• Title/Summary/Keyword: Solid Surface

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A Review of Surface Energy of Solid Electrodes with Emphasis on Its Controversial Issues in Interfacial Electrochemistry

  • Go Joo-Young;Pyun Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.211-219
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    • 2004
  • A classical Lippmann equation valid for liquid electrodes can not describe the interfacial properties of solid electrodes due to the elastic surface strain on solid electrodes. Although there have been many attempts to derive the thermodynamic equations for solid electrodes Outing the past few decades, their validity has been still questioned by many researchers. In practice, although there are various experimental techniques to measure surface energy of solid electrodes, the results obtained by each technique are rather inconsistent due to the complexity of the surface strain on solid electrodes. This article covers these controversial issues in surface energy of solid electrodes. After giving brief summaries of the definition of the important thermodynamic parameters and the derivation of the thermodynamic equations for solid electrodes, the several experimental methods were introduced for the measurement of surface energy of solid electrodes. And then we discussed in detail the inconsistent results in the measurement of the potential of zero charge (pac) and the potential of electrocapillary maximum (ecm).

Evaluation of Friction and Wear Characteristics of Carbon-based Solid Lubricant Films for Surface Application of Compressor Parts (압축기 부품소재 표면 적용을 위한 탄소 기반 고체 윤활막의 마찰 및 마모 특성 평가)

  • Lee, Sung-Jun;Kim, Chang-Lae
    • Tribology and Lubricants
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    • v.38 no.5
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    • pp.222-226
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    • 2022
  • Between diaphragms made of stainless steel (SUS), which is the main component of a hydrogen gas compressor, micro-slip occurs owing to repeated bending, resulting in scratches on the surface. The surface scratch of the compressor part is a problem with airtightness, which reduces the efficiency of the compressor; in severe cases, damage is a possibility. In this study, the changes in friction and wear characteristics due to the surface polishing of SUS and carbon-based solid lubricant films (graphene and CNT) were analyzed. Bare SUS, polished SUS, graphene film, and CNT film specimens were prepared. The surface roughness of the SUS was significantly reduced by surface polishing but increased by carbon-based solid lubricating films. In contrast, the friction coefficient maintained a similar value after surface polishing but was significantly reduced by the carbon-based solid lubricant films. In particular, the graphene film exhibited the lowest initial friction coefficient, while the CNT film exhibited the lowest overall average friction coefficient. Regarding the wear rate, polished SUS exhibited the lowest value, but the surface condition of the wear track showed that the carbon-based solid lubricating films were relatively less damaged. Although the wear rate measured was largely attributed to the solid lubricating film peeling off, the SUS surface under the film was considered protected.

CAE Solid Element Mesh Generation from 3D Laser Scanned Surface Point Coordinates

  • Jarng S.S.;Yang H.J.;Lee J.H.
    • Korean Journal of Computational Design and Engineering
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    • v.10 no.3
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    • pp.162-167
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    • 2005
  • A 3D solid element mesh generation algorithm was newly developed. 3D surface points of global rectangular coordinates were supplied by a 3D laser scanner. The algorithm is strait forward and simple but it generates hexahedral solid elements. Then, the surface rectangular elements were generated from the solid elements. The key of the algorithm is elimination of unnecessary elements and 3D boundary surface fitting using given 3D surface point data.

Surface Discharge Characteristics Study on the Laminated Solid Insulator in Quasi-Uniform Electric Field with Dry Air

  • Min, Gyeong-Jun;Bae, Sungwoo;Kang, Byoung-Chil;Park, Won-Zoo
    • Journal of Electrical Engineering and Technology
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    • v.10 no.2
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    • pp.603-609
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    • 2015
  • Dry air is an excellent alternative to $SF_6$ gas and is used as an insulation gas in Eco-friendly Gas Insulated Switchgears (EGISs), which has gained popularity in industry. Solid insulators in EGIS play an important role in electrical insulation. On the other hand, surface discharge can occur easily when solid insulators are used. This paper explored the surface discharge characteristics on the structure of three-layered laminated solid insulators to elevate the flashover voltage. A laminated solid insulator was inserted after the quasi-uniform electric field was formed in the test chamber. Dry air was then injected to set the internal pressure to 1 ~ 6 atm, and the AC voltage was applied. When identical solid insulators were stacked, the surface discharge characteristics were similar to those of a single solid insulator. On the other hand, the flashover voltage rose when the middle part was thicker and had lower permittivity than the top and bottom parts in the laminated solid insulator. Based on experimental results, when stacking a solid insulator in three layers, the middle part of the solid insulator should be at least four times as thick as the top and bottom parts and have lower permittivity than the others. In addition, the flashover voltage increased with increasing gas pressure on the surface of the laminated solid insulator due to the gas effect. This study may allow insulation design engineers to have useful information when using dry air for the insulation gas where the surface discharge can occur.

Water droplet behavior on a solid-infused surface cured with commercial Gentoo polymer (상용 Gentoo 폴리머가 경화된 고체주입표면에서 물방울 거동)

  • Hyeongwon Kim;Jeong-Hyun Kim
    • Journal of the Korean Society of Visualization
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    • v.22 no.1
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    • pp.61-67
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    • 2024
  • In this study, the behavior of water droplets on a solid-infused surface was evaluated by quantifying a water droplet's contact angle, sliding angle, and terminal velocity. The contact angle hysteresis and sliding angle of water on the solid-infused surface were measured to be lower than those of the hydrophobic PTFE surface. It led to the enhancement of the initiation of the water droplet's movement. When the capillary number was lower than Ca < 0.004, the terminal velocity of the water droplet on the solid-infused surface was higher than the PTFE surface due to the low contact line resistance. However, the transition of the droplet morphology from a hemispherical shape to a streamlined teardrop shape beyond Ca > 0.004 lost the effect of reducing frictional resistance on the solid-infused surface.

Surface Polarity Dependent Solid-state Molecular Biological Manipulation with Immobilized DNA on a Gold Surface

  • Lee, Jiyoung;Kim, Jeong Hee
    • International Journal of Oral Biology
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    • v.37 no.4
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    • pp.181-188
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    • 2012
  • As the demand for large-scale analysis of gene expression using DNA arrays increases, the importance of the surface characterization of DNA arrays has emerged. We compared the efficiency of molecular biological applications on solid-phases with different surface polarities to identify the most optimal conditions. We employed thiol-gold reactions for DNA immobilization on solid surfaces. The surface polarity was controlled by creating a self-assembled monolayer (SAM) of mercaptohexanol or hepthanethiol, which create hydrophilic or hydrophobic surface properties, respectively. A hydrophilic environment was found to be much more favorable to solid-phase molecular biological manipulations. A SAM of mercaptoethanol had the highest affinity to DNA molecules in our experimetns and it showed greater efficiency in terms of DNA hybridization and polymerization. The optimal DNA concentration for immobilization was found to be 0.5 ${\mu}M$. The optimal reaction time for both thiolated DNA and matrix molecules was 10 min and for the polymerase reaction time was 150 min. Under these optimized conditions, molecular biology techniques including DNA hybridization, ligation, polymerization, PCR and multiplex PCR were shown to be feasible in solid-state conditions. We demonstrated from our present analysis the importance of surface polarity in solid-phase molecular biological applications. A hydrophilic SAM generated a far more favorable environment than hydrophobic SAM for solid-state molecular techniques. Our findings suggest that the conditions and methods identified here could be used for DNA-DNA hybridization applications such as DNA chips and for the further development of solid-phase genetic engineering applications that involve DNA-enzyme interactions.

Development and Decay of Columnar Vortex in Two Phases Interface; Gas/Liquid, Solid/Liquid (기/액, 고/액 2상 경계면에서의 수직와류의 성장과 소멸)

  • Kim, K.H.;Yang, S.Y.;Park, M.H.
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.241-246
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    • 2001
  • Vortices terminating at free surface have been investigated extensively. Most of investigations, however, are focused on surface parallel vortices and little has been known about surface normal vortex or columnar vortex. Visualized experimental results utilizing LIF technique are discussed for the purpose of characterization of columnar vortex interacting with a clean and a contaminated free surfaces and a solid body interface in the present investigation. The results reveal that surface tension changes due to surface contamination although bulk viscosity remains constant and eventually the behavior of a columnar vortex interacting with a contaminated free surface and a solid body interface are totally different from the clean free surface case.

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A Study on Induction Heating with Compulsive Surface Cooling in Semi-Solid Forming Process (반용융 성형에서 간제 표면 냉각에 의한 유도 가열 방법에 관한 연구)

  • Choi, J. C.;Kim, B. M.;Choi, Y.;Park, J. H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.465-468
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    • 2000
  • The procedure of semi-solid forming is composed of heating a billet, forming, compression holding and ejecting step. There are several methods to heat a billet during semi-solid forming process such as electric heating and induction heating. Usually in semi-solid forming process, induction heating has been adopted to achieve more uniform temperature of semi-solid material. Although induction heating is better method than any others, however, there is still difference of temperature between internal part and surface part of semi-solid material. Worse yet, in case of high liquid fraction of semi-solid material, liquid of the billet will flow down though solid of the billet still remains, which is very difficult to handle. In the present study, induction heating of semi-solid material with compulsive surface cooling has been performed to obtain uniform distribution of temperature. Distribution of temperature of the billets was measured and compared with that of conventional distribution of temperature. By this new induction heating method, not only temperature over the whole billet become uniform, but also control of temperature is possible.

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Tool Interference Avoidance in compound Surface Using solid Modeling Method (Solid Modeling 기법을 응용한 복합곡면 가공에 있어서 공구간섭 제거)

  • 장동규
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.5 no.2
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    • pp.20-28
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    • 1996
  • Compound surface modeling is widely used for die cavities and punches. A compound surface is defined in 3-D space by specifying the topological relationship of several anlytic surface elements and a sculptured surface. A constructive solid gemonetry scheme is employed to model the analytic compound surface. the desired compound surface can be accomplished by specifying topological reationship in terms of boolean relations between pimitives and the sculptured surfaces. Additionally, a method is presented for checking and avoiding the tool interference occuued in machining the compound surface. Using this method. the interference of concave, convex, and side region can be checked easily and avoided rpapidly.

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