• Title/Summary/Keyword: Solidified layer

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Particle Refinement and Nano-structure Formation of Gas Atomized Al-14wt.%Ni-14 wt.%Mm Alloy Powder by Mechanical Milling (가스 분사된 Al-14wt.%Ni-14wt.%Mm 합금 분말의 기계적 밀링에 의한 입자 미세화와 나노조직 형성)

  • 홍순직;이윤석;천병선
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.26-33
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    • 2003
  • Al-l4wt.%Ni-l4wt.% Mm(Mm=misch metal) alloy powders rapidly solidified by the gas atomization method were subjected to mechanical milling(MM). The morphology, microstructure and hardness of the powders were investigated as a function of milling time using scanning electron microscopy(SEM), transmission electron microscopy(TEM) and Vickers microhardness tester. Microstructural evolution in gas-atomized Al-l4wt.%Ni-l4wt.% Mm(Mm=misch metal) alloy powders was studied during mechanical milling. It was noted that the as-solidified particle size of $200\mutextrm{m}$ decreases during the first 48 hours and then increases up to 72 hours of milling due to cold bonding and subsequently there was continuous refinement to $20\mutextrm{m}$ on milling to 200 hours. Two microstructurally different zones, Zone A, which is fine microstructure area and Zone B, which has the structure of the as-solidified powder, were observed. The average thickness of the Zone A layer increased from about 10 to $15\mutextrm{m}$ in the powder milled for 24 hours. Increasing the milling time to 72 hours resulted in the formation of a thicker and more uniform Zone A layer, whose thickness increased to about $30~50\mutextrm{m}$. The TEM micrograph of ball milled powder for 200 hours shows formation of nano-particles, less than 20 nm in size, embedded in an Al matrix.

Preparation of Cu-Ag Powder having Core-Shell Structure by Electroless Plating Method (무전해 도금법을 이용한 코어 셸 구조의 Cu-Ag분말 제조)

  • Kim, Jong-Wan;Lee, Huk-Hee;Won, Chang-Whan
    • Journal of the Korean institute of surface engineering
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    • v.42 no.1
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    • pp.47-52
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    • 2009
  • Cu-Ag powder having Core-Shell structure was prepared from by electroless plating method using agents such as $AgNO_3$, $NH_{4}OH$, Hydroquinone. Ag coated copper powders were analyzed using scanning electron microscopy(SEM) and energy dispersive X-ray spectrometer(EDX). The silver coating layer of copper powder was affected from various reaction conditions such as molar ratio of $NH_{4}OH$, $AgNO_3$, and pulp density. Free silver was generated below 0.1M or 0.3M and above of $NH_{4}OH$ mole ratio. Silver coating layer thickened as addition of $AgNO_3$. When the pulp density reached 12% with 0.2M $NH_{4}OH$, and 0.15M $AgNO_3$ at $4^{\circ}C$, silver was homogeneously distributed around the copper particles and free silver particles were not generated.

Design and Fabrication of Durable Micro Heater for Intelligent Mold System (금형온도 능동제어 시스템 적용을 위한 고 내구성 마이크로 히터의 설계 및 제작)

  • Noh Cheolyong;Kim Youngmin;Choi Yong;Kang Shinill
    • 정보저장시스템학회:학술대회논문집
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    • 2005.10a
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    • pp.26-30
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    • 2005
  • Stamper surface temperature is very critical in replicating the high density optical disc substrates using injection molding as the pit or land/groove patterns on the optical disc substrate have decreased due to the rapid increase of areal density. During the filling stage, the polymer melt in the vicinity of the stamper surfaces rapidly solidifies and the solidified layer generated during polymer filling greatly deteriorates transcribability and fluidity of polymer melt. To improve transcribability and fluidity of polymer melt, stamper surface temperature should be controlled such that the growth of the solidified layer is delayed during the filling stage. In this study, the effect of heating on replication process was simulated numerically. Then, an injection mold equipped with instant active heating system was designed and constructed to raise the stamper surface temperature over the glass transition temperature during filling stage of the injection molding. Also, the closed loop controller using the Kalman filter and the linear quadratic Gaussian regulator was designed. As a result, the stamper surface temperature was controlled according to the desired reference stamper surface temperature.

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Design and Fabrication of Durable Micro Heater for Intelligent Mold System (금형온도 능동제어 시스템 적용을 위한 고 내구성 마이크로 히터의 설계 및 제작)

  • Noh, Cheol-Yong;Kim, Young-Min;Choi, Yong;Kang, Shin-Ill
    • Transactions of the Society of Information Storage Systems
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    • v.2 no.2
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    • pp.100-104
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    • 2006
  • Stamper surface temperature is very critical in replicating the high density optical disc substrates using injection molding as the pit or land/groove patterns on the optical disc substrate have decreased due to the rapid increase of areal density. During the filling stage, the polymer melt in the vicinity of the stamper surfaces rapidly solidifies and the solidified layer generated during polymer filling greatly deteriorates transcribability and fluidity of polymer melt. To improve transcribability and fluidity of polymer melt, stamper surface temperature should be controlled such that the growth of the solidified layer is delayed during the filling stage. In this study, the effect of heating on replication process was simulated numerically. Then, an injection mold equipped with instant active heating system was designed and constructed to raise the stamper surface temperature over the glass transition temperature during filling stage of the injection molding. Also, the closed loop controller using the Kalman filter and the linear quadratic Gaussian regulator was designed. As a result. the stamper surface temperature was controlled according to the desired reference stamper surface temperature.

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Development of Dissipation Model of Excess Pore Pressure in Liquefied Sand Ground (액상화된 모래지반의 과잉간극수압 소산모델 개발)

  • Kim, Sung-Ryul;Hwang, Jae-Ik;Ko, Hon-Yim;Kim, Myoung-Mo
    • Journal of the Korean Geotechnical Society
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    • v.23 no.10
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    • pp.13-22
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    • 2007
  • Recently, many researches on the dissipation of excess pore pressure in liquefied sand grounds have been performed to evaluate post-liquefaction behavior of structures. In this research, centrifuge tests were performed to analyze liquefaction behavior of level saturated sand grounds. Based on the test results, the evaluation model of solidified layer thickness was developed to simulate non-linear variation of the thickness with time. The thickness evaluation model was combined with the solidification theory and the consolidation theory in order to simulate dissipation of excess pore pressure. The suggested dissipation model properly estimated the solidified layer thickness and the time history of excess pore pressure.

Numerical Study on the 300 MW Shell-type One-stage Entrained Flow Coal Gasifier Apllied with 4-Layer Slagging Model (4-Layer Slagging Model을 적용한 300 MW급 Shell형 1단 분류층 석탄 가스화기 전산수치해석)

  • Hong, Jung-Woo;Jeong, Hyo-Jae;Song, Ji-Hoon;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.17 no.1
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    • pp.1-11
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    • 2012
  • A slag building simplified model was developed to determine wall heat flux of a Shell 300 MW coal gasifier. In the model 4 layers(particulate, sintered, molten slag, solidified slag) were considered and mass conservation and energy balance were used to obtain each slag layer's thickness and surface temperature. Thermo-chemical and fluid charateristics of the gasifier were studied with and without considering the slag model using commercial CFD code FLUENT. Consideration of the slag layer did not affect syn-gas mole fractions. However, the slag layer caused to increase the exit gas temperature by about 50 K.

Temperature Characteristics of Wet-mixing Solidified Soil Pavement (습식교반경화토포장의 온도특성)

  • Yoo Ji-Hyeung;Lee Seong-Won;Kim Dae-Sung
    • International Journal of Highway Engineering
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    • v.8 no.1 s.27
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    • pp.45-54
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    • 2006
  • The Construction policy of government ever since 1970s have brought the economical growth, but has been causing environmental problems. Most roads were paved either asphalt concrete or portland cement concrete. These types of pavements has caused to rise temperature by making local heat islands in urban during summer time. Recently the wet-mixing solidified soil pavement, a kind of soil-cement, has developed and has been applied to the environment-oriented pavement. The solidified soil wet-mixed is placed on the subgrade along with asphalt concrete and portland cement concrete. Thermistors are laid in these field test pavements. The temperature gradients of these pavements are automatically measured with time. As the results of this test, the equation estimating surface temperature of pavement is proposed by analyzing measured temperature data. It is shown that the temperature change within the surface layer due to the change of air temperature is the greatest in the asphalt mixture and the least in the solidified soil mixture. Since it is proven that this wet-mixing solidified soil pavement emit less radiant heat than other existed pavements. Therefore this type of pavement can be successfully applied to the roads, such as walks, parkways, and bikeways, which are required to be human-friendly and environment-oriented.

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The Effects of Solidified Sewage Sludge as a Soil Cover Material for Cultivation of Bioenergy Crops in Reclaimed Land (에너지작물 재배를 위한 간척지 토양의 토양복토재로써 하수슬러지 고화물의 이용효과)

  • An, Gi-Hong;Koo, Bon-Cheol;Choi, Yong-Hwan;Moon, Youn-Ho;Cha, Young-Lok;Bark, Surn-Teh;Kim, Jung-Kon;Yoon, Yong-Mi;Park, Kwang-Guen;Kim, Jang-Taeck
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.3
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    • pp.238-247
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    • 2012
  • To determine the possibility of solidified se wage sludge for use as a soil cover material in reclaimed land, the growth of energy crops and soil chemical properties investigated in each experimental plots during 2 years (2010 and 2011). The experimental plots consisted of the mixing with solidified sewage sludge plot (SS50), the covering with solidified sewage sludge plot (SS100), and the original reclaimed land plot (ORL) on reclaimed land for the intended landfill in Sudokwon Landfill Site Management Corporation (SLC). Plant height, measured in the second year (2011), was highest in the Geodae 1 grown at plots treated with solidified sewage sludge. The growth of energy crops cultivated in both SS50 and SS100 were better than in ORL. The contents of organic matter (OM) and total nitrogen (T-N) at both SS50 and SS100 were considerably higher than that of the ORL over 2 years. However, the soil from ORL showed higher salinity with high contents of exchangeable $Na^+$ cation than that of SS50 and SS100 over 2 years. We consider that soil chemical and physical properties on reclaimed land used in this study could be improved by the application of solidified sewage sludge due to following reasons. Firstly, the application of solidified sewage sludge may provide soil nutrients on reclaimed land i.e. the growth of energy crops better than in ORL, resulted in more OM and T-N contents in SS50 and SS100. Secondly, the top layers mixed or covered with solidified sewage sludge on reclaimed land may be prevented the salinity accumulation due to capillary rise to surface soil, and improved the cultivation layer for effectively propagating the rhizomes of energy crops. Thus the solidified sewage sludge may be a great soil cover materials for cultivation of bioenergy crops in reclaimed land.

Enhanced Adhesion and Transmittance Uniformity in Laminated Polymer-Dispersed Liquid Crystal Films

  • Yoo, Seong-Hyeon;Park, Min-Kyu;Park, Ji-Sub;Kim, Hak-Rin
    • Journal of the Optical Society of Korea
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    • v.18 no.6
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    • pp.753-761
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    • 2014
  • We propose a two-step UV irradiation procedure to fabricate polymer-dispersed liquid crystal (PDLC) films by lamination. During the first UV treatment, before lamination, the UV-curable monomers coated on one film substrate are solidified through photo-polymerization as the phase separation between the liquid crystals and the monomers. Introducing an adhesion-enhancement layer on the other plastic substrate and controlling the UV irradiation conditions ensure that UV-induced cross-linkable functional groups remain on the surfaces of the photo-polymerized layers. Thereby, the adhesion stability between the top and bottom films is much improved during a second (post-lamination) UV treatment by further UV-induced cross-linking at the interface. Because the adhesion-enhancement and PDLC layers prepared by the bar-coating process are solidified before lamination, the PDLC droplet distribution and the cell gap between the two plastic substrates remain uniform under the lamination pressure. This ensures that the voltage-controlled light transmittance is uniform across the entire sample.

Preparation and Radionuclide Detection Analysis of Inorganic Fluor Impregnated Double-layered Membranes (이중구조 무기형광 함침막 제조 및 방사성핵종 탐지능력의 분석)

  • 이근우;서범경;박진호;남석태;한명진
    • Membrane Journal
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    • v.12 no.4
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    • pp.240-246
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    • 2002
  • New polysulfone scintillation proximity membranes were prepared by impregnating Cerium Activated Yttrium Silicate (CAYS), an inorganic fluor, in a membrane structure. The membranes were applied to detect the radionuclide contamination directly without the aid of a scintillation cocktail. The preparation of membranes was divided into two processes. A supporting polymer film was made of casting solutions consisting of polysulfone and solvent, their cast film being solidified by vacuum evaporation. CAYS-dispersed polymer solutions were cast over the first, solidified polymer films and coagulated either by evaporating solvent or by exchanging solvent in the solution with nonsolvent in a coagulation bath. The prepared membranes had two distinguished, but tight1y attached, double layers: one is the supporting layer of dense polymer film and the other the detecting layer consisting of CAYS and polymer. The radionuclide counting results revealed that the prepared membranes were efficient to monitor radioactivity contamination with reliable counting ability.