• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.1
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• pp.52-59
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• 2005

The study was targeted to saccharify foodwastes with the cellulolytic and amylolytic enzymes obtained from culture supernatant of Trichoderma harzianum FJ1 and analyze the kinetics of the saccharification in order to enlarge the utilization in industrial application. T. harzianum FJ1 highly produced various cellulolytic (filter paperase 0.9, carboxymethyl cellulase 22.0, ${\beta}$-glucosidase 1.2, Avicelase 0.4, xylanase 30.8, as U/mL-supernatant) and amylolytic (${alpha}$-amylase 5.6, ${\beta}$-amylase 3.1, glucoamylase 2.6, as U/mL-supernatant) enzymes. The $23{\sim}98\;g/L$ of reducing sugars were obtained under various experimental conditions by changing FPase to between $0.2{\sim}0.6\;U/mL$ and foodwastes between $5{\sim}20\%$ (w/v), with fixed conditions at $50^{\circ}C$, pH 5.0, and 100 rpm for 24 h. As the enzymatic hydrolysis of foodwastes were performed in a heterogeneous solid-liquid reaction system, it was significantly influenced by enzyme and substrate concentrations used, where the pH and temperature were fixed at their experimental optima of 5.0 and $50^{\circ}C$, respectively. An empirical model was employed to simplify the kinetics of the saccharification reaction. The reducing sugars concentration (X, g/L) in the saccharification reaction was expressed by a power curve ($X=K{\cdot}t^n$) for the reaction time (t), where the coefficient, K and n. were related to functions of the enzymes concentrations (E) and foodwastes concentrations (S), as follow: $K=10.894{\cdot}Ln(E{\cdot}S^2)-56.768,\;n=0.0608{\cdot}(E/S)^{-0.2130}$. The kinetic developed to analyze the effective saccharification of foodwastes composed of complex organic compounds could adequately explain the cases under various saccharification conditions. The kinetics results would be available for reducing sugars production processes, with the reducing sugars obtained at a lower cost can be used as carbon and energy sources in various fermentation industries.

• Journal of the Korean GEO-environmental Society
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• v.11 no.8
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• pp.33-40
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• 2010

In this study, evaluation of basic unit of non-point pollutant, which is fundamental evaluation of non-point loading, was conducted using both road point and angle of intersection point in Maesong area, West coast highway by utilizing Event Mean Concentrations(EMC). Concentration of pollutants except heavy metals at these two points rapidly decreased in 30 minutes after start of runoff. According to the results of EMC, for both sampling points, it was determined that the concentrations of TSS(Total Suspended Solid), $BOD_5$(Biological Oxygen Demand), and DOC(Dissolved Organic Carbon) were higher than those of wastewater effluent standard in Korea, however, the concentrations of T-N(Total Nitrogen) and T-P(Total Phosphorus) were lower than those of the standard. In terms of heavy metals, Fe, Pb, and Zn showed higher concentrations than others. When compared with the units established by the Ministry of Environment in Korea, the basic units of $BOD_5$ and T-N in this study were lower. On the other hand, when compared with foreign units, Cu, Pb, and Zn showed approximately 10 times higher concentrations. It was estimated that a long term monitoring should be conducted for obtaining additional data and more reliable basic units for the non-point pollutnats based on the results from this study.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.11
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• pp.927-933
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• 2016

In a solid propulsion system, the rocket nozzle is exposed to high temperature combustion gas. Hence, choosing an appropriate material that could demonstrate adequate performance at high temperature is important. As advanced materials, carbon/silicon carbide composites (C/SiC) have been studied with the aim of using them for the rocket nozzle throat. However, when compared with typical structural materials, C/SiC composites are relatively weak in terms of both strength and toughness, owing to their quasi-brittle behavior and oxidation at high temperatures. Therefore, it is important to evaluate the thermal and mechanical properties of this material before using it in this application. This study presents an experimental method to investigate the fracture behavior of C/SiC composite material manufactured using liquid silicon infiltration (LSI) method at elevated temperatures. In particular, the effects of major parameters, such as temperature, loading, oxidation conditions, and fiber direction on strength and fracture characteristics were investigated. Fractography analysis of the fractured specimens was performed using an SEM.

• Asian-Australasian Journal of Animal Sciences
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• v.27 no.3
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• pp.439-446
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• 2014

Many studies on methane ($CH_4$) and nitrous oxide ($N_2O$) emissions from livestock industries have revealed that livestock production directly contributes to greenhouse gas (GHG) emissions through enteric fermentation and manure management, which causes negative impacts on animal environment sustainability. In the present study, three essential values for GHG emission were measured; i.e., i) maximum $CH_4$ producing capacity at mesophilic temperature ($37^{\circ}C$) from anaerobically stored manure in livestock category ($B_{0,KM}$, Korean livestock manure for $B_0$), ii) $EF_{3(s)}$ value representing an emission factor for direct $N_2O$ emissions from manure management system S in the country, kg $N_2O-N$ kg $N^{-1}$, at mesophilic ($37^{\circ}C$) and thermophilic ($55^{\circ}C$) temperatures, and iii) $N_{ex(T)}$ emissions showing annual N excretion for livestock category T, kg N $animal^{-1}$ $yr^{-1}$, from different livestock manure. Static incubation with and without aeration was performed to obtain the $N_2O$ and $CH_4$ emissions from each sample, respectively. Chemical compositions of pre- and post- incubated manure were analyzed. Contents of total solids (% TS) and volatile solid (% VS), and the ratio of carbon to nitrogen (C/N) decrease significantly in all the samples by C-containing biogas generation, whereas moisture content (%) and pH increased after incubation. A big difference of total nitrogen content was not observed in pre- and post-incubation during $CH_4$ and $N_2O$ emissions. $CH_4$ emissions (g $CH_4$ kg VS-1) from all the three manures (sows, layers and Korean cattle) were different and high C/N ratio resulted in high $CH_4$ emission. Similarly, $N_2O$ emission was found to be affected by % VS, pH, and temperature. The $B_{0,KM}$ values for sows, layers, and Korean cattle obtained at $37^{\circ}C$ are 0.0579, 0.0006, and 0.0828 $m^3$ $CH_4$ kg $VS^{-1}$, respectively, which are much less than the default values in IPCC guideline (GL) except the value from Korean cattle. For sows and Korean cattle, $N_{ex(T)}$ values of 7.67 and 28.19 kg N $yr^{-1}$, respectively, are 2.5 fold less than those values in IPCC GL as well. However, $N_{ex(T)}$ value of layers 0.63 kg N $yr^{-1}$ is very similar to the default value of 0.6 kg N $yr^{-1}$ in IPCC GLs for National greenhouse gas inventories for countries such as South Korea/Asia. The $EF_{3(s)}$ value obtained at $37^{\circ}C$ and $55^{\circ}C$ were found to be far less than the default value.

• Journal of Bio-Environment Control
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• v.26 no.2
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• pp.64-71
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• 2017

The study was performed on the effects of crop load of pear (Pyrus pyrifolia Nakai) trees on shoot growth, reserved nutrients, and fruit production for two years, as well as regrowth of cuttings treated with various cold temperatures in 2012 and 2013. Crop load adjustments included three levels of fruiting; 54 (60%), 90 (100%), and 126 fruits per tree (140%). As increasing crop load from 60% to 140%, water sprout growth decreased, and one-year old shoot resulted in declined concentrations of total carbon, macro-nutrients, and free sugar. The 140% of crop load greatly increased fruit yield of approximately 35 tons per ha in both 2011 and 2012 but slightly reduced weight, size, and soluble solid contents in fruit. However, 140% of crop load increased annual production income to approximately over 10 million won compared to the 60% and 100% of crop load. Germination rates in the cuttings did not rapidly decrease up to $-20^{\circ}C$ in a growth chamber condition. The 140% of crop load decreased germination rates less than 70% of cuttings grown under $-30^{\circ}C$. Amounts of electrolyte leakage in the cuttings under various cold temperatures were not significantly different among the adjustment of crop load.

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.739-744
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• 2013

In this study, torrefaction was performed to improve fuel properties of Larch. The optimal condition for torrefaction was investigated by response surface methodology. The torrefaction temperature and time ranged $220{\sim}280^{\circ}C$ and 20~80 min, respectively. As the torrefaction temperature and time increased, the carbon content of torrefied biomass increased from 49.36 to 56.65%, while its hydrogen and oxygen contents decreased from 5.56 to 5.48% and from 37.62 to 31.67%, respectively. The weight loss and calorific value increased with SF, while energy yield decreased. At the severe torrefaction condition (SF 7), the weight loss and calorific value were 26.58% and 22.30 MJ/kg, respectively. The energy contained in torrefied biomass increased to 20.41%, when compared with the untreated biomass. As the torrefaction severity increased, the energy yield decreased due to the relatively high weight loss of biomass. Therefore, the highest energy yield was obtained at high calorific value and low weight loss of biomass (SF 5.72).

• Journal of Korean Society of Environmental Engineers
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• v.30 no.12
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• pp.1273-1280
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• 2008

This study sought to establish the optimum operating condition for the recovery of caustic (NaOH) solution from mercerization in textile process. As main factors, the silt density index (SDI) evaluation of ceramic membrane for the application of nanofiltration/reverse osmosis (NF/RO) membrane, the recovery yield measurement of caustic solution for the application of polymeric membrane, the optimum condition of chemical cleaning for the membrane regeneration, the optimum removal condition of total organic carbon (TOC), turbidity, color, and the permeate flux of ceramic membrane/polymeric membrane combined process were investigated. As results, ceramic ultrafiltration (UF) in the first step and nanofiltration (NF) in the second step were found to be suitable for the removal of total suspended solid (TSS), residual organics, turbidity including color, and the recovery of caustic solution from caustic wastewater stream in mercerization process. When only the ceramic UF membrane was used, the rejection efficiency of both of TSS and turbidity was more than 99.0%, and the color and TOC were rejected about 74.7% and 49.2%, respectively. Meanwhile, the combined membrane precess of UF and NF membranes showed even more efficient removal abilities and thus more than 99.9% of TSS and turbidity, 87.7% of color, and 78.2% of TOC were removed. In particular, 91.3% of NaOH was successfully recovered with 83.7% of total volume in the combined membrane process. With this regard, a clean caustic solution was obtained in a high purity, which can be reused for mercerization process, expecting to offer economical benefits.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.55 no.4
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• pp.284-291
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• 2010

A simulation modeling for predicting the harvesting date with high potato solids consists of development of mathematical models. The mathematical model on potato growth and its development should be obtained by using agricultural elements which analyze relations of solar radiation quantity, temperature, photon quantity, carbon dioxide exchange rate, water stress and loss, relative humidity, light intensity, and wind etc. But more reliable way to predict harvesting date against climatic change employs in vivo energy consumption for growth and induction shape in a slight environmental adaptation. Therefore, to calculate in vivo energy loss, we take a concept of estimate of the amount of basal metabolism in each tuber on the basis of $Wm={\int}^m_tf(x)dt$ and $Tp=\frac{Tm{\cdot}Wm^{Tp}}{Wm^{Tm}}$. In the validation experiments, results of measuring solid accumulation of potato harvested at simulated date agreed fairly well with the actual measured values in each regional field during the growth period of 2005-2009. The calculation method could be used to predict an appropriate harvesting date for a production of high potato solids according to weather conditions.

• The Korean Journal of Pharmacology
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• v.32 no.1
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• pp.93-102
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• 1996

Platinum coordination complexes are currently one of the most compounds used in the treatment of solid tumors. However, its use is limited by severe side effects such as nephrotoxicity. Our platinum-based drug discovery program is aimed at developing drugs capable of diminishing toxicity and broadening the clinical spectrum of activity of cisplatin. We synthesized new Pt(II) complex analogue containing 1,2-diaminocyclohexane (dach) as carrier ligand and 1,3-bis(diphenyl phosphino)propane (DPPP) as a leaving group. Furthermore, nitrate was added to improve the solubility. A new series of PC-1 [Pt(cis-dach) (DPPP)]. $2NO_3_2$ was synthesized and characterized by their elemental analysis and by various spectroscopic techniques [infrared (IR), $^{13}carbon$ nuclear magnetic resonance (NMR)]. PC-1 was demonstrated acceptable antitumor activity aganist SKOV -3, OVCAR-3 human ovarian adenocarcinomacells and significant activity as compared with that of cisplatin. The toxicity of PC-1 was found quite less than that of cisplatin using MTT, $[^3H]thymidine$ uptake and glucose consumption tests in rabbit proximal tubule cells, human kidney cortical cells and human renal cortical tissues. Based on these results, this novel platinum compound represent a valuable lead in the development of a new anticancer chemotherapeutic agent capable of improving antitumor activity and low toxicity.

• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.60-67
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• 2017

In this study, we performed surface modification of biodegradable microcrystalline cellulose (MCC) to use as a filler in polyethylene (PE) composite in food packaging application. We modified MCC surface with (3-trimethoxysilylpropyl)diethylenetriamine (TPDT) silane coupling agent, which has one primary amino group and two secondary amino groups per molecule, to introduce amino groups with a carbon dioxide adsorption capability in MCC. Effects of each of the reaction conditions such as amount of TPDT introduced, swelling time, reaction temperature, and reaction time on surface modification degree of MCC were investigated by changing a variety of above reaction conditions. The amount of TPDT grafted on MCC surface and formation of chemical bonds were confirmed by Fourier transform infrared spectroscopy (FT-IR), elemental analysis (EA), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and solid state $^{29}Si$ nuclear magnetic resonance (NMR) spectroscopy. We confirmed increase of grafted amount of TPDT on MCC with increasing reaction time, reaction temperature, and amount of introduced TPDT.