluene and benzoic acid in aqueous SDS solution was examined. It showed a similar experimental results for phenol and toluene. The diffusion coefficients of the solutes were characterized by the presence of two distinct regions: below the cmc and above the cmc. For phenol and toluene, it remained approximately unchanged when the SDS concentration was below the cmc. Above the cmc there was an apparent decrease in the diffusion coefficients of the two solutes with increasing SDS concentration. However, for benzoic acid the diffusion behavior was different from that of phenol and toluene. The diffusion coefficient of benzoic acid decreased slightly with increasing SDS concentration, however the diffusion coefficient was almost constant above the cmc. For benzoic acid the diffusion behavior was dependent on the joint contribution of benzoic acid molecules as well as the benzoate ions.

Mobility of Water and Solute Intluenced by PHYSICAL PROCESSES in field Soils (포장에서 물리적 진행과정에 의해 영향을 받은 물질과 수분의 이동성)

  • Doug Young Chung
    • Journal of Korea Soil Environment Society
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    • v.1 no.2
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    • pp.73-81
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    • 1996
  • The self-diffusion coefficients of chloride and tritiated water ranged from 4.8 $\times$ 10-7 to 7.2 $\times$ 10-7 cm2/sec and 5.5 $\times$ 10-5 to 1.6 $\times$ 10-4 cm2/sec for three different depths of soil constituents at about 50% water content by volume, respectively Mobility of solute and water was conducted under steady-state flow conditions in a field soil consisting of 70 cm of clay to silty clay over a medium sand. A steady-state water flow conditions was maintained by applying irrigation water at a constant flux of 2cm per day. The water labeled with chloride and tritium was leached into the plot during the steady-state condition for 87 days. The positions of tritium and chloride as a function of soil depth and the time was measured by extracting samples of the soil solution with suction probes. Extremes in solute displacement occurred at equal and different depths within the plot. An analysis of these measurements indicated the observations of the pore-water velocity and the apparent diffusion coefficient were log normally disturbed. Twenty-four soil suction probes, used to identify the rate at which a solute was displaced in the soil, will yield an estimate of the mean pore-water velocity of this soils within a range of approximately 5% of its true value providing the effects of potential solute-soil interaction are taken into account.

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Analysis of Creep Effective Stress in Austenitic Heat Resistant Steel (오스테나이트계 내열강의 크리프 유효응력 해석)

  • Nam, Ki-Woo;Park, In-Duck
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1317-1323
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    • 2002
  • This paper describes the comparison of calculated effective stress with experimental one in austenitic heat resistant steels, STS310J1TB and STS310S with and without a small amount of Nb and N. Based on a solute atoms diffusion model, contribution from soluble nitrogen to the high-temperature strength was numerically examined for austenitic heat-resisting Fe-Cr-Ni-N(STS310J1TB) and Fe-Cr-Ni (STS310S) alloys. The solute atmosphere dragging stress of dislocation was calculated in optional dislocation velocity of STS310J1TB and STS310S at $650^{\circ}C$, $675^{\circ}C$ and $700^{\circ}C$. As a result of the numerical calculation, the solute atmosphere dragging stress of STS310J1TB was about 50 times larger than that of STS310S. When the temperature became high, the maximum value of solute atmosphere dragging stress was small and the velocity of moving dislocation was fast. From the relationship between the dislocation rate and the solute atmosphere dragging stress, the relation of both was proportional and the inclination is about 1 in the level with low velocity of moving dislocation. From above results, the mechanism of dislocation movement in STS310J1TB was the solute atmosphere dragging stress. The solute atmosphere dragging stress, which was calculated from the numerical calculation was close to the effect stress in stress relaxation tests.