• 한국수소및신에너지학회논문집
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• 제26권3호
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• pp.271-277
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• 2015

The present paper discusses about noble idea on various reactions including hydrides, hydrogen peroxide and nano-sized metal powders, which do not emit toxic materials as well as carbon dioxide. Here in this paper, the very first-ever concept that heat energy can be generated from the direct reaction between sodium borohydride and hydrogen peroxide is presented. Sodium hydride as fuel can supply hydrogen reacting with oxygen provided by the decomposition of hydrogen peroxide solution. Solid sodium borohydride can be resolved in water and treated as liquid solution for the easy handling and the practical usage although its solid powder can be directly mixed with hydrogen peroxide for the higher reactivity. The thermodynamic analysis was conducted to estimate adiabatic reaction temperatures from these materials. The preliminary experiment on the reactions conducted using sodium borohydride powder and hydrogen peroxide water solution revealed that the self-propagating reaction can occur and that its reactivity increases with an increase of hydrogen peroxide concentration.

• Bulletin of the Korean Chemical Society
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• 제25권3호
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• pp.341-342
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• 2004

• 유기물자원화
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• 제9권2호
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• pp.87-92
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• 2001

발암성 물질 내지는 내분비계장애물질로 인식되고 있는 농약에 대한 관심이 날로 증가함에 따라 잔류농약제거에 관한 연구의 중요성이 증대되고 있다. 본 연구에서는 과산화수소가 첨가된 광산화공정을 이용한 고체상의 표면에 잔류하는 농약의 분해에 관한 실험을 수행하였다. 카바메이트계인 베노밀과 유기염소계인 클로로타로닐을 대상으로 실험을 한 결과 파장은 350nm에서, 과산화수소의 공급은 20%에서 최적처리효율을 나타냈으며 과산화수소 또는 UV 조사를 단독적으로 적용하였을 때 그 제거효과는 미미하였으나 UV와 과산화수소를 병행하여 처리하였을 때 처리효율은 가속화되었다. 최적조건에서 20분간 반응하였을 때 고체상 표면에 잔류하는 베노밀은 약 $2{\mu}g/cm^2$이 제거되었으며, 클로로타로닐은 약$1.88{\mu}g/cm^2$이 제거되었다.

• KSBB Journal
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• 제14권3호
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• pp.358-364
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• 1999

참나무의 전처리에 과산화수소가 미치는 영향을 조사하였다. 반응온도는 $170^{\circ}C$이고 전처리에 사용된 반응용액은 암모니아, 황산 그리고 순수 물이었다.10% 암모니아용액을 사용한 경우 산을 사용하는 경우에 비해 리그닌 제거율은 55%로 상당히 높았지만 헤미셀룰로오스 회수율은 26%로 상당히 낮았다. 그래서 헤미셀룰로오스 회수율을 높이기 위해 암모니아 용액에 산화제인 과산화수소를 첨가하여 반응시켰는데 과산화수소 첨가량의 증가에 따라 리그닌 제거율과 헤미셀룰로오스 회수율의 증가는 크지 않았다. 그리고 과산화수소 첨가량의 증가에 따라 액상으로 용해된 당의 분해가 증가하여 전체 헤미셀룰로오스와 셀룰로오스의 물질수지에 문제가 있었다. 반응기에 주입된 과산화수소는 주로 반응기의 전반부에 충진된 기질과 반응하는 것으로 나타났다. 헤미셀룰로오스 회수율을 높이기 위해서는 알카리용액보다 산성용액에서 기질을 전처리하는 것이 필요하였고 산보다는 물을 사용하였을 때 과산화수소의 효과가 더 컸다.

• Journal of Ecology and Environment
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• 제40권3호
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• pp.136-143
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• 2016

Background: Mussels are stubborn organisms attached to solid substrata by means of byssus threads. The abundance of marine mussel Mytilus edulis in marine facilities like power stations was reason to select among fouling animals. Methods: Mortality patterns as well as physiological behavior (oxygen consumption, foot activity, and byssus thread production) of two different size groups (14- and 25-mm shell length) of M. edulis were studied at different hydrogen peroxide concentrations ($1-4mg\;l^{-1}$). Results: Studied mussels showed progressive reduction in physiological activities as the hydrogen peroxide concentration increased. Mussel mortality was tested in 30 days exposure, and 14 mm mussels reached the highest percentage of 90% while 25 mm mussels reached 81%. Produced data was echoed by Chick-Watson model extracted equation. Conclusions: This study points that, while it could affect the mussel mortality moderately in its low concentrations, hydrogen peroxide has a strong influence on mussels' physiological activities related to colonization. Therefore, hydrogen peroxide can be an alternative for preventing mussel colonization on facilities of marine environment.

• 한국환경과학회지
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• 제25권10호
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• pp.1397-1405
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• 2016

Mussels are stubborn organism attached to solid substrate by byssus threads and caused operational problems in utility of power generating stations. Sole and combined usage of ultrasonic (28 kHz- and 42 kHz- frequencies) and hydrogen peroxide ($H_2O_2$) has studied for control of blue mussel larvae and adult stage in seawater condition. A theoretical wo rking model using disinfection (Chick and Watson type) approaches is presented based on helpful results of experiments. This study also demonstrate that the combined treatment (ultra-sonication with $H_2O_2$) is overall highly efficient than individual treatment would, but on the basis of exposure time, the ultra-sonication was the most efficient among them. Therefore the development of sole and combined technique might be effective practical mitigation strategy against mussel attachment for water handling facilities.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 춘계학술대회 논문집
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• pp.331-334
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• 2009

본 연구에서는 우주 및 수중 동력원을 위한 연료전지 기반 공기 불요 추진 시스템을 개발하였다. 공기 불요 동력 시스템을 위해 과산화수소를 산화제로 선택하였고, 촉매 분해 반응을 통해 산소와 물을 발생하였다. 순수한 산소는 연료전지에 공급되고, 물은 분리한 후 저장된다. 본 연구에서는 고체 상태의 수소화붕소나트륨을 수소원으로 사용하였고, 촉매 가수분해 반응을 통해 순수한 수소를 발생할 수 있었다. 연료전지 기반 공기 불요 동력 시스템을 검증하기 위해 연료전지 시스템을 구축하였고 다양한 조건에서 평가를 수행하였다.

• Asian-Australasian Journal of Animal Sciences
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• 제3권1호
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• pp.1-6
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• 1990

The objective of this experiment was to compare the effect of pH-regulated alkaline hydrogen peroxide (AHP) treatment of rice straw with those of sodium hydroxide (NaOH) and anhydrous ammonia ($NH_3$) treatments on in sacco digestivility. Three non-lactating ruminally cannulated Holstein cows were fed a diet containing 90% forage and 10% concentrate on a dry matter (DM) basis. The AHP treatment significantly (p<0.05) reduced acid detergent lignin content of the straw, resulting in significant (p<0.05) increase of neutral detergent fiber (NDF), acid detergent fiber (ADF) and cellulose concentrations. Disappearance rates of DM and NDF of the straw significantly (p<0.05) increased at the incubation time of 24 h. On the other hand, those of ADF and cellulose were significantly (p<0.05) higher at the incubation time of 12 h than those of the others. The effective degradability of DM(EDDM), NDF(EDNDF), ADF(EDADF) and cellulose (EDCE) were determined using in sacco nylon bag technique on the basis of 0.05/h solid outflow rate. The greater differences (p<0.05) of EDDM, EDNDF, EDADF and EDCE were found between AHP treated straw and the others. In general, AHP treatment of the straw recorded higher digestion coefficients than untreated straw as well as NaOH and $NH_3$ treated straws. The results of this study demonstrate that AHP treatment can be used as a effective method for improving the nutritive value of rice straw for ruminants.

• 한국환경보건학회지
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• 제8권2호
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• pp.33-46
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• 1982

This experiment was carried out for the purpose of reducing alkaloid in reconstituted tobacco sheet and effluent of reconstituted tobacco sheet manufacturing company by treating oxidizing agents such as ozone, sodium hypochlorite, perchloric acid and hydrogen peroxide to tobacco extract created from the manufacturing process of reconstituted tobacco sheet. The effect of alkaloid reduction in tobacco extract by the volume added, time of treatment and pH of oxidizing agents were as follows: 1. When the solid rate of tobacco extract stood at 10 percent, the content of alkaloid, total sugar, total nitrogen and chlorine was 1,600mg/l, 11,000mg/l, 3,200mg/l and 4,000mg/l, respectively. 2. The effect of alkaloid reduction through ozone treatment was in proportion to time of ozone treatment. Alkaloid showed a 31.2 percent reduction under 8 hours' ozone treatment and 0.23g ozone consumed to remove lmg alkaloid. 3. Alkaloid reduction through sodium hypochlorite treatment was influenced by quantity of chlorine in sodium hypochlorite solution. To remove lmg alkaloid, 36.3mg chlorine was used. Reduction of alkaloid was not affected by time of sodium hypochlorite treatment, while showed the best reaction under pH 5-7. 4. The effect of alkaloid reduction by perchloric acid was under the control of the volume added and time of treatment of perchloric acid. The volume of perchloric acid required to remove alkaloid was on the decrease as time of treatment was getting longer. lmg alkaloid was removed by 0.15g perchloric acid under 8 hours' perchloric acid treatment. 5. Alkaloid reduction reacted slowly to the volume added and time of treatment of hydrogen peroxide. Under 8 hours' hydrogen peroxide treatment, it showed maximum removal, registering 10 percent alkaloid reduction.

• 방사성폐기물학회지
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• 제10권2호
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• pp.77-85
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• 2012

본 연구는 우라늄-함유 석회침전물로부터 U을 제거(/회수) 하기위하여 탄산염 산화용해-산성화 침전과 질산용해-과산화수소 침전을 각각 고찰하였다. 석회침전물 내 우라늄을 용해하는 관점에서는 질산용해가 유리하나 (약 98% 이상 용해) 이 경우 U과 Al, Ca, Fe, Mg, Si 등의 공존 불순물이 다량 공용해되고, 또한 과산화수소 침전에서도 상당량의 불순물이 U과 함께 공침전 된다. 한편 탄산염 용해에 의한 산성화 침전은 우라늄의 용해가 90% 이하로 방사성 고체페기물의 부피감용 측면에서는 질산용해 보다 덜 효율적이지만, 우라늄과 불순물의 공용해나 산성화 침전에 의한 우라늄과 불순물의 공침전이 거의 일어나지 않아 보다 순수한 U을 회수하는 측면에서는 매우 효과적이다.