• Journal of the Korean Applied Science and Technology
• /
• v.28 no.3
• /
• pp.306-312
• /
• 2011

In this study, we are crystallized to the low density polyethylene (LDPE) micro-particles in $n$-dodecanol solution by thermally induced phase separation(TIPS) method. The Low density polyethylene micro-particles is used in a wide variety of polymer coatings and industrial application. The utility of that for a particular application depends on a number of factors such as the particle size and distribution, and chemical composition of the materials. However, there are still needs for new methods of preparation which will provide the structure with unique sizes. The widely used processes for micro-size particles are crystallization method and thermally induced phase separation. TIPS process based on the phase separation mechanism was performed for the LDPE system which undergoes liquid-solid phase separation. Effects of various operating parameters were examined on the structure variation of the particles. Professionality, take-up speed and crystallization rate depended on temperature and concentration of polymer in solution.

• Journal of Advanced Marine Engineering and Technology
• /
• v.31 no.6
• /
• pp.804-809
• /
• 2007

In order to provide reliability. reproducibility. objectivity of solid particle separation performance test on marine centrifugal purifier, an investigation had been done on solid test dusts. test standards and designation of a definite standard test dust In test specifications or standards. ISO 121031-1 A2 test dust is the best test particle to meet commercial and military fuel oil and lube oil requirements on marine standards.

• Journal of Pharmaceutical Investigation
• /
• v.22 no.1
• /
• pp.33-40
• /
• 1992

This study was aimed to control the release characteristics of ketoprofen by microencapsulating $ketoprofen-{\beta}-cyclodextrin\;(KF-{\beta}-CyD)$ solid dispersion with Eudragit RS by the phase separation method using a nonaqueous vehicle. KF alone was also microencapsulated with Eudragit RS by the evaporation process in water phase. The results obtained showed that it was not possible to microencapsulate KF alone by phase separation in a chloroform-cyclohexane system while it was easy to microencapsulate $(KF-{\beta}-CyD)$ solid dispersion system. For the microcapsules, the release test was performed in the first fluid (pH 1.2) and the second fluid (pH 6.8) of K.P.V disintegration medium at $37^{\circ}C$. The release of KF from $(KF-{\beta}-CyD)$ solid dispersion microcapsules (1:1 core wall ratio) was more sustained than that from KF microcapsules, and followed zero-order kinetics. Especially, solid dispersion microcapsules showed pH-independent release patterns with higher wall to core ratio (1:1 w/w).

• Journal of Environmental Science International
• /
• v.31 no.1
• /
• pp.1-8
• /
• 2022

In this study, solid-liquid separation conditions for coagulation and sedimentation experiments using inorganic coagulant (aluminum sulfate and Poly-Aluminum Chloride (PAC)) were optimized with brine wastewater discharged by the epoxy-resin process. When the turbidity and suspended solid (SS) concentration in raw wastewater were 74 NTU and 4.1 mg/L, respectively, their values decreased the lowest in a coagulant dosage of 135.0 - 270.0 mg Al³⁺/L. The epoxy resin was re-dispersed in the upper part of wastewater treated above 405.0 mg Al³⁺/L. The removal efficiencies of turbidity and SS via dosing with aluminum sulfate and PAC were evaluated at initial turbidity and SS of 74 - 630 NTU and 4.1 - 38.5 mg/L, respectively. They increased most in the range from 135.0 - 270.0 mg Al³⁺/L. The solid-liquid separation condition was quantitatively compared to the correlation of SS removal efficiency between the coagulant dosage and SS concentration based on the concentration of aluminum ions. The empirical formula, R = be^aD, shows the relationship between SS removal efficiency (R) and coagulant dosage (D) at 38.5 mg/L; it produced high correlation coefficients (r²) of 0.9871 for aluminum sulfate and 0.9751 for PAC.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2007.06a
• /
• pp.37-38
• /
• 2007

It needs several large reservoirs and long time to remove suspended solid like steel fines and iron oxide in hot rolling coolant. If removing rate of suspended solid in rolling coolant is improved by using high gradient magnetic separation (HGMS) system, the productivity of working process can be increased and the area of reservoir can be reduced. Pre-treatment process that react magnetic floc with inorganic and organic flocculant in coolant was studied. Horizontal type superconducting HGMS system was manufactured successfully, which was constituted with automatic filter transportation apparatus, 6 T He-free superconducting magnet system and water circulation system. The solid suspension removal ratio in hot rolling coolant was increased by flocculation with inorganic and organic flocculant.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2006.06a
• /
• pp.87-88
• /
• 2006

It is needed several large reservoirs and long time in order to remove suspended solid like steel fines and iron oxide at steel making factory. If removing rate of suspended solid in rolling coolant is improved, the productivity of working process can be increased and the area of reservoir can be reduced. Pre-treatment to add extra magnetization of suspended solid was studied Iron hydroxide and electrolytic dissociation were used for pretreatment. High gradient magnetic separation (HGMS) system was used for removing of magnetized suspended solid. Removing ratio showed over than 99% in the coolant containing magnetic fines. Magnetic properties of suspended solid were investigated after mixed with Al2(SO2)3 and organic flocculant by using electrochemical treatment.

• Macromolecular Research
• /
• v.16 no.2
• /
• pp.113-119
• /
• 2008

A series of amphiphilic dendrons n-18 (n: generation number, 18: octadecyl chain) based on an aliphatic polyether denderitic core and octadecyl peripheries were synthesized using a convergent dendron synthesis consisting of a Williamson etherification and hydroboration/oxidation reactions. This study investigated their thermal and self-assembling behavior in the solid state using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) absorption spectroscopy, and small angle X-ray scattering (SAXS). DSC indicated that the melting transition and the corresponding heat of the fusion of the octadecyl chain decreased with each generation. FT-IR showed that the hydroxyl focal groups were hydrogen-bonded with one another in the solid state. DSC and FT-IR indicated microphase-separation between the hydrophilic dendritic cores and hydrophobic octadecyl peripheries. SAXS data analysis in the solid state suggested that the lower-generation dendrons 1-18 and 2-18 self-assemble into lamellar structures based upon a bilayered packing of octadecyl peripheries. In contrast, the analyzed data of higher-generation dendron 3-18 is consistent with 2-D oblique columnar structures, which presumably consist of elliptical cross sections. The data obtained could be rationalized by microphase-separation between the hydrophilic dendritic core and hydrophobic octadecyl peripheries, and the degree of interfacial curvature associated with dendron generation.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2017.05a
• /
• pp.275-276
• /
• 2017

• Journal of the Korea Organic Resources Recycling Association
• /
• v.22 no.3
• /
• pp.23-32
• /
• 2014

Recently, it is increase in the processing of organic waste using anaerobic digestion. Therefore, the studies on the processing method for increasing the anaerobic digestion waste water. But it is very difficult to solid-liquid separation, because the characteristics of anaerobic digestion waste water. So this study evaluate solid-liquid separation efficiency of anaerobic digestion sludge using CST(Capillary Suction Time), TTF(Time to Filter). To address this problem, a membrane filter press of the lab scale was produced and the anaerobic digestion wastewater was applied to it. Polymer coagulants were found to be most suitable 7192PLUS and 1T60, It is necessary to minimum injection concentration is 7192PLUS (200 mg/L), 1T60 (100 mg/L). To evaluate dehydration efficiency, it was measured the moisture content of the dehydrated cake and suspended solids of decanted water. As a result, showed that a high removal efficiency of 97.4% when the solid-liquid separation using the membrane filter press. And the moisture content of the dehydrated cake was less than 65%.

• Resources Recycling
• /
• v.16 no.6
• /
• pp.3-9
• /
• 2007

Although the ferrous material was separated by the magnetic separation before the incineration process, the municipal solid waste incineration bottom ash generated during incinerator in metropolitan area consists of many iron products which account for about $3{\sim}11%$ as well as ceramics and glasses. The formation of $NiFe_2O_4$ and $FeCr_2O_4$ with a $Fe_3O_4-Fe_2O_3$ (similar to pure Fe) on the surface of iron product was found during air-annealing in the incinerator at $1000^{\circ}C$, because Ni and Cr has a chemical attraction about iron is using to coat with Ni and Cr metals for poish or to prevent corrosion. Therefore, Fe-Ni Cr oxide can be formed on durface of the iron product and it can be separated from bottom ash through the magnetic separation. So, in this study, the separation ratio of heavy metals as magnetic separation and mineralogical formation of Fe-ion(heavy metal) in ferrous metals corroded were investigated. As the result, the separation ratio of Ni and Cr based on particle sizes accounted for about $45{\sim}50%$, and Cu and Pb accounted for below 20%. Also, the leaching concentration of Ni and Cr in bottom ash separated by magnetic separation was lower than that in fresh bottom ash.