• Smart Structures and Systems
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• v.22 no.1
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• pp.105-120
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• 2018

In this paper, the nonlinear free and forced vibration responses of sandwich nano-beams with three various functionally graded (FG) patterns of reinforced carbon nanotubes (CNTs) face-sheets are investigated. The sandwich nano-beam is resting on nonlinear Visco-elastic foundation and is subjected to thermal and electrical loads. The nonlinear governing equations of motion are derived for an Euler-Bernoulli beam based on Hamilton principle and von Karman nonlinear relation. To analyze nonlinear vibration, Galerkin's decomposition technique is employed to convert the governing partial differential equation (PDE) to a nonlinear ordinary differential equation (ODE). Furthermore, the Multiple Times Scale (MTS) method is employed to find approximate solution for the nonlinear time, frequency and forced responses of the sandwich nano-beam. Comparison between results of this paper and previous published paper shows that our numerical results are in good agreement with literature. In addition, the nonlinear frequency, force response and nonlinear damping time response is carefully studied. The influences of important parameters such as nonlocal parameter, volume fraction of the CNTs, different patterns of CNTs, length scale parameter, Visco-Pasternak foundation parameter, applied voltage, longitudinal magnetic field and temperature change are investigated on the various responses. One can conclude that frequency of FG-AV pattern is greater than other used patterns.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.22-25
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• 2005

The thermal degradation of carbon/phenolic composite have been studied at high temperature by using thermogravimetric (TGA). A heating .ate of 5, 10, 15, 30 and $50^{\circ}C/min$ was used for the determination of thermal decomposition parameters of composite materials at high-temperature service. It has been shown that as the heating rates is increased, the peak decomposition rates are occur at higher temperature. Based on results of thermogravimetric analysis, the pyrolysis process is analyzed and physical and mathematical models for the process are proposed. The thermal analysis also has been conducted using transient heat conduction and the in-depth temperature distribution and the density profile were evaluated along the solid rocket nozzle. As a future effort the thermal decomposition parameter determined in this investigation will be used as input to thermal and mechanical analysis when subjected to solid rocket propulsion environment.

• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3381-3386
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• 2013

This paper reports a method using molecularly imprinted polymers that are grafted onto the surface of carboxyl-modified multi-walled carbon nanotubes as the solid-phase extraction adsorbents to detect Rhodamine B in chili powder samples. The polymers were characterized by FTIR and TGA. Various parameters which probably influence efficiency of extraction were optimized. The analytical parameters such as precision, accuracy and linear working range were also determined in optimal experimental conditions. And the proposed method was applied to analysis of Rhodamine B in chili powder samples. The limits of detection and quantification were 2.57 and 8.56 ${\mu}g/g$, respectively. The recoveries for analytes were higher than 95% and relative standard deviation values were found to be in the range of 0.83-4.15%. This method was successfully applied for the determination of Rhodamine B.

• Steel and Composite Structures
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• v.27 no.4
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• pp.525-536
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• 2018

This paper focuses on the application of the first-order shear deformation theory (FSDT) to thermo-elastic static problems of functionally graded carbon nanotubes reinforced composite (FG-CNTRC) cylindrical pressure vessels. A symmetric displacement field is considered as unknown function along the longitudinal direction, whereas a linear distribution is assumed along the thickness direction. The cylindrical pressure vessels are subjected to an inner and outer pressure under a temperature increase. Different patterns of reinforcement are applied as distribution of CNTs. The effective material properties of FG-CNTRC cylindrical pressure vessels are measured based on the rule of mixture, whereas the governing equations of the problem are here derived through the principle of virtual works. A large parametric investigation studies the effect of some significant parameters, such as the pattern and volume fraction of CNTs, on the longitudinal distribution of deformation, strain and stress components, as useful tool for practical engineering applications.

• Journal of the Korean Ceramic Society
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• v.53 no.5
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• pp.483-488
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• 2016

Anode supported solid oxide fuel cells (SOFCs), consisting of Ni+YSZ anode, YSZ electrolyte, and LSM+YSZ cathode, were fabricated and constant current tested with direct internal reforming of methane (steam to carbon ratio ~ 2) as well as hydrogen fuel at $800^{\circ}C$. The cell, operated under direct internal reforming conditions, showed relatively rapid degradation (~ 1.6 % voltage drop) for 95 h; the cells with hydrogen fuel operated stably for 170 h. Power density and impedance spectra were also measured before and after the tests, and post-test analyses were conducted on the anode parts using SEM / EDS. The results indicate that the performance degradation of the cell operated with internal reforming can be attributed to carbon depositions on the anode, which increase the resistance against anode gas transport and deactivate the Ni catalyst. Thus, the present study shows that direct internal reforming SOFCs cannot be stably operated even under the condition of S/C ratio of ~ 2, probably due to non-uniform mixture (methane and steam) gas flow.

• Bulletin of the Korean Chemical Society
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• v.15 no.8
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• pp.616-622
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• 1994

The oxidation of carbon monoxide by gaseous oxygen in the presence of a powdered $Nd_{1-x}Sr_xCoO_{3-y}$ solid solution as a catalyst has been investigated in the temperature range from 150$^{\circ}$C to 300$^{\circ}$C under various CO and $O_2$ partial pressures. The site of Sr substitution, nonstoichiometry, structure, and microstructure were studied by means of powder X-ray diffraction and infrared spectroscopy. The electrical conductivity of the solid solution has been measured at 300$^{\circ}$C under various CO and $O_2$ partial pressures. The oxidation rates have been correlated with 1.5-and 1.2-order kinetics with and without a $CO_2$ trap, respectively; first-and 0.7 order with respect to CO and 0.5-order to $O_2$. For the above reaction temperature range, the activation energy is in the range from 0.25 to 0.35 eV/mol. From the infrared spectroscopic, conductivity and kinetic data, CO appears essentially to be adsorbed on the lattice oxygens of the catalyst, while $O_2$ adsorbs as ions on the oxygen vacancies formed by Sr substitution. The oxygen vacancy mechanism of the CO oxidation and the main defect of $Nd_{1-x}Sr_xCoO_{3-y}$ solid solution are supported and suggested from the agreement between IR data, conductivities, and kinetic data.

• Computers and Concrete
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• v.24 no.3
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• pp.185-192
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• 2019

In this paper, the buckling of micro sandwich hollow circular plate is investigated with the consideration of the porous core and piezoelectric layer reinforced by functionally graded (FG)carbon nano-tube. For modeling the displacement field of sandwich hollow circular plate, the high-order shear deformation theory (HSDT) of plate and modified couple stress theory (MCST) are used. The governing differential equations of the system can be derived using the principle of minimum potential energy and Maxwell's equation that for solving these equations, the Ritz method is employed. The results of this research indicate the influence of various parameters such as porous coefficients, small length scale parameter, distribution of carbon nano-tube in piezoelectric layers and temperature on critical buckling load. The purpose of this research is to show the effect of physical parameters on the critical buckling load of micro sandwich plate and then optimize these parameters to design structures with the best efficiency. The results of this research can be used for optimization of micro-structures and manufacturing different structure in aircraft and aerospace.

• Structural Engineering and Mechanics
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• v.70 no.3
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• pp.351-365
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• 2019

In this paper, free vibration of Cooper-Naghdi micro sandwich cylindrical shell with saturated porous core and reinforced carbon nanotube (CNT) piezoelectric composite face sheets is investigated by using first order shear deformation theory (FSDT) and modified couple stress theory (MCST). The sandwich shell is subjected to magneto-thermo-mechanical loadings with temperature dependent material properties. Energy method and Hamilton's principle are used for deriving of the motion equations. The equations are solved by Navier's method. The results are compared with the obtained results by the other literatures. The effects of various parameters such as saturated porous distribution, geometry parameters, volume fraction and temperature change on the natural frequency of the micro-sandwich cylindrical shell are addressed. The obtained results reveal that the natural frequency of the micro sandwich cylindrical shell increases with increasing of the radius to thickness ratio, Skempton coefficient, the porosity of the core, and decreasing of the length to radius ratio and temperature change.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3835-3839
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• 2013

A new synthesis route for Pt nanoparticles by direct electrochemical reduction of a solid-state Pt ion precursor ($K_2PtCl_6$) is demonstrated. Solid $K_2PtCl_6$-supported polyethyleneimine (PEI) coatings on the surface of glassy carbon electrode were prepared by simple mixing of solid $K_2PtCl_6$ into a 1.0% PEI solution. The potential cycling or a constant potential in a PBS (pH 7.4) medium were applied to reduce the solid $K_2PtCl_6$ precursor. The reduction of Pt(IV) began at around -0.2 V and the reduction potential was ca. -0.4 V. A steady state current was achieved after 10 potential cycling scans, indicating that continuous formation of Pt nanoparticles by electrochemical reduction occurred for up to 10 cycles. After applying the reduction potential of -0.6 V for 300 s, Pt nanoparticles with diameters ranging from $0.02-0.5{\mu}m$ were observed, with an even distribution over the entire glassy carbon electrode surface. Characteristics of the Pt nanoparticles, including their performance in electrochemical reduction of $H_2O_2$ are examined. A distinct reduction peak observed at about -0.20 V was due to the electrocatalytic reduction of $H_2O_2$ by Pt nanoparticles. From the calibration plot, the linear range for $H_2O_2$ detection was 0.1-2.0 mM and the detection limit for $H_2O_2$ was found to be 0.05 mM.

• KSBB Journal
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• v.7 no.4
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• pp.318-324
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• 1992

The adsorption characteristics of bovine serum albumin(BSA) on the modified carbon fiber and cellulose surfaces were investigated. In order to define the effects of solid surface characteristics on protein adsorption, surfaces of carbon fiber and cellulose were modified by physical and chemical treatment. The amounts of BSA adsorbed onto various solid surfaces were evaluated by batch method under various pH and ionic strength. The amount of adsorbed BSA was highly dependent on pH as well as surface functional groups.