• Title/Summary/Keyword: Solid Shapes

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Preparation of SrTiO3: Pr3+ Phosphors Using Supercritical Fluid Method and its Luminescence Properties (초임계 유체법에 의한 SrTiO3: Pr3+ 형광체 분말 제조 및 발광특성)

  • Choi, Keun-Mook;Hong, Seok-Hyoung;Lim, Dae-Young;Nho, Jun-Seok;Cho, Seung-Beom
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1023-1027
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    • 2002
  • In this paper, we have prepared phase-pure $SrTiO_3:\;Pr^{3+}$ phosphor powder by Supercritical Fluid Mixing using $Sr(OH)_2{\cdot}8H_2O$ and $TiO_2$ powders as starting materials. Its luminescent properties were investigated in comparison with $SrTiO_3:\;Pr^{3+}$ powders prepared by solid-state method with conventional mixing. $SrTiO_3:\;Pr^{3+}$ phosphor powders by Supercritical Fluid Mixing have spherical shapes and narrow particle size distribution. We have investigated the luminescent properties of $SrTiO_3:\;Pr^{3+}$ phosphor using $Al^{3+}$ and $Ga^{3+}$ as sensitizer.

Preparation of corundum $(\alpha-AL_2O_3)$ by hydrothermal growing process: II. A study on the effects of a mineralizer and substances on preparation of corundum (수열성장법에 의한 코런덤$(\alpha-AL_2O_3)$제조 : II. 광화제와 성장기질이 코런덤 합성에 미치는 영향에 관한 연구)

  • 이기정;서경원
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.47-58
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    • 1997
  • In this study single crystalline corundum ($\alpha$-$Al_2O_3$) powders were prepared from gibbsite using hydrothermal growing processes. Addition of a mineralizer and the characteristics of solid substances were investigated to find their effects on the size distribution and crystalllnity of products. Experimental results showed that as the concentration of potassium hydroxide (KOH), a mineralizer, the particle size of corundum powders became larger at lower reaction temperatures. However, the size of corundum powders became smaller as the concentration of gibbsite increased in the feedstock. The hydrothermal synthetic conditions are also strongly dependent on the properties of hydrothermal solutions. Corundum powders which have the weight mean particle size of 1~10 $\mu\textrm{m}$ with shapes of hexagonal were prepared in this experiment.

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Design of Turbulent In-situ Mixing Mixer and Fabrication of Cu-TiB2 Nanocomposities (난류 용탕 In-situ 합성 믹서의 설계 및 Cu-TiB2 나노 복합재료의 제조)

  • Choi, Baek-Boo;Park, Jung-Su;Yun, Ji-Hun;Ha, Man-Young;Park, Yong-Ho;Park, Ik-Min
    • Korean Journal of Materials Research
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    • v.17 no.1
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    • pp.11-17
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    • 2007
  • Turbulent in-situ mixing process is a new material process technology to get dispersed phase in nanometer size by controlling reaction of liquid/solid, liquid/gas, flow ana solidification speed simultaneously. In this study, mixing which is the key technology to this synthesis method was studied by computational fluid dynamics. For the simulation of mixing of liquid metal, static mixers investigated. Two inlets for different liquid metal meet ana merge like 'Y' shape tube having various shapes and radios of curve. The performance of mixer was evaluated with quantitative analysis with coefficient of variance of mass fraction. Also, detailed plots of intersection were presented to understand effect of mixer shape on mixing. The simulations show that the Reynolds number (Re) is the important factor to mixing and dispersion of $TiB_2$ particles. Mixer was designed according to the simulation, and $Cu-TiB_2$ nano composites were evaluated. $TiB_2$ nano particles were uniformly dispersed when Re was 1000, and cluster formation and reduction in volume fraction of $TiB_2$ were found at higher Re.

Point Defects and Photoluminescence of Green Phosphors Ca(1-1.5x)WO4:Tbx3+ and Ca(1-2x)WO4:Tbx3+, Nax+

  • Cho, Seon-Woog
    • Korean Journal of Materials Research
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    • v.23 no.9
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    • pp.537-542
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    • 2013
  • Two types of Tb- and Na-substituted green phosphors $Ca_{(1-1.5x)}WO_4:Tb_x^{3+}$: and $Ca_{(1-2x)}WO_4:Tb_x^{3+},Na_x^+$ were synthesized with various x values, using a solid-state reaction. The former phosphors contained both substitutional and vacancy point defects, while the later had only substitutional defects. X-ray diffraction results showed that the main diffraction peak, (112), was centered at $2{\theta}=28.72^{\circ}$ and indicated that there was no basic structural deformation caused by substitutions or vacancies. The photoluminescence emission and photoluminescence excitation spectra revealed the optical properties of trivalent terbium ions, $Tb^{3+}$. Typical transitions, $^5D_3{\rightarrow}^7F_6,\;^7F_5,\;^7F_4$ and $^5D_4{\rightarrow}^7F_6,\;^7F_5,\;^7F_4,\;^7F_3$, and cross relaxations were observed. Subtle differences in the photoluminescence of green phosphors were observed as a result of the point defects. The FT-IR spectra indicated that some of the ungerade vibrational modes had shifted positions and changed shapes, spreading out over a wide range of frequencies. This change can be attributed to the different masses of $Tb^{3+}$ and $Na^+$ ions and $V_{Ca}$" vacancies compared to $Ca^{2+}$ ions. The gerade normal modes of the Raman spectra exhibited subtle differences resulting from point defects in $Ca_{(1-1.5x)}Tb_xWO_4$ and $Ca_{(1-2x)}Tb_xNa_xWO_4$.

A study on the compressive capacity of structural skin timber for the furniture manufacturing and heavy timber construction (가구 및 중목구조용 실대재 스킨팀버의 압축 성능에 관한 연구)

  • Kim, Gwang-Chul
    • Journal of the Korea Furniture Society
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    • v.21 no.4
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    • pp.273-283
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    • 2010
  • Structural larger timber have some weak points as like much longer drying time at lower MC(15%), a considerable check developing and the difficulty for the chemicals injection, so it is necessary to develop lighter structural size member for using the new Hanok, heavy timber construction, living necessaries, furniture and industrial goods. The developed skin timber can be a good raw material for those uses. Skin timber is a hollowed timber which be bored out of its considerable cross-sectional area. The intention of this study was the evaluation of compressive capacity of skin timber. Specially, skin timbers which have more than 200mm in sizes were used to analyze the compressive capacity. From the results of this study, the following conclusions have been made: 1. Though considerable inner parts were bored out, both pine skin timber and larch skin timber showed a good compressive capacity to that of non-bored solid timber. 2. According to ASTM, pine skin timber showed various failure types, but Splitting type, Brooming and end rolling type were main failure types for the larch skin timber. 3. Pine skin timber didn't show the significance between cylindrical shape and rectangular shape, but larch skin timber showed the significance between two shapes. Therefore, for the larch skin timber, cylindrical shape and rectangular shape should be used as a column uses and beam uses respectively. 4. Pine skin timber and larch skin timber didn't show the significance on the compressive capacity. There is not much difference of compressive capacity between them, so it can be possible to select on the user convenience.

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An Experimental Study on the Heat Transfer Characteristics to Enhance the Artificial Hydrate Formation Performance (전열특성을 이용한 가스하이드레이트 인공제조 성능향상에 대한 실험적 연구)

  • Shin, Chang-Hoon;Park, Seoung-Su;Kwon, Ok-Bae;Shin, Kwang-Sik;Choi, Yang-Mi;Lee, Jeong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.515-518
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    • 2007
  • Gas hydrates are ice-like crystalline compounds that form under low temperature and elevated pressure conditions. Recently, gas hydrates present a novel means for natural gas storage and transportation with potential applications in a wide variety of areas. An important property of hydrates that makes them attractive for use in gas storage and transportation is their very high gas-to-sol id ratio. In addition to the high gas content, gas hydrates are remarkably stable. The main barrier to development of gas hydrate technology is the lack of an effective mass production method of gas hydrate in solid form. In this study, some performance comparison among several cases classified by different volume sizes of solution were carried to identify the characteristics due to the volume increment. And it is found that one of the main reasons disturbing hydrate formation is related to the lack of cooling heat transfer due to the volume increase of the solution. So, three kinds of heat transfer plates which have different shapes and cross sectional areas were made and tested for the performance comparison following to the shape and area of each plate. Finally it is clarified that the heat transfer is one of the major factors effecting hydrate formation performance and the installation of heat transfer plate can enhance the formation performance especially not in terms of the quantity but the speed.

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Effect of soil pile structure interaction on dynamic characteristics of jacket type offshore platforms

  • Asgarian, Behrouz;Shokrgozar, Hamed Rahman;Shahcheraghi, Davoud;Ghasemzadeh, Hasan
    • Coupled systems mechanics
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    • v.1 no.4
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    • pp.381-395
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    • 2012
  • Dynamic response of Pile Supported Structures is highly depended on Soil Pile Structure Interaction. In this paper, by comparison of experimental and numerical dynamic responses of a prototype jacket offshore platform for both hinge based and pile supported boundary conditions, effect of soil-pile-structure interaction on dynamic characteristics of this platform is studied. Jacket and deck of a prototype platform is installed on a hinge-based case first and then platform is installed on eight skirt piles embedded on continuum monolayer sand. Dynamic characteristics of platform in term of natural frequencies, mode shapes and modal damping are compared for both cases. Effects of adding and removing vertical bracing members in top bay of jacket on dynamic characteristics of platform for both boundary conditions are also studied. Numerical simulation of responses for the studied platform is also performed for both mentioned cases using capability of ABAQUS and SACS software. The 3D model using ABAQUS software is created using solid elements for soil and beam elements for jacket, deck and pile members. Mohr-Coulomb failure criterion and pile-soil interface element are used for considering nonlinear pile soil structure interaction. Simplified modeling of soil-pile-structure interaction effect is also studied using SACS software. It is observed that dynamic characteristics of the system changes significantly due to soil-pile-structure interaction. Meanwhile, both of complex and simplified (ABAQUS and SACS, respectively) models can predict this effect accurately for such platforms subjected to dynamic loading in small range of deformation.

Feature-Based Non-manifold Geometric Modeling System to Provide Integrated Environment for Design and Analysis of Injection Molding Products (사출 성형 제품의 설계 및 해석의 통합 환경을 제공하기 위한 특징 형상 기반 비다양체 모델링 시스템의 개발)

  • 이상헌;이건우
    • Korean Journal of Computational Design and Engineering
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    • v.1 no.2
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    • pp.133-149
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    • 1996
  • In order to reduce the trial-and-errors in design and production of injection molded plastic parts, there has been much research effort not only on CAE systems which simulate the injection molding process, but also on CAD systems which support initial design and re-design of plastic parts and their molds. The CAD systems and CAE systems have been developed independently with being built on different basis. That is, CAD systems manipulate the part shapes and the design features in a complete solid model, while CAE systems work on shell meshes generated on the abstract sheet model or medial surface of the part. Therefore, it is required to support the two types of geometric models and feature information in one environment to integrate CAD and CAE systems for accelerating the design speed. A feature-based non-manifold geometric modeling system has been developed to provide an integrated environment for design and analysis of injection molding products. In this system, the geometric models for CAD and CAE systems are represented by a non-manifold boundary representation and they are merged into a single geometric model. The suitable form of geometric model for any application can be extracted from this model. In addition, the feature deletion and interaction problem of the feature-based design system has been solved clearly by introducing the non-manifold Boolean operation based on 'merge and selection' algorithm. The sheet modeling capabilities were also developed for easy modeling of thin plastic parts.

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Fuel Cell End Plates: A review

  • Kim, Ji-Seok;Park, Jeong-Bin;Kim, Yun-Mi;Ahn, Sung-Hoon;Sun, Hee-Young;Kim, Kyung-Hoon;Song, Tae-Won
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.1
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    • pp.39-46
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    • 2008
  • The end plates of fuel cell assemblies are used to fasten the inner stacks, reduce the contact pressure, and provide a seal between Membrane-Electrode Assemblies (MEAs). They therefore require sufficient mechanical strength to withstand the tightening pressure, light weight to obtain high energy densities, and stable chemical/electrochemical properties, as well as provide electrical insulation. The design criteria for end plates can be divided into three parts: the material, connecting method, and shape. In the past, end plates were made from metals such as aluminum, titanium, and stainless steel alloys, but due to corrosion problems, thermal losses, and their excessive weight, alternative materials such as plastics have been considered. Composite materials consisting of combinations of two or more materials have also been proposed for end plates to enhance their mechanical strength. Tie-rods have been traditionally used to connect end plates, but since the number of connecting parts has increased, resulting in assembly difficulties, new types of connectors have been contemplated. Ideas such as adding reinforcement or flat plates, or using bands or boxes to replace tie-rods have been proposed. Typical end plates are rectangular or cylindrical solid plates. To minimize the weight and provide a uniform pressure distribution, new concepts such as ribbed-, bomb-, or bow-shaped plates have been considered. Even though end plates were not an issue in fuel cell system designs in the past, they now provide a great challenge for designers. Changes in the materials, connecting methods, and shapes of an end plate allow us to achieve lighter, stronger end plates, resulting in more efficient fuel cell systems.

Optimum Design of Rail in Semiconductor Processing (반도체 공정에 이용되는 레일의 최적설계)

  • 조재승;김학선;황종균;임오강
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.17 no.3
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    • pp.241-249
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    • 2004
  • There is an over head hoist transporter(OHT) by the system for delivering the wafer in semiconductor processing. The transfer system consist of carrier, vehicle, rail and support. The Tail supporting the wafer and the transfer system should maintain enough strength and stiffness. To achieve lightness and enough strength and stiffness, optimization algorithm should be introduced in design process. In this study, two kinds of section shapes as L-type, C-type is carried out the structure analysis and optimization. Total weight of rail is to be minimized while displacement should not exceed limit. To improve the initial model, topology optimization is done by the plain problem. Size optimization is done with 3D solid element and PLBA algorithm, the RQP algorithm. The weight of optimum model as L-type, C-type is decreased by 2.3%, 10% respectively. It is improved better than the initial model in the strength and stiffness of the structure.