• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.610-616
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• 2014

The influence of solvent polarity on the absorption spectra of some synthesized azo dye with heterocyclic moieties and ${\beta}$-naphthol (1-3) have been investigated using a UV-Visible spectrophotometer. The spectral characteristics of the azo dyes (1-3) in different solvents at room temperature were analyzed. The solvatochromic empirical variables like ${\pi}^*$, ${\alpha}$, and ${\beta}$ have been used to discuss the solvatochromic behaviour of the dyes and to evaluate their contributions to the solute-solvent interactions. A multi-parameter regression model for quantitative assessment of the solute/solvent interaction and the absorption has been used to explain the solvent effect on azo dyes (1-3).

• Macromolecular Research
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• v.10 no.4
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• pp.209-214
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• 2002

Miscibility of polysulfone (PSf) with various hydrophilic copolymers was explored. Among these blends, PSf gives homogeneous mixtures with poly(1-vinylpyrrolidone-co-styrene) copolymers [P(VP-S)] when these copolymers contained VP from 68 to 88 wt%. Microporous membranes for the ultrafiltration process were prepared from PSf blends with P(VP-S) copolymers. The membranes prepared from the PSf/(VP-S) blends exhibited higher water flux than the membranes prepared from PSf irrespective of the VP content. The solute rejection examined with the membranes fabricated from the miscible blends was similar to that of PSf membrane. However, the solute rejection examined with the membranes fabricated from the immiscible blends was lower than that of PSf membranes.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.10a
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• pp.1512-1517
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• 2008

Laboratory column tests were conducted in this study using $Cl^-$ tracers on Jumunjin sand to analyze contaminant transport in mixed contaminated soils. Results obtained from clean soils and soils containing residual diesel verified heterogeneous distribution of residual diesel, and clear acceleration of solute movement. In addition, asymmetric breakthrough curves indicated development of immobile region where solute movement becomes stagnant and creates tailing phenomenon.

• Journal of the Korean Society of Safety
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• v.24 no.6
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• pp.20-26
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• 2009

The creep deformation behavior of AZ31 magnesium alloy was examined in the temperature range from 573 to 673K (0.62 to 0.73 Tm) under various constant stresses covering low strain rate range from $4{\times}10^{-9}\;s^{-1}$ to $2{\times}10^{-2}\;s^{-1}$. At low stress level, the stress exponent for the steady-state creep rate was ~3 and the present results were in good agreement with the prediction of Takeuchi and Argon model. At high stress level, the stress exponent was ~5 and the present results were in good agreement with the prediction of Weertman model. The transition of deformation mechanism from solute drag creep to dislocation climb creep could be explained in terms of solute-atmospherebreakaway concept.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.41 no.1
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• pp.56-62
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• 1992

The GaAs bulk crystals are grown by the Synthesis Solute Diffusion(SSD) method and its properties are investigated. The crystal growth rate at optimum condition is 0.28 cm/day and their temperature dependence is R(T) = 2.92 x 10S04T exp(-1.548eV/kS1BTT) [cmS02T/day.K]. Etch pits density distribution along radial direction is order of 10S04TcmS0-2T and 10S03TcmS0-2T at the edge and middle of the wafers, respectively, and it increased exponentially along vertical direction of ingot. Moreover,it is uniformly distributed as order of 10S03TcmS0-2T in radial direction of In doped GaAs. The carrier concentration and mobilities are measured to 0.34-2.1 x 10S016T cmS0-3T and 2.3-3.3x10S03T cmS02T/V.sec, respectively.

• Journal of computational fluids engineering
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• v.7 no.1
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• pp.36-43
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• 2002

A numerical investigation is made of unsteady double-diffusive convection of a Boussinesq fluid in a rectangular cavity subject to time-periodic thermal excitations. The fluid is initially stratified between the top endwall of low solute concentration and the bottom endwall of high solute concentration. A time-dependent heat flux varying in a square wave fashion, is applied on one sidewall to induce buoyant convection. The influences of the imposed periodicity on double-diffusive convection are examined. A special concern is on the occurrence of resonance that the fluctuations of flow and attendant heat and mass transfers are mostly amplified at certain eigenmodes of the fluid system. Numerical solutions illustrate that resonant convection results in a conspicuous enhancement of time-mean mass transfer rate.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1195-1200
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• 2004

A fully coupled fluid flow, heat, and solute transport model was developed to investigate turbulent flow, solidification, and macrosegregation in a continuous casting process of steel slab with EMBR. Transport equations of mass, momentum, energy, and species for a binary iron-carbon alloy system were solved using a continuum model. The electromagnetic field was described by the Maxwell equations. A finite-volume method was employed to solve the conservation equations associated with appropriate boundary conditions. The effects of intensity of magnetic field and carbon segregation were investigated. The electromagnetic field reduces the velocity of molten flow in the mold and an increase in the percentage of C in steel results in a decrease of carbon segregation ratio.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.6
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• pp.651-657
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• 2010

Solute transport through a groove is affected by its vortices. Our laboratory and numerical experiments of dye transport through a single axisymmetric groove reveal evidence of enhanced spreading and mixing by the vortex, i.e., a new kind of dispersion called here the vortex dispersion. The uptake and release of contaminants by vortices in porous media is affected by the flow Reynolds number. The larger the flow Reynolds number, the larger is the vortex dispersion, and the larger is the mass-transfer rate between the mobile zone and the vortex. The long known dependence of the mass-transfer rate between the mobile and "immobile" zones in porous media on flow velocity can be explained by the presence of vortices in the "immobile" zone and their uptake and release of contaminants.

• Journal of the Korean Ceramic Society
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• v.35 no.10
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• pp.1049-1054
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• 1998

In order to fabricate ideal powders new processing is necessary in which the solute atoms in solution ra-pidly move to mix each other to the degree of molecular level the viscosity of solution should be low not to effect the moving of solute atoms and the powders could be directly obtained as crystalline. Supercritical fluid is defined as condensed gas sated up to its critical pressure and temperature. In this paper su-percritical fluid methods were studied as a new ceramic processing of powder preparation. The crystalline powders of TiO2 which are useful for electronic ceramic materials were fabricated by hydrolysis of titanium (IV) ethoxide using ethanol as a supercritical fluid at the condition of 270$\pm$3$^{\circ}C$, 7.3 MPa for 2hr. The cry stalline anatase powders could be directly obtained and its primary particle size was 20 min.

• Magazine of the Korean Society of Agricultural Engineers
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• v.42 no.2
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• pp.71-77
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• 2000

A multi-region model for solute transport through saturated soils has been developed to describe preferential flow. The model consists of numerous discrete pore groups, which are characterized by a discrete dispersion coefficient, flow velocity, and porosity . The hydraulic properties for each pore group are derived from a soil's hydraluic conductivity and soil water characteristic functions . Flow in pore group is described by the classical advection-disersion equation (ADE). An implict finite difference scheme was applied to the governing equation that results in a block-tridiagonal system of equations that is very efficient and allows the soil to be divided into any number of pore groups. The numerical technique is derived from methods used to solve coupled equations in fluid dynamics problems and can also be applied to the transport of interacting solutes. The results of the model are compared to the experimental data from published papers. This paper contributes on the characteristics of the method when applied to the parallel porosity model to describe preferential flow of solutes in soil.