• Title/Summary/Keyword: Solidfication

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Microstructure of the Hybrid Al2O3-TiC/Al Composite by Rapid Solidification and Stone Mill Process. (급속응고 및 Stone Mill 공정에 의해 제조된 하이브리드 Al2O3-TiC/Al 복합재료의 미세조직)

  • 김택수;이병택;조성석;천병선
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.15-20
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    • 2003
  • Hybrid $A1_2O_3-TiC$ ceramic particle reinforced 6061 and 5083 Al composite powders were prepared by the combination of twin rolling and stone mill crushing process, followed by consolidating processes of cold compaction, degassing and hot extrusion. The composite bar consists of lamellar structure of ceramic particle rich area and matrix area, in which the hybrid was decomposed into each TiC of about $3-4\mutextrm{m}$ and $AI_2O_3$ particles of about $1-2\mutextrm{m}$ in diameter. It also found that fine $Mg_2Si$ precipitates of about 30 nm were embedded in the matrix, which have grains of about 3 $\mutextrm{m}$. Higher UTS was measured at the 5083 composite bar compared to the conventionally fabricated composite, due to again refinement effect by the rapid solidification. No particle was shown to form in the interface between the matrix and reinforcement, whereas carbon was diffused into the matrix.

Effects of Porous Microstructure on the Electrochemical Properties of Si-Ge-Al Base Anode Materials for Li-ion Rechargeable Batteries (리튬이차전지용 다공성 Si-Ge-Al계 음극활물질의 전기화학적 특성)

  • Cho, Chung Rae;Kim, Myeong Geun;Sohn, Keun Yong;Park, Won-Wook
    • Journal of Powder Materials
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    • v.24 no.1
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    • pp.24-28
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    • 2017
  • Silicon alloys are considered promising anode active materials to replace Li-ion batteries by graphite powder, because they have a relatively high capacity of up to 4200 mAh/g, and are environmentally friendly and inexpensive ECO-materials. However, its poor charge/discharge properties, induced by cracking during cycles, constitute their most serious problem as anode electrode. In order to solve these problems, Si-Ge-Al alloys with porous structure are designed as anode alloy powders, to improve cycling stability. The alloys are melt-spun to obtain the rapidly solidified ribbons, and then ball-milled to make fine powders. The powders are etched using 1 M HCl solution, which gives the powders a porous structure by removing the element Al. Subsequently, in this study, the microstructures and the characteristics of the etched powders are evaluated for application as anode materials. As a result, the etched porous powder shows better electrochemical properties than as-milled Si-Ge-Al powder.

A study on transient liquid phase diffusion bonding of 304 stainless steel and structural carbon steels (304 스테인레스강과 구조용탄소강과의 천이액상확산접합에 관한 연구)

  • 김우열;정병호;박노식;강정윤;박세윤
    • Journal of Welding and Joining
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    • v.9 no.4
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    • pp.28-39
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    • 1991
  • The change of microstructure in the bonded interlayer and mechanical properties of the joints were investigated during Transient Liquid Phase Diffusion Bonding(TLP bonding) of STS304/SM17C and STS304/SM45C couples using Ni base amorphous alloys added boron and prepared alloy as insert metal. Main experimental results obtained in this study are as follows: 1) Isothermal solidification process was completed much faster than theoretically expected time, 14ks at 1473K temperature. Its completion times were 3.6ks at 1423K, 2.5ks at 1473K and 1.6ks at 1523K respectively. 2) As the concentration of boron in the insert metal increased, the more borides were precipitated near bonded interlayer and grain boundary of STS304 side during isothermal solidification process, its products were $M_{23}P(C,B)_6}_3)$ The formation of grain boundary during isothermal solidification process was completed at structural carbon steel after starting the solidfication at STS304 stainless steel. 4) The highest value of hardness was obtained at bonded interface of STS304 side. The desirable tensile properties were obtained from STS304/SM17C, STS304/SM45C using MBF50 and experimentally prepared insert metal with low boron concentration.

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