• Membrane Journal
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• v.28 no.5
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• pp.368-377
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• 2018

The n-nitrilotris(methylene) phosphonic acid (NTPA) potassium salt was synthesized as a draw solute for forward osmosis. NTPA-4K, NTPA-5K and NTPA-6K were synthesized by varying the content of KOH added to NTPA and confirmed by $^1H$-NMR and $^{13}C$-NMR. The osmotic pressure, viscosity, water flux and reverse salt flux were measured to characterize the draw solute. In the forward osmosis process when distilled water was used as a feed solution and 0.5 M of NTPA-4K, NTPA-5K and NTPA-6K were used as a draw solution, the water flux was 35.8, 38.8 and 42.2 LMH, the reverse salt flux was 5.4, 6.9 and 7.4 gMH, respectively. It was confirmed that the water flux was lower than the conventional NaCl draw solution, but the reverse salt flux was much lower. In order to recover the diluted draw solution, nanofiltration was conducted. The results showed that the draw solute could be retained by above 90%.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.3
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• pp.229-243
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• 2013

An in situ solute migration system was designed and installed in KAERI Underground Research Tunnel (KURT) constructed in the site of Korea Atomic Energy Research Institute (KAERI) in order to investigate the migration and retardation of non-sorbing and sorbing tracers through a rock fracture. The system is composed of three main parts including injection, extraction, and data treatment. For the selection of a water-conducting fracture, boreholes were drilled. The fractures in the drilled boreholes were investigated using borehole image analysis using borehole image processing system (BIPS). The results of BIPS analysis showed that borehole YH 3-1 and YH 3-2 were connected each other. Moreover, hydraulic tests were carried out to determine the test section with connectivity for the in situ experiments. The in situ solute migration experiments were accomplished to understand the migration of solutes through fractures in KURT using non-sorbing tracers which were fluorescein sodium, eosin-B, bromide and sorbing tracers which were rubidium, nickel, zirconium, and samarium.

• Journal of Korea Water Resources Association
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• v.54 no.5
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• pp.335-345
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• 2021

The one-dimensional solute transport models have been developed for recent decades to predict behavior and fate of solutes in rivers. Transient storage model (TSM) is the most popular model because of its simple conceptualization to consider the complexity of natural rivers. However, the TSM is highly dependent on its parameters which cannot be directly measured. In addition, the TSM interprets the late-time behavior of concentration curves in the shape of an exponential function, which has been evaluated as not suitable for actual solute behavior in natural rivers. In this study, we suggested a stochastic approach to the solute transport analysis. We delineated the model development and model application to a natural river, and compared the results of the proposed model to those of the TSM. To validate the proposed model, a tracer test was carried out in the 4.85 km reach of Gam Creek, one of the first-order tributaries of Nakdong River, South Korea. As a result of comparing the power-law slope of the tail of breakthrough curves, the simulation results from the stochastic storage model yielded the average error rate of 0.24, which is more accurate than the 14.03 and 1.87 from advection-dispersion model and TSM, respectively. This study demonstrated the appropriateness of the power-law residence time distribution to the hyporheic zone of the Gam Creek.

• Proceedings of the Korea Water Resources Association Conference
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• 1996.05a
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• pp.553-558
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• 1996

• Bulletin of the Korean Chemical Society
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• v.21 no.12
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• pp.1179-1180
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• 2000

• Bulletin of the Korean Chemical Society
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• v.21 no.3
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• pp.351-352
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• 2000

• Journal of applied mathematics & informatics
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• v.25 no.1_2
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• pp.51-66
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• 2007

A layer of compressible, rotating, elastica-viscous fluid heated & soluted from below is considered in the presence of vertical magnetic field to include the effect of Hall currents. Dispersion relation governing the effect of viscoelasticity, salinity gradient, rotation, magnetic field and Hall currents is derived. For the case of stationary convection, the Rivlin-Erickson fluid behaves like an ordinary Newtonian fluid. The compressibility, stable solute gradient, rotation and magnetic field postpone the onset of thermosolutal instability whereas Hall currents are found to hasten the onset of thermosolutal instability in the absence of rotation. In the presence of rotation, Hall currents postpone/hasten the onset of instability depending upon the value of wavenumbers. Again, the dispersion relation is analyzed numerically & the results depicted graphically. The stable solute gradient and magnetic field (and corresponding Hall currents) introduce oscillatory modes in the system which were non-existent in their absence. The case of overstability is discussed & sufficient conditions for non-existence of overstability are derived.

• Journal of Photoscience
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• v.12 no.2
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• pp.57-61
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• 2005

The ground and excited state dipole moments of Coumarin 450 (C 450) laser dye were measured at room temperature in several solvents of varying dipole moments. The ground state dipole moment (${\mu}_g$) is estimated by using the modified Onsagar model and the excited state dipole moments (${\mu}_e$) were estimated by the method of solvatochromism as well as by utilizing the microscopic solvent polarity parameter ($E^N_T$). Further, the deviation of some of the points from the linearity of the $E^N_T$ versus Stokes shift indicates the existence of specific type of solute-solvent interaction. The excited state dipole moment of C 450 were found to be higher than those of the ground state and is interpreted in terms of the resonance structure of the molecule. A reasonable agreement has been observed between the values obtained by the method of solvatochromism and modified Onsagar model. It is observed that, corresponding to cyclohexane solution, the fluorescence maxima shift towards the red region with increasing the polarity of the solvents, hence the transition involved are of ${\pi}-{\pi}^*$ type.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.1236-1239
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• 2004

The object of this study is to develop a model of the cardiovascular system capable of simulating the short-term transient and steady-state hemodynamic responses such as hypotention and disequilibrium syndrome during hemodialysis or hemofiltration. The model consists of a closed loop 12 lumped-parameter representation of the cardiovascular circulation connected to set-point models of the arterial and cardiopulmonary baroreflexes and 3 compartmental body fluid and solute kinetic model. The hemodialysis model includes the dynamics of sodium, urea, and potassium in the intracellular and extracellular pools, fluid balance equations for the intracellular, interstitial, and plasma volumes. We have presented the results of many different simulations performed by changing a few model parameters with respect to their basal values.

• Journal of Environmental Science International
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• v.5 no.4
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• pp.495-511
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• 1996

The quantitative study of the groundwater contamination in a porous media is a difficult task. For complex problems, numerical solutions are the most effective means to study the movement of contaminants in the groundwater, The solute transport model used in this study has proved to be an efficient tool to model contaminant transport for complex problems. The model demonstrates its effectiveness in reproducing the coniamination by ihlorides of the groundwater at the landfill site due to leachath from the wastes. It describes the two dimentional solute transport and alteration of the water quality and forecasts the contamination for different management alternatives of the landfill. The model also indicates how the groundwater contamination can be contained within the lower site if a barrier is constructed downstream of the disposed wastes.