• Title/Summary/Keyword: Solid carbon

Search Result 985, Processing Time 0.028 seconds

Municipal Solid Waste-derived Syngas Fermentation Process by Pressurization (가압을 통한 도시형 생활 폐기물 기반 합성가스발효 공정 개발)

  • Subin Shin;Jae Hee Go;Myounghoon Moon;Min-Sik Kim;Mungyu Lee;In Seop Chang;Seongsoo Son;Gwon Woo Park
    • New & Renewable Energy
    • /
    • v.19 no.4
    • /
    • pp.35-45
    • /
    • 2023
  • Global efforts are focused on achieving carbon neutrality due to the increases in the levels of greenhouse gases. Moreover, the greenhouse gases generated from the disposal of municipal solid waste (MSW) are the primary sources of emissions in South Korea. In this study, we conducted the biological conversion of syngas (CO, H2, and CO2) generated from MSW gasification. The MSW-derived syngas was used as a feed source for cultivating Eubacterium limosum KIST612, and pressurization was employed to enhance gas solubility in culture broth. However, the pH of the medium decreased owing to the pressurization because of the CO2 in the syngas and the cultivation-associated organic acid production. The replacement of conventional HEPES buffer with a phosphate buffer led to an approximately 2.5-fold increase in acetic acid concentration. Furthermore, compared with the control group, the pressurized reactor exhibited a maximum 8.28-fold increase in the CO consumption rate and a 3.8-fold increase in the H2 consumption rate.

Hydrothermal carbonization of sewage sludge for solid recovered fuel and energy recovery (수열탄화를 이용한 하수 슬러지의 고형연료화 및 에너지 회수 효율)

  • Kim, Daegi;Lee, Kwanyong;Park, Kiyoung
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.29 no.1
    • /
    • pp.57-63
    • /
    • 2015
  • Recently, Korea's municipal wastewater treatment plants generated amount of wastewater sludge per day. However, ocean dumping of sewage sludge has been prohibited since 2012 by the London dumping convention and protocol and thus removal or treatment of wastewater sludge from field sites is an important issue on the ground site. The hydrothermal carbonization is one of attractive thermo-chemical method to upgrade sewage sludge to produce solid fuel with benefit method from the use of no chemical catalytic. Hydrothermal carbonization improved that the upgrading fuel properties and increased materials and energy recovery, which is conducted at temperatures ranging from 200 to $350^{\circ}C$ with a reaction time of 30 min. Hydrothermal carbonization increased the heating value though the increase of the carbon and fixed carbon content of solid fuel due to dehydration and decarboxylation reaction. Therefore, after the hydrothermal carbonization, the H/C and O/C ratios decreased because of the chemical conversion. Energy retention efficiency suggest that the optimum temperature of hydrothermal carbonization to produce more energy-rich solid fuel is approximately $200^{\circ}C$.

Electrochemical Characteristics of all solid supercapacitor based on DAAQ(1,5-diaminoanthraquinone) and SPEEK(sulfonated polyether ether ketone) (DAAQ와 SPEEK를 이용한 전고상 슈퍼커패시터의 전기화학적 특성)

  • Kim, Jin-Yong;Kim, Hong-Il;Kim, Han-Joo;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.07a
    • /
    • pp.371-372
    • /
    • 2005
  • Supercapacitors are promising devices for delivering high power density. Digital communications, electric vehicles and other devices that require electrical energy at high power levels in relatively short pulses have prompted considerable research on supercapacitors. In recent years, solid electrolytes have been investigated for supercapacitors. Solid electrolytes are advantageous over liquid electrolytes in respect of easy handling and reliability without electrolyte leakage. In this preliminary study, an electrochemical supercapacitor in all solid configuration has been fabricated using CNF-DAAQ and poly-vinylidenefluoride(PVdF). A new type of Supercapacitor was constructed by using carbon nanofibers(CNFs) and DAAQ(l,5-diaminoanthraquinone) monomer. DAAQ was deposited on the carbon nanofibers by chemical polymerization with $(NH_4)_2S_2O_8$ as oxidant in the 0.1M $H_2SO_4$. Dried SPEEK powder was mixed with N-methyl pyrrolidone to make 10 wt.% solution in an ultrasonic bath, the slurry was cast over a glass substrate heated to $70^{\circ}C$ for solvent evaporation. And then we used solid electrolyte of SPEEK. The unit cell consist of DAAQ-CNF/electrolyte/Pt. From the analysis, it is clear that surface of carbon nanofibers was quite uniformly coated with DAAQ. The performance characteristics of the supercapacitors have been evaluated using Cyclic Voltammetry.

  • PDF

Experimental Study on the Effect of Sojagangki-tang (소자강기탕이 면역반응에 미치는 효과)

  • Ju Hyun Woo;Shin Woo Jin;Kam Chul Woo;Park Dong Il
    • Journal of Physiology & Pathology in Korean Medicine
    • /
    • v.17 no.4
    • /
    • pp.1002-1007
    • /
    • 2003
  • In order to investigate the effect of Sojagangki-tang on imuno-activity. the author performaed this experimental study. Delayed type hypersensitivity (DTH) and rosette forming cells (RFC) for cell-mediated immune response, hemagglutinin (HA) titers, hemolysin (HL) titers for humoral immune response, Carbon clearance for phagocytic function of MPS (mononuclear phagocyte system) were measured in ICR mice. The results were summurized as follows: Delayed tape hypersensitivity was increased with statistical significance in the administrated solid extract of Sojagangki-tang treated group as compared with the control group. Hemagglutinin titers were increased with statistical significance in the administrated solid extract of Sojagangki-tang treated group as compared with the control group. Hemolysin titers were increased with statistical significance in the administrated solid extract of Sojagangki-tang treated group as compared with the control group. Number of RFC was increased with statistical significance in the administrated solid extract of Sojagangki-tang treated group as compared with the control group. Carbon clearance was increased with statistical significance in the administrated solid extract of Sojagangki-tang treated group as compared with the control group. Through in vivo experimental study in ICR mice Sojagangki-tang enhences the cell-mediated immmune response, the humoral immune respose. According to the above results, I think that Sojagangki-tang could be used for allergy asthma and lung damage patients.

Bioconversion of flowers waste: Composting using dry leaves as bulking agent

  • Sharma, Dayanand;Yadav, Kunwar D.
    • Environmental Engineering Research
    • /
    • v.22 no.3
    • /
    • pp.237-244
    • /
    • 2017
  • At present, in India, handling of solid waste has become a major challenge for the municipal authorities. Composting of solid waste, especially organic waste, can be one of the solutions to tackle the issue of handling solid waste. The present study is focused on agitated piles composting of flower waste (FW). Five combinations of FW with dry leaves (DL) and cow dung (CD) were prepared to conduct the study. Significant changes were observed due to the addition of bulking agent. The bulking material helps to reduce the production of leachate and also to maintain the aerobic condition within the piles. The reduction of total organic carbon was 21% in FW composting which increased by 36.48% during the composting of FW on addition of DL and CD. On the 120th day of composting, the pH of pile five (70 kg FW + 20 kg CD + 15 kg DL) was 7.33, electrical conductivity 2.77 mS/cm, total organic carbon 26.9%, total nitrogen 2.2%, and C:N ratio was 12. Appropriate proportion of waste mixture played an important role in providing favorable conditions for the microbial transformation of flower waste to stabilized compost. Finally, FW with the combination of CD and DL was found to be successful during pile composting.

Molecular Weight Distribution of Liquid Phase AN and Solid Phase Polymer in Precipitation Polymerization of AN By Changing Solution Composition and Temperature

  • Liu, Weiwei;Zhang, Shuangkun;Wang, Jing;Ryu, Seung Kon;Jin, Ri-Guang
    • Carbon letters
    • /
    • v.13 no.3
    • /
    • pp.133-138
    • /
    • 2012
  • According to kinetic mechanisms, liquid phase polymerization and solid phase polymerization are different in acrylonitrile (AN) polymerization, and so the relationship between the contribution ratio and molecular weight distribution (MWD) was obtained through theoretic analysis. The precipitation homopolymerization of AN was carried out in a mixture solution of dimethyl sulfoxide (DMSO) and water at $50{\sim}65^{\circ}C$ using ${\alpha}$,${\alpha}^{\prime}$-azobisisobutyronitrile as an initiator. The contribution ratio decreased and approached 0; the MWD also decreased and approached 2 with the increase of the $H_2O$/DMSO ratio from 10/90 to 90/10. The experimental data were found to coincide well with the theoretical equation derived from the mechanisms.

Overview of Coffee Waste and Utilization for Biomass Energy Production in Vietnam

  • Thriveni, Thenepalli;Kim, Minsuk;Whan, Ahn Ji
    • Journal of Energy Engineering
    • /
    • v.26 no.1
    • /
    • pp.76-83
    • /
    • 2017
  • In this paper, the carbon resources recycling of the overview of coffee waste generation in Vietnam. Since few years, there has been a significant research studies was done in the areas of coffee waste generation areas and also waste water generation from coffee production. The coffee residue (solid) and waste water (liquid) both are caused the underground water contamination and also soil contamination. These residues contain high organic matter and acid content leads to the severe threat to environment. In second stage of coffee production process, the major solid residue was generated. Various solid residues such as spent coffee grounds, defective coffee beans and coffee husks) pose several environmental concerns and specific problems associated with each type of residue. Due to the unlimited usage of coffee, the waste generation is high. At the same time, some researchers have been investigated the spent coffee wastes are the valuable sources for various valuable compounds. Biodiesel or biomass productions from coffee waste residues are the best available utilization method for preventing the landfill problems of coffee waste residues.

Synthesis and optical properties of star-like ZnO nanostructures grown on with carbon catalyst (탄소 촉매에 의하여 성장된 별-모양 ZnO 나노 구조물의 합성과 광학적 특성)

  • Jung, Il-Hyun;Chae, Myung-Sic;Lee, Ui-Am
    • Journal of the Semiconductor & Display Technology
    • /
    • v.9 no.2
    • /
    • pp.1-6
    • /
    • 2010
  • Star-like ZnO nanostructures were grown on SI(100) substrates with carbon(C) catalyst by employing vapor-solid(VS) mechanism. The morphologies and structure of ZnO nanostructures were investigated by Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and Raman spectrum, Photoluminescence spectrum. The results demonstrated that the as-synthesized products consisted of star-like ZnO nanostructure with hexagonal wurtzite phase. Nanostructures grown at 1100 were mainly star-like in structure with diameters of 500 nm. The legs of the star-like nanostructures were preferentially grown up along the [0001] direction. A vapor.solid (VS) growth mechanism was proposed to explain the formation of the star-like structures. Photoluminescence spectrum exhibited a narrow emission band peak around 380 nm and a broad one around 491 nm. Raman spectrum of the ZnO nanostructures showed oxygen defects in ZnO nanostructures due to the existence of Ar gas during the growth process, leading to the dominant green band peak in the PL spectrum.

Buckling and vibration of porous sandwich microactuator-microsensor with three-phase carbon nanotubes/fiber/polymer piezoelectric polymeric nanocomposite face sheets

  • Arani, Ali Ghorbanpour;Navi, Borhan Rousta;Mohammadimehr, Mehdi
    • Steel and Composite Structures
    • /
    • v.41 no.6
    • /
    • pp.805-820
    • /
    • 2021
  • In this research, the buckling and free vibration of three-phase carbon nanotubes/ fiber/ polymer piezoelectric nanocomposite face sheet sandwich microbeam with microsensor and micro-actuator surrounded in elastic foundation based on modified couple stress theory (MCST) is investigated. Three types of porous materials are considered for sandwich core. Higher order (Reddy) and sinusoidal shear deformation beam theories are employed for the displacement fields. Sinusoidal surface stress effects are extracted for sinusoidal shear deformation beam theory. The equations of motion are derived by Hamilton's principle and then the natural frequency and critical buckling load are obtained by Navier's type solution. The determined results are in good agreement with other literatures. The detailed numerical investigation for various parameters is performed for this microsensor-microactuator. The results reveal that the microsensor-microactuator enhanced by increasing of Skempton coefficient, carbon nanotubes diameter length to thickness ratio, small scale factor, elastic foundation, surface stress constants and reduction in porous coefficient, micro-actuator voltage and CNT weight fraction. The valuable results can be expedient for micro-electro-mechanical (MEMS) and nano-electro-mechanical (NEMS) systems.

Nonlinear stability of non-axisymmetric functionally graded reinforced nano composite microplates

  • Loghman, Abbas;Arani, Ali Ghorbanpour;Barzoki, Ali Akbar Mosallaie
    • Computers and Concrete
    • /
    • v.19 no.6
    • /
    • pp.677-687
    • /
    • 2017
  • The nonlinear buckling response of nano composite anti-symmetric functionally graded polymeric microplate reinforced by single-walled carbon nanotubes (SWCNTs) rested on orthotropic elastomeric foundation with temperature dependent properties is investigated. For the carbon-nanotube reinforced composite (CNTRC) microplate, a uniform distribution (UD) and four types of functionally graded (FG) distribution are considered. Based on orthotropic Mindlin plate theory, von Karman geometric nonlinearity and Hamilton's principle, the governing equations are derived. Generalized differential quadrature method (GDQM) is employed to calculate the non-linear buckling response of the plate. Effects of FG distribution type, elastomeric foundation, aspect ratio (thickness to width ratio), boundary condition, orientation of foundation orthotropy and temperature are considered. The results are validated. It is found that the critical buckling load without elastic medium is significantly lower than considering Winkler and Pasternak medium.