• Title/Summary/Keyword: Solid Flux

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Effects of $ B_2O_3$ composition for the photoluminescence and after-glow charcteristics of $SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ phosphors ($SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ 장잔광 형광체에 있어서 발광 및 장잔광특성에 미치는$B_2O_3$의 영향)

  • 이영기;엄기석
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.3
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    • pp.123-128
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    • 2004
  • Both photoluminescence and the long-phosphorescent properties for $SrAl_2O_4$ : Eu$^{+2}$, $Dy^{+3}$ phosphor powder synthesized by the solid phase reaction were investigated as a function of $B_2O_3$ composition (0-10 wt%). The highest emission wavelength (520nm) of photoluminescence spectra was not affected by $B_2O_3$concentration. The highest emission intensity was obtained by the concentration of 3 wt% $B_2O_3$.After the removal of the Xenon lamp excitation (360nm), also, the excellent long-phosphorescent property of the phosphors was obtained by the concentration of 3 wt% $B_2O_3$ although the decay times for all phosphors decreased exponentially.

Verification of the Filter Media Applied to Filter Type Facility Considering the Treatment Efficiency Factor (여과형 시설에 적용되는 여재의 처리효율 영향인자를 고려한 실증화 평가)

  • Kim, Taeyoon;Lee, Junebae;Lee, Dongwoo;Shin, Hyunsuk;Kim, Hyunchul;Kwon, Soonchul
    • Journal of Korean Society on Water Environment
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    • v.33 no.5
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    • pp.572-579
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    • 2017
  • Increased impervious surface caused by rapid urbanization serves to produce the discharge of non-point source pollutants such as total suspended solid (TSS). There exist various methods of removing TSS, including a filtration process using granular media (a well-known method to be practically used after the consideration of removal efficiency, clogging, and backwashing efficiency). To determine the TSS removal capability of the filter, we initially performed lab-scale experiments which assessed flow rates, influent concentrations, permeability co-efficients, the particular shapes of suspended solids and potential clogging, and also evaluated TSS removal efficiency when applied to filtration facility in a pilot-scale. In low filtration flux condition, the removal efficiency of suspended solids was more than 95 %, while decreased to 83% in high filtration flux. Regarding the clogging aspect of the experiment, total cumulative solids were loaded up to $19.15kg/m^2$, and TSS removal efficiency was noted to commence to decrease when the loaded solids exceeded $9.0kg/m^2$. It was also noted, however, that superior efficiency was maintained for six hours. In addition, for pilot-scale experiment, the removal efficiency was still high enough (83.4 %) for the solid concentration of 140 ~ 343 mg SS/L and after backwashing, head loss was recovered to 92 ~ 95 % during two hour filtration. With these results, It was confirmed that lifetime of the filter applied to the test was prolonged due to the high treatment efficiency and good backwashing efficiency for the cumulative solids load.

Effects of Ultrafiltration on the Production of Xylooligosaccharides (Xylooligosaccharides 제조를 위한 한외여과 처리)

  • Park, Youn-Je;Oh, Hwa-Gyun;Lee, Ji-Wan;Lee, Chang-Seung;Lee, Un-Taek;Rhew, Bo-Kyoung;Yang, Chang-Kun;Yoon, Se-Wang
    • Korean Journal of Food Science and Technology
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    • v.32 no.2
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    • pp.312-316
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    • 2000
  • Crude xylooligosaccharides(XO) were separated with a cellulose membrane (10,000 molecular weight cut-off). Flux variation was measured at transmembrane pressures of 5, 10, 20 and 30 psi, while flow rates were maintained at 100, 200, 300 and 400 ml/min and temperatures at 10, 20, 23-25 and $30^{\circ}C$. Optimal conditions were found at the transmembrane pressure of 20 psi, the flow rate of 300 ml/min and the temperature of $23-25^{\circ}C$, where the flux was decreasing with time by 62% after 200 min. Total sugar, total solid and ash contents were rather independent of ultrafiltration but protein was removed up to 55% from crude XO. Especially, the use of ultrafiltration was very effective for decolorization (84%) of crude XO. These results suggest that ultrafiltration is a useful method for the primary purification of XO.

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Solid State Cesium Ion Beam Sputter Deposition

  • Baik, Hong-Koo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.5-18
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    • 1996
  • The solid state cesium ion source os alumino-silicate based zeolite which contains cerium. The material is an ionic conductor. Cesiums are stably stored in the material and one can extract the cesiums by applying electric field across the electrolyte. Cesium ion bombardment has the unique property of producing high negative ion yield. This ion source is used as the primary source for the production of a negative ion without any gas discharge or the need for a carrier gas. The deposition of materials as an ionic species in the energy range of 1.0 to 300eV is recently recognized as a very promising new thin film technique. This energetic non-thermal equilibrium deposition process produces films by “Kinetic Bonding / Energetic Condensation" mechansim not governed by the common place thermo-mechanical reaction. Under these highly non-equilibrium conditions meta-stable materials are realized and the negative ion is considered to be an optimum paeticle or tool for the purpose. This process differs fundamentally from the conventional ion beam assisted deposition (IBAD) technique such that the ion beam energy transfer to the deposition process is directly coupled the process. Since cesium ion beam sputter deposition process is forming materials with high kinetic energy of metal ion beams, the process provider following unique advantages:(1) to synthesize non thermal-equilibrium materials, (2) to form materials at lower processing temperature than used for conventional chemical of physical vapor deposition, (3) to deposit very uniform, dense, and good adhesive films (4) to make higher doposition rate, (5) to control the ion flux and ion energy independently. Solid state cesium ion beam sputter deposition system has been developed. This source is capable of producing variety of metal ion beams such as C, Si, W, Ta, Mo, Al, Au, Ag, Cr etc. Using this deposition system, several researches have been performed. (1) To produce superior quality amorphous diamond films (2) to produce carbon nitirde hard coatings(Carbon nitride is a new material whose hardness is comparable to the diamond and also has a very high thermal stability.) (3) to produce cesiated amorphous diamond thin film coated Si surface exhibiting negative electron affinity characteristics. In this presentation, the principles of solid state cesium ion beam sputter deposition and several applications of negative metal ion source will be introduced.

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A Modeling Approach: Effects of Wetland Plants on the Fate of Metal Species in the Sediments (퇴적물에서 금속 이온 거동에 미치는 습지 식물의 영향에 관한 모델 연구)

  • Choi, Jung Hyun
    • Journal of Korean Society on Water Environment
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    • v.24 no.5
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    • pp.603-610
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    • 2008
  • A mathematical model was developed to understand how the presence of plants affects vertical profiles of electron acceptors, their reduced species, and trace metals in the wetland sediments. The model accounted for biodegradation of organic matter utilizing sequential electron acceptors and subsequent chemical reactions using stoichiometric relationship. These biogeochemical reactions were affected by the combined effects of oxygen release and evapotranspiration driven by wetland plants. The measured data showed that $SO_4{^{2-}}$ concentrations increased at the beginning of the growing season and then gradually decreased. Based on the measured data, it was hypothesized that the limitation of the solid phase sulfide in direct contact with the roots may result in the gradual decrease of $SO_4{^{2-}}$ concentrations. With the dynamic formulation for the limitation of the solid phase sulfide, model simulated time variable sulfate profiles using published model parameters. Oxygen release from roots produced divalent metal species (i.e. $Cd^{2+}$) as well as oxidized sulfur species (i.e. $SO_4{^{2-}}$) in the sediment pore water. Evapotranspiration-induced advection increased flux of divalent metal species from the overlying water column into the rhizosphere. The increased divalent metal species were converted to the metal sulfide with sufficient FeS around the rhizosphere, which contributed to the decrease of bioavailability and toxicity of divalent metal activity in the pore water. Since the divalent metal activity is a good predictor of the metal bioavailability, this model with a proper simulation of solid phase sulfide plays an essential role to predict the dynamics of trace metals in the wetland sediments.

Topographical Change Monitoring of the Sandbar and Estimation of Suspended Solid Flux in the Nakdong River Estuary - Focused on Jinudo - (낙동강 하구역 사주지형 변동과 부유사(SS) 수송량 산정 - 진우도를 중심으로 -)

  • Lee, I.C.;Lim, S.P.;Yoon, H.S.;Kim, H.T.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.2
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    • pp.70-77
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    • 2008
  • In this study, to establish countermeasure from marine casualties as a basic study fur long-term prediction of topographical change around Jinudo in the Nakdong river estuary, spatio-temporal topographical change monitoring was carried out. Also, in order to estimate the deposition variations concerning SS (Suspended Solid) flux which moved at St.S1 during neap and spring tide, respectively. From the topographical monitoring, it was found that the annual mean ground level and deposition rate were 141 mm and 0.36 mm/day and all parts except the northern part of Jinudo had the active topographical changes and a tendency to annually deposit. From vertical distribution of SS net fluxes, $SS_{LH}$ (latitudinal SS net flux) during spring tide overall flows average 28 $kg/m^2/hr$ (eastward), and $SS_{LV}$ (longitudinal SS net flux) flows average 11.1 $kg/m^2/hr$ (northward). And, $SS_{LH}$ overall flows average 4.8 $kg/m^2/hr$ (eastward), and $SS_{LV}$ flows average 1.5 $kg/m^2/hr$ (northward) during neap tide similar with spring tide. The depth averaged values of the latitudinal and longitudinal SS net fluxes during spring tide were approximately 6 times higher than those during neap tide. As result of, it was considered that topographical change of southern part of Jinudo was affected by resuspension of bottom sediments due to strong current in bottom layer during flood flow.

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Long Term Operation of Microfiltration Membrane Pilot Plant for Drinking Water Treatment (정수처리를 위한 정밀여과막 모형플랜트의 장기운전 특성)

  • Kim, Chung H.;Lee, Byung G.;Lim, Jae L.;Kim, Seong S.;Lee, Kyeong H.;Chae, Seon H.
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.4
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    • pp.493-501
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    • 2007
  • The membrane pilot plant has being operated in the Hyeondo pumping station to find the optimal operation technique of Gong-Ju membrane water treatment plant (WTP) which is constructing in $250m^3/d$ scale. The pilot plant was consisted of two trains which can treat $30,000m^3/d$ per train. First train was operated for one year under the condition of flux $1m^3/m^2{\cdot}d$ while the effects of flux variation and addition of powdered activated carbon(PAC) were evaluated in second train. The turbidity of membrane product water of first train which is operated on Flux $1m^3/m^2{\cdot}d$ was always below 0.05 NTU regardless of raw water turbidity. And also, the trance-membrane pressure(TMP) was maintained at $0.3{\sim}0.5kgf/cm^2$ for about 9 months and increased rapidly to $1.8kgf/cm^2$ which is maximum operating TMP. However, TMP was rapidly increased to $1.8kgf/cm^2$ within 2 months as flux was increased from 1 to $2m^3/m^2{\cdot}d$, especially, within 10 days under high turbidity(30~50NTU). This reault means that if Gongju membrane WTP is operated in flux $1m^3/m^2{\cdot}d$, chemical cleaning period can be maintained over 6 months. Only 10% of dissolved organic carbon (DOC) was removed in membrane process while the removal efficiencies of manganese and iron were 60% and 77% respectively. However, because only solid manganese and iron were removed in membrane process, an additional process for treating soluble manganese is required if souble manganese is high in raw water. 70% of 70ng/L 2-MIB which is causing taste & odor was removed in powdered activated carbon (PAC) tank with 50mg/L PAC which is design concentration of Gongju WTP. In addition, TMP was reduced with addition of 50mg/L PAC regardless of flux. Because TMP was not influenced even if 100mg/L PAC was added, the high taste and odor problem can be controled by additional injection of PAC.

Synthesis and Luminescent Characteristics of Sr4Al14O25 Phosphor (Sr4Al14O25 형광체의 합성과 발광특성)

  • Han Sang Hyuk;Kim Young Jin
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.529-534
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    • 2004
  • $Sr_{4}Al_{14}O_{25}$ was synthesized by solid state reaction with flux. $H_{3}BO_3$ was used to synthesize $SrO-Al_{2}O_{3}$ phosphor system as a flux. The effect of doping system such as Eu+Dy, Eu, and Ce on the luminescent properties of $Sr_{4}Al_{14}O_{25}$ was investigated. Both PL spectra of $Sr_{4}Al_{14}O_{25}$:Eu and $Sr_{4}Al_{14}O_{25}$:Eu+Dy excited at 390 nm showed greenish-blue emission at about 490 nm, while the emission wavelength was shifted to 400 nm by doping Ce. The reduction of $Eu^{3+}$ ions to $Eu^{2+}$ could be accomplished by the annealing process under $N_{2}^{+}$ vacuum atmosphere, and attributed to the emission at 490 nm. It is verified that $Sr_{4}Al_{14}O_{25}$:Eu phosphor is suitable for white LEDs became of a broad absorption band peaking at 390 nm.

A Study on the Local Regression Rate of Solid Fuel in Hybrid Rocket (하이브리드 로켓에서의 고체연료의 국부 후퇴율에 관한 연구)

  • Kim, Soojong;Lee, Jungpyo;Kim, Gihun;Cho, Jungtae;Kim, Hakchul;Woo, Kyoungjin;Moon, Heejang;Sung, Hong-Gye;Kim, Jin-Kon
    • Journal of Aerospace System Engineering
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    • v.2 no.4
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    • pp.1-6
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    • 2008
  • In generally, the regression rate was expressed with average value and oxidizer mass flux in hybrid propulsion system. This can not represent the local value of regression rate along with oxidizer flow direction. In this study, experimental studies were performed with Separation method and Cutting method for measure local regression rate. In axial injection, the local regression rate decreases rapidly with axial location near entrance and increases with axial direction from the leading edge and the empirical formula for local regression rate with function of oxidizer mass flux and location was derived. Swirl injection regression rate has higher value at the leading edge of the fuel and comparatively uniform regression rate at the downstream. Overall regression rate of swirl injection is higher increased about 54 % than regression rate of axial injection.

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An Analytical Solution for the Unsteady Close-Contact Melting by Convective Heating (대류가열 비정상 접촉융해에 대한 해석해)

  • Yoo, Ho-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.3
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    • pp.450-458
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    • 2000
  • This study deals with the unsteady close-contact melting of solid blocks on a flat surface subject to convective heating. Normalizing the model equations in reference to the steady solution successfully leads them to cover constant heat flux and isothermal limits at small and large extremes of the Biot number, respectively. The resulting equations admit a compactly expressed analytical solution, which includes the previous solutions as a subset. Based on the steady solution, the characteristics of close-contact melting can be categorized into constant heat flux, transition, and isothermal regimes, the boundaries of which appear to be nearly independent of the contact force. The unsteady solutions corresponding to Biot numbers in the transition regime show intermediate behaviors between those of the two limits. With a proper approximation, the present solution procedure can cope with the case of variable fluid temperature and heat transfer coefficient. Regardless of imposed conditions, the mean normalized Nusselt number during the unsteady process asymptotically approaches to a constant value as the Biot number comes close to each limit.