• 한국재료학회지
• /
• 제17권6호
• /
• pp.313-317
• /
• 2007

In-situ micro-channeled multi tubular solid oxide fuel cell(SOFC) was fabricated using multi-pass extrusion process with out side diameter of 2.7 mm and active length of 5 mm that contained 61 individual cells. Cell materials used in this work were NiO-YSZ (50 : 50 vol.%), 8 mol% yttria-stabilized zirconia(8YSZ), $La_{0.8}Sr_{0.2}MnO_3(LSM)$ as anode, electrolyte, and cathode, respectively. The arrangement of each electrode and electrolyte layer in green bodies showed uniformity and integrity after extrusion and sintering. The XRD analysis confirmed that no reaction phases appeared and the microstructure of the electrolyte was fairly dense (relative density > 96%) after sintering.

• 한국에너지공학회:학술대회논문집
• /
• 한국에너지공학회 2003년도 춘계 학술발표회 논문집
• /
• pp.649-653
• /
• 2003

일반적으로 연료전지에는 알카리형(AFC)과 인산형(PAFC), 고분자형 연료전지(PEMFC) 등과 같이 비교적 저온에서 동작되는 연료전지와 고온형으로 $650^{\circ}C$에서 정온 동작되는 용융탄산염형 연료전지(MCFC)와 운전온도가 약 500~100$0^{\circ}C$로 폭넓게 적용될 수 있는 고체산화물 연료전지(혹은 고체전해질 연료전지, Solid Oxide Fuel Cell, SOFC)가 있다.(중략)

• Journal of Electrical Engineering and Technology
• /
• 제3권2호
• /
• pp.143-151
• /
• 2008

This paper presents the operation of Fuel Cell Distributed Generation(FCDG) systems in distribution systems. Hence, modeling, controller design, and simulation study of a Solid Oxide Fuel Cell(SOFC) distributed generation(DG) system are investigated. The physical model of the fuel cell stack and dynamic models of power conditioning units are described. Then, suitable control architecture based on fuzzy logic and the neural network for the overall system is presented in order to activate power control and power quality improvement. A MATLAB/Simulink simulation model is developed for the SOFC DG system by combining the individual component models and the controllers designed for the power conditioning units. Simulation results are given to show the overall system performance including active power control and voltage regulation capability of the distribution system.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2010년도 하계학술대회 논문집
• /
• pp.332-333
• /
• 2010

The 5kW SOFC(Solid Oxide Fuel Cell) System is composed to 3kW parallel Fuel Cell. We propose to the parallel control of 5kW PCS in the unbalance condition of fuel cell. The developed 5kW PCS can be found control ability of DC/DC converters in the operating conditions of the unbalanced parallel operation. It is verify to the control characteristics by simulation and experiment.

• 대한기계학회논문집B
• /
• 제30권3호
• /
• pp.193-200
• /
• 2006

The purpose of this study is to compare the part-load performance of a SOFC/GT hybrid power system with three different kinds of load-following operation modes. The primary mode for the part load operation of a hybrid power system is the reduction of supplied fuel (e.g., fuel control mode) to the hybrid system. The other two options, i.e., variable speed and VIGV controls, are related to the reduction of supplied air simultaneously with the reduction of supplied fuel to the system. With the performance analysis of a SOFC/GT hybrid power system, it is concluded that the variable speed con佐ol mode Provides the best performance for the part-load operations. It is also found that the VIGV control mode, with its better performance behavior than the fuel control mode, can be used as an important option for the part-load operation especially in case that the variable speed control mode can not be adopted.

• 한국세라믹학회지
• /
• 제47권1호
• /
• pp.86-91
• /
• 2010

Among various fuel cells, solid oxide fuel cells (SOFCs) offer the highest energy efficiency, when taking into account the thermal recycling of waste heat at high temperature. However, the highest efficiency and lowest pollution for a SOFC can be achieved through the sophisticated control of its constituent components such as electrodes, electrolytes, interconnects and sealing materials. The electrochemical conversion efficiency of a SOFC is particularly dependent upon the performance of its electrode materials. The electrode materials should meet highly stringent requirements to optimize cell performance. In particular, both mass and charge transport should easily occur simultaneously through the electrode structure. Matter transport or charge transport is critically related to the configuration and spatial disposition of the three constituent phases of a composite electrode, which are the ionic conducting phase, electronic conducting phase, and the pores. The current work places special emphasis on the quantification of this complex microstructure of composite electrodes. Digitized images are exploited in order to obtain the quantitative microstructural information, i.e., the size distributions and interconnectivities of each constituent component. This work reports regarding zirconia-based composite electrodes.

• 한국표면공학회지
• /
• 제30권5호
• /
• pp.333-346
• /
• 1997

Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

• 대한설비공학회:학술대회논문집
• /
• 대한설비공학회 2006년도 하계학술발표대회 논문집
• /
• pp.885-890
• /
• 2006

This study presents analysis results for the hybrid system combining solid oxide fuel cell and gas turbine. Two different system layouts(an ambient pressure system and pressurized system) are considered and their design performance are comparatively investigated taking into account critical design factor, the most critical parameter such as turbine inlet temperature, gas turbine pressure ratio, temperature difference at the fuel cell and fuel cell operating temperature are considered as design constraints. Performance variations according to system layout and design parameters are examined in energetic view point.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
• /
• pp.303-306
• /
• 2009

High temperature solid oxide fuel cells (SOFCs) offer a clean, pollution-free technology to electrochemically generate electricity at high efficiencies. Solid oxide fuel cells in several different designs have been investigated; these include planar and tubular geometries. The tubular type cell is widely researched due to it have advantages about thermal expansion and sealing issues. Unfortunately, lab scale tubular cell for testing has thermal expansion and sealing problems. The previous Jig for lab scale tubular cell testing has many sealing problems. When we feed fuel gas to jig inlet, ceramic glue sealant has amount of gas expansion pressure, because temperature of feeding gas changes ambient temperature to high temperature ($700{\sim}900^{\circ}C$). Furthermore, when we carry out long time test, something like degradation test, crack of ceramic glue sealant due to weakness of mechanical properties can make stop working the test. Additionally, we reduce setting process for assembling, because micanite is not required drying or debinding process.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2001년도 추계학술대회 논문집
• /
• pp.157-159
• /
• 2001

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO$_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(47vo1%) was bettor excellent than the others.