• 한국자기공명학회논문지
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• 제5권1호
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• pp.19-28
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• 2001

Miscibility and morphology in blends of bisphenol-A type polycarbonate and poly (ester-ether) elastomer with different compositions are studied by solid-state NMR spectroscopy. $^{13}$ C Solid-state NMR of CP/MAS/TOSS/DD, CP/MAS/DD, inversion recovery CP/MAS/DD, and 2D rotor driven spin diffusion techniques are used to identify the miscibility, morphology, and transesterification in blends. The blends of PC /BT elastomer with 15% to 42% of soft segment seem to be single phase miscible mixing and those of PC/PBT and PC/PBT elastomer with 62% of soft segment are cocontinuous two phase immiscible mixing. No significant transesterification reactions are observed in blends with different compositions.

• 한국토양비료학회지
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• 제49권3호
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• pp.227-234
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• 2016

The influence of mixing on biogas production and organic material removal performance of solid state anaerobic digestion of dairy manure and sawdust bedding mixtures was evaluated using 22 L volume lab-scale digesters. After 45 days of anaerobic digestion at $37^{\circ}C$, cumulative methane yield of unmixed test unit ($73.1N{\cdot}mL/g-VS$) was almost 1.3 times of that of mixed one ($56.3N{\cdot}mL/g-VS$). The biodegradable volatile solids removal rate of unmixed test unit was 67%, which was almost 28% greater than mixed one. Our results reveal that unmixed condition is better than mixed one in terms of biogas production and organic material reduction.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 2006년 제4회 한국유체공학학술대회 논문집
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• pp.471-474
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• 2006

The Mixer is apparatus that help precipitation or an inhomogeneous distribution of various phases to be mixed and that user makes necessary material mixing one or the other. Mainly the mixer which is used from chemical and food industry is very important system in engineering that mixes the material. The inside flow of the mixer under the actual states which put a basis in flow of the fluid is formed rotation of the impeller. The inside flow of impeller will be caused by various reasons change with shape of impeller, number of rotation, mixing material and flow pattern of free surface etc. Also mixer study depended in single-phase flow and experimental research. So the numerical analysis of flow mixing solid-fluid particle is simulated. It is become known, that the case where agitator inside working fluid includes the solid particle the sinkage reverse which the solid particle has decreases an agitation efficiency. From the research which it sees the hazard solid which examines the effect where the change of the sinkage territory which it follows agitation number of revolution and diameter of the particle goes mad to an agitator inside flow distribution - numerical analysis the inside flow distribution of liquid state with Eulerian Two-Phase Method.

• Mycobiology
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• 제30권4호
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• pp.228-232
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• 2002

This study focused on the production of high quality compost for the growth of aero-thermophilic fungi, which has a promoting effect on the growth rate and production of oyster mushrooms. The automated solid-state bioreactor system was designed on the basis of a Three-Phase-One system, which controls the serial steps of prewetting, pasteurization and fermentation processes. High numbers of thermophilic fungi and bacteria were recovered from the mushroom composts prepared by this solid-state bioreactor. The rates of composting process were depended on physical as well as chemical factors. Among these factors, the parameters of moisture content and temperature were found to be particularly important. In our automated system, constant levels of moisture content, temperature and ventilation via mixing were provided by a centralized control apparatus including PLC, water tank and water jacket systems. These features induced higher microbiological activity of aero-thermophiles.

• 한국자기공명학회논문지
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• 제21권4호
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• pp.114-118
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• 2017

Here, I report solid state Dynamic Nuclear Polarization (DNP) of $^1H$ nuclear spins at 0.3 T and 4.2 K. The DNP polarizer was developed based on a commercial X-band Electron Spin Resonance (ESR) modified for DNP, in combination with a NMR console and a liquid-Helium cryostat. By detuning magnetic field, DNP spectrum was measured to find the optimal condition. At +3 mT detuned from on-resonance field, $^1H$ NMR signal of 60:40 glycerol/water frozen solution doped with 20 mM perdeuterated-Tempone was amplified 43 times. The $^1H$ spin polarization obtained at 4.2 K is over 3100 times higher than that at 300 K. The width of the DNP spectrum, which is five times broader than ESR spectrum, is inconsistent with solid effect or thermal mixing, and presumably suggests a different DNP mechanism.

• 한국결정성장학회지
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• 제9권6호
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• pp.601-605
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• 1999

$LiCoO_2$와 고용체 화합물인 $LiCo_{1-x}Ni_XO_2$을 고상반응법을 이용하여 제조하여 XRD, SEM, 입도분석, $^7$Li NMR을 통하여 그 구조적 cation mixing 현상을 조사하였다. 고상반응법으로 합성한 $LiCoO_2$와 $LiCo_{1-x}$$Ni_x$$O_2$의 미세결정상은 hexagonal layered structure를 보여주었고 전반적인 입도는 니켈의 함량에 따라 증가되었다. 고용체에 있어서 Ni의 함량 분율(x)이 x=0.3, 0.5, 0.7로 Ni의 양이 증가함에 따라 cation mixing 효과가 증가되었다. $^7$Li NMR의 peak frequency는 Ni의 함량이 증가함에 따라 high frequency로 shift되었고 line width는 Ni의 함량에 따라 넓어지는 양상을 보여주었다.

• 한국진공학회지
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• 제12권S1호
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• pp.7-9
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• 2003

Solid-state reactions in Ni/Si multilayered films (MLF) with an overall stoichiometry of $Ni_2Si$, NiSi and $NiSi_2$, induced by ion-beam mixing (IBM) and thermal annealing, were studied by using spectroscopic ellipsometry and magneto-optical spectroscopy as well as x-ray diffraction (XRD). The mixing was performed with Ar+ ions of an energy of 80 keV and a dose of $1.5 x\times10^{16}$ $Ar^+$/$\textrm{cm}^2$. It was shown that the IBM induces structural changes in the Ni/Si MLF, which cannot be detected by XRD but are confidently recognized by the optical method. A thermal annealing at 673 K of the Ni/Si MLF with an overall stoichiometry of NiSi and $NiSi_2$ causes formation of the first η -NiSi phase. The first trace for $NiSi_2$ phase on the background of NiSi one was detected by XRD after an annealing at 1073 K while, according to the optical results, $NiSi_2$ turns out be the dominant phase for the annealed Ni/Si MLF with an overall stoichiometry of $NiSi_2$.

• ETRI Journal
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• 제42권1호
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• pp.129-137
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• 2020

All-solid-state batteries are promising energy storage devices in which high-energy-density and superior safety can be obtained by efficient cell design and the use of nonflammable solid electrolytes, respectively. This paper presents a systematic study of experimental factors that affect the electrochemical performance of all-solid-state batteries. The morphological changes in composite electrodes fabricated using different mixing speeds are carefully observed, and the corresponding electrochemical performances are evaluated in symmetric cell and half-cell configurations. We also investigate the effect of the composite electrode thickness at different charge/discharge rates for the realization of all-solid-state batteries with high-energy-density. The results of this investigation confirm a consistent relationship between the cell capacity and the ionic resistance within the composite electrodes. Finally, a concentration-gradient composite electrode design is presented for enhanced power density in thick composite electrodes; it provides a promising route to improving the cell performance simply by composite electrode design.

• Journal of Advanced Marine Engineering and Technology
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• 제24권1호
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• pp.88-93
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• 2000

In this study, the mixing process of two-phase flow generated by two jets with height difference is analyzed. The primary jet is jetted on the condition of the state mixed pulverized solid particles with air. The height difference between the main jet and the secondary jet is changed into three kinds(0, 32.5, 47.5mm). The velocity vector field, concentration field and turbulent properties of solid particles are measured by using 3-Dimensional Particles Dynamics Analyzer. As the height difference of two jets through the two nozzles increases, the solid particle recirculation zone and the dense zone in the combustion chamber become large. The solid particle concentration at the center of the combustion chamber gets dense because the particle velocity remains slow due to the existence of the solid particle recirculation zone. The particle concentration in the combustion chamber can also be influenced by the hight difference of two jets.

• 한국분말재료학회지
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• 제28권4호
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• pp.287-292
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• 2021

In this study, the layered structures of immiscible Fe and Cu metals were employed to investigate the interface evolution through solid-state mixing. The pure Fe and Cu powders were cold-consolidated by high-pressure torsion (HPT) to fabricate a layered Cu-Fe-Cu structure. The microstructural evolutions and flow of immiscible Fe and Cu metals were investigated following different iterations of HPT processing. The results indicate that the HPT-processed sample following four iterations showed a sharp chemical boundary between the Fe and Cu layers. In addition, the Cu powders exhibited perfect consolidation through HPT processing. However, the Fe layer contained many microcracks. After 20 iterations of HPT, the shear strain generated by HPT produced interface instability, which caused the initial layered structure to disappear.