• 한국자동차공학회논문집
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• 제22권4호
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• pp.152-159
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• 2014

Urea solution as a reductant of SCR has been widely used to reduce NOx emissions from diesel engine. But it has lots of problems which are freezing at low temperature due to liquid state, deposition of solid formation in the exhaust, dosing device, and complex package such as mixers for uniform concentration of ammonia. In order to overcome these obstacle, ammonium carbonate which is one of solid ammonium materials to produce ammonia gas directly by sublimation process is considered. Simple reactor with visible widow was designed to predict equilibrium temperature and pressure of ammonium carbonate. To simulate real operation conditions under automobile environment, several cycles of heating and cooling condition were settled, two different re-solidification materials were extracted from the reactor and visible window. Analytical study is performed to characterize these unknown materials by XRD(X-Ray Diffraction), FT-IR(Fourier Transform Infrared Spectroscopy), and EA(Elemental Analyzer). From analytical results, re-solidification materials from heating and cooling cycles are very similar to original material of ammonium carbonate.

• 대한기계학회논문집
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• 제17권1호
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• pp.162-171
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• 1993

본 연구에서는 2성분혼합물의 응고과정해석에 머시영역의 비등방성을 포함시 킬수 있는 모델을 정립하고 실제계산을 수행하여 비등방성이 천이현상 및 조대편석(m- acrosegregation)에 미치는 영향을 보이고자 한다. 이 과정에서 기본 방정식의 변형 을 통한 수치해석의 효율화에 관해서도 취급할 것이다. 해석대상은 비등방성의 효과 가 잘 나타날 수 있으면서 해석은 용이한 2차원 정사각형용기로 선택하였다. 대상혼 합물은 실용적으로 관심있는 금속 합금과 결정구조가 유사하며 물성치가 비교적 잘 확 립된 염화암모늄수용액(NH$_{4}$C1-H$_{2}$O)이다. 특히 아공정염화암모늄수용액은 부력비(buoyancy factor)가 -1.4정도로서 온도와 농도구배에 의한 부력이 크기는 비슷 하지만 작용방향이 반대이기 때문에 이중확산대류의 전형적인 형태를 고찰하기에 편리 한 물질이다.

• Journal of Welding and Joining
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• 제2권1호
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• pp.4-17
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• 1984

Overlaid weld metals of austenitic stainless steel in a pressure vessel of power reactor are usually post-weld heated for a long period of time after welding. The PWHT is considered as a kind of sensitizing and it is important to check the soundness of the weld metal after PWHT, especially about the precipitation of carbides. The purpose of this report is to obtain information on the relation between the change of microstructure and Post-Weld Heat Treatment in the overlaid weld metals. Metallurgical aspects of the problem on austenitic stainless steel heated at $625^{\circ}C$, $670^{\circ}C$, $720^{\circ}C$ and $760^{\circ}C$ for 3, 10, 30, 100 and 300 hours have been investigated by means of optical-micrography, micro-hardness measurement, scanning electron microscope and electron-probe micro analysis. From the results obtained, the following conclusions are drawn; 1) The PWHT above $625^{\circ}C$ for a long time causes a diffusion of carbon atoms from low alloy steel into stainless steel, and consequently carbon is highly concentrated at the boundary layer of stainless steel. 2) C in ferritic steel migrated to austenitic steel and carbides precipitated in austenitic steel along fusion line. At higher temperatures, the ferrite grains coarsened in the decarburized zone. 3) In the change of microstructure of stainless steel overlaid weld metal, the width of carbides precipitated zone and decarburized zone increased with increase of PWHT temperature and time. 4) At about $625^{\circ}C$ to $760^{\circ}C$, chromium carbides, mainly $M_{23} C_6$, precipitate very closely in the carburized layer with remarkable hardening. 5) Precipitation of delta ferrite from molten weld metal depends on solidification phenomenon. There was a small of ferrite near the bond in which the local solidification time was short, comparing with after parts of weld metal. Shape and amount of ferrite were not changed by Post-Weld Heat Treatment after solidification.

• 열처리공학회지
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• 제22권2호
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• pp.95-100
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• 2009

In this study, the casting process using forged insert was investigated to characterize the manufacturing process by which good mechanical properties can be obtained when compared with existing casting products. Process analysis for the casting design was performed by using FVM (Finite Volume Method) software. In pouring process, three kinds of candidate gating systems are considered and analyzed respectively. The molten metal behavior in gating system is so important that it affects the solidification behavior of the cast. The results show that as the number of gates is increased, hardness of cast was increased and gaps of cast with forged insert were decreased.

• 한국결정성장학회지
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• 제8권1호
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• pp.187-192
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• 1998

일반적으로 재료의 응고조직은 주상정과 등축정 수지상 영역으로 이루어지는데 이것은 제품의 기계적, 물리적 성질과 밀접한 관계를 가지기 때문에 주상정-등축정 천이에 관한 많은 이론적 연구가 행하여지고 있다. 본 연구에서는 J.D. Hunt에 의하여 일방향응고시 주상정앞에서의 핵생성과 결정성장조건을 이용하여 구하여진 해석학적 주상정-등축정 조건식을 바탕으로 응고속도에 따라 변하는 분배계수와 액상선기울기를 적용하여 수정된 조건식을 구하였다. 그리고 Al-Cu합금에 대하여 응고변수인 핵생성수, 핵생성온도, 합금의 조성, 응고속도 온도기울기에 따른 천이현상의 변화를 조사하였다.

• 소성∙가공
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• 제7권2호
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• pp.139-149
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• 1998

The technology of Semi-Solid Forging(SSF) has been actively developed to fabricate near net shape products using light and hardly formable materials. Generally the SSF process is composed of slug is compressed during a certain holding time in order to completely fill the die cavity and accelerate the solidification rate. The decision of compression time is important since it can affect microstructural characteristics, mechanical properties and shape of products.. In order to determine it proper overall heat transfer coefficient between the slug and dies should be investigated. This paper presents the procedure to find the overall heat transfer coefficient between the slug and dies by nonlinear optimization of temperature and solid fraction for a cylindrical slug at compression step in closed-die semi-solid forging. In finite ele-ment heat transfer analysis release of latent heat during solidification was considered. The influence of the predicted compression time on miscrostructural characteristics mechanimcal properties and shape of products is finally investigated by experiment.

• 대한기계학회논문집B
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• 제23권10호
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• pp.1254-1264
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• 1999

A three-dimensional coupled turbulent fluid flow and solidification process were analyzed in a continuous casting process of a steel slab with Electromagnetic Brake(EMBR). A revised low-Reynolds number $k-{\varepsilon}$ turbulence model was used to consider the turbulent effects. The enthalpy-porosity relation was employed to suppress the velocity within a mushy region. The electromagnetic field was described by Maxwell equations. Tile application of EMBR to the mold region results in the decrease of the transfer of superheat to the narrow face, the increase of temperature in free surface region and most liquid of submold region, and the higher temperature gradient near the solidifying shell. The increasing magnetic flux density effects mainly to the surface temperature of the solidifying shell of narrow face, hardly to the one of wide face. It is seen that in the presence of EMBR a thicker solidifying shell is obtained at the narrow face of the slab.

• 한국주조공학회지
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• 제14권5호
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• pp.464-470
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• 1994

The horizontal continuous casting method with the heated mold was applied to study the solidification structures of the pure Al and Al-0.5wt%Si and Al-1.0wt%Si alloy rods. The results could be summarized as follows: 1. The S/L interface structures of pure Al represented the hexagonal cells at the casting speed of 590 and 350mm/min, respectively. However, the hexagonal cells became irregular as the casting speed and(or) Si amount increased. 2. The striation increased as the Si amount and casting speed increased and was found to result from the occurrence of growth twin crystals by XRD analysis. 3. The striation did not affect the mechanical and electrical property of the drawn wire from the casted rod. This means the striation is not a serious defect which has to consider in the production of micro-sized fine wire in the drawing process.

• 한국주조공학회지
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• 제16권2호
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• pp.141-148
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• 1996

In high chromium cast iron, the control of matrix microstructure as well as carbide structure is important to the performance as a wear resistant material. In this study, 3.0% C-24.0% Cr white cast irons with various molybdenum contents(residual, 1.0%, 3.0% and 5.0%) were solidified conventionally and unidirectionally for studying their effects on the microstructure and hardness. In the conventional casting, two sets of castings were poured from each melt. One set of the castings consisted of cylindrical bars of 10 and 20mm by 155mm long. The second set of the castings was a cylindrical bar of 30mm by 200mm long. On the other hand, a pep-set mold set on the Cu plate was employed to make the solidification unidirectionally. X-ray diffraction method was used to observe retained austenite and carbides in the high chromium cast iron. The morphology of eutectic $M_7C_3$ carbides changed from needle-like type to nodular type with the increase of Mo content. And, the presence of $M_2C$ carbides was identified in the sample where Mo was added over 3.0 %. Primary and eutectic carbides appeared as rod type and corngrain type, respectively in the unidirectionally solidified samples which were cut to parallel to the solidification direction. In the EDX analysis, Cr concentration was higher in the primary and eutectic $M_7C_3$ carbides, Mo in the $M_2C$ carbides, and Fe in the matrix.

• 한국결정성장학회지
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• 제6권1호
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• pp.19-31
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• 1996

갈륨 비소 반도체 결정을 성장시키는 데 많이 사용되는 수평브렷지만법에 의하여 성장된 갈륨비소 단결정 내에셔 불순물 분포를 알아보기 위하여 액상에서 열전달, 물질전달, 유 체흐름과 고상에서 열전달을 묘사하는 과도기 모탤을 수립하였고 유한요소법과 음함수 척분법 에 의하여 수치모사를 행하였다. 그 결과 Gr이 작은 경우에는 확산조절성장의 특성을 보였으며 G Gr이 1,700 정도만 되어도 농도의 최소값이 계면 근처로 이동하였다. 응고가 진행됨에 따라 계 면의 곡률이 증가하였고, 흐름에 의한 혼합이 안정될 때까지 수직편석이 증가하였다. 수펑편석 은 응고가 진행됨에 따라 증가하였지만 흐름의 강도가 강한 경우에는 곧 일정하게 유지되였다. G Gr이 아주 작거나 큰 경우에는 Smith식과 Scheil식의 경우와 잘 일치하였다.