• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.105.2-105.2
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• 2011

화비정질 실리콘의 빛에 의한 노화현상 (light-induced degradation; LID)은 이미 1977년 보고된 Staebler-Wronski 효과에 의해서 확인된 바 있다. 이는 비정질 실리콘이 빛에 노출될 때, 이미 포함되어 있는 수소원자가 빛 에너지에 의해서 이동하게 되고, 이로 인해서 생성 또는 소멸되는 댕글링 본드 때문에 일어난다. 특히, 일상적인 태양광의 노출 하에서 태양전지의 장시간 성능을 예측하는데 물리적인 이해의 부족 및 기술 환경적인 어려움이 있고, 이러한 요인들은 안정된 태양전지를 개발하는데 장해요인으로 나타난다. 그러므로 비정질 실리콘 태양전지가 장시간 태양광에 노출되어 시간이 지남에 따라서 "성능이 어떻게 변하는지?" 그리고 "이에 대한 원인은 무엇인지?" 등은 여전히 과학적으로 풀어야할 숙제로 남아있다. 본 논문에서는 비정질 실리콘으로 구성된 태양전지가 태양광에 노출될 때 시간이 지남에 따라서 (1) 성능이 어떻게 변하는지, (2) LID의 변화는 언제 안정화되는지, 그리고 (3) 성능변화에 대한 원인은 무엇인지에 대해서 논의한다. 본 논문은 장시간 빛에 노출되는 비정질 실리콘 태양전지의 성능예측에 관해서 연구하였다. 결함밀도의 운동학적 모형을 통해서 태양광 노출에 대한 태양전지 성능변화를 예측하는데 초점을 맞추었고, 이를 위해서 태양전지에 조사되는 태양광 세기, 주변온도, 등이 고려되었다. 특히, 전하운반자의 수명이 결함밀도에 의해서 결정되기 때문에 비정질 실리콘 태양전지의 빛에 대한 노화현상 (LID)이 확장지수함수 (stretched-exponential) 완화법칙을 따르는 결함밀도에 의해서 물리적으로 설명된다. 한편 이와 같은 물리적 계산의 유용성을 확인하기 위해서 동일한 태양전지에 대해서 AMPS-1D 컴퓨터 프로그램을 사용하였고, 이를 통해서 비정질 실리콘 태양전지의 빛에 대한 노화현상을 물리적 및 정량적으로 이해하였다. 본 연구에 적용되는 태양전지는 비정질 실리콘으로 구성된 pin 구조 (glass/$SnO_2$/a-SiC:H:B/a-Si:H/a-Si:H:P/ITO)로서 다음과 같은 특성을 갖는다: 에너지 띠간격~1.72 eV, 두께~400 nm, 내부전위~1.05 V, 초기 fill factor~0.71, 초기 단락전류~16.4 mA/$cm^2$, 초기 개방전압 0.90 V, 초기 변환효율 10.6 %. 우리는 이와 같은 연구를 통해서 과학적으로 비정질 실리콘의 빛에 의한 노화현상을 이해하고, 기술적으로 효율 및 경제성이 높은 태양전지의 개발에 도전한다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.364-364
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• 2013

현재 투명전극은 주로 ITO를 사용하고 있으며, ITO는 인듐산화물(In2O3)과 주석산화물(SnO2)이 9대 1의 비율로 혼합된 화합물로 인듐이 주성분이다. 따라서 ITO 사용량의 증가는 인듐의 수요 증가를 이끌어 2003년 이후 인듐 잉곳의 가격이 급등하였다. LCD에 응용되는 금속재료의 가격추이를 비교해보면, 인듐이 가장 큰 변화를 보이고 있으며, 2005년 인듐 가격은 2002년 대비 1,000% 이상 상승하였다가 2007년 이후 500%p 하락하여 2008년 2월 22일 기준으로 톤당 49만 달러에 거래되고 있다. 같은 기간 동안 알루미늄의 가격은 76.6% 상승하였으며 구리는 394%, 주석은 331% 상승하였다. 이러한 인듐의 가격 상승폭은 동일한 기간 동안 다른 금속 재료와 비해 매우 크며, 단위 질량당 가격도 20배 이상 높은 수준이다. ITO의 주성분인 인듐의 이러한 가격의 급등 및 향후 인듐의 Shortage 예상으로 인해 ITO 대체재 확보의 필요성이 증가되고 있다. 태양광 발전산업에서 현재 주류인 결정질 실리콘 태양전지의 변환효율은 꾸준히 향상되고 있으나, 태양전지의 가격이 매년 서서히 하강되고 있는 실정에서 결정질 실리콘 가격의 상승 등으로 고부가 가치 산업유지에 어려움이 있으며, 생산 원가를 낮출 수 있는 태양전지 제조기술로는 2세대 태양전지로 불리는 박막형이 현재의 대안으로 자리매김하고 있으며, 박막태양전지 산업분야가 현재의 정부정책 지원 없이 자생력을 갖추고 또한 시장 경쟁력을 확보하기 위해서는 박막태양전지 개발과 더불어 저가의 재료개발도 시급한 상황이다. 본 연구에서는 In-line magnetron sputtering system을 사용하여 소다라임 유리기판 위에 박막태양전지용 투명전도성 ZnO(Al) 박막 및 ZnO(AlGa) 박막을 각각 제작하였다. 각각 박막의 표면특성 및 성장구조, 결정성을 조사하였고, 또한 전기적 특성, 홀이동도와 개리어농도, 박막의 두께, 광투과율 특성을 연구하였다. ZnO(Al)박막, ZnO(AlGa)박막 대한 각각 특성을 평가하고 그 결과들을 논하고자 한다.

• Journal of Astronomy and Space Sciences
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• v.21 no.4
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• pp.505-528
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• 2004

We have reproduced the records of lunar occultation recorded in the History of Three Kingdoms(삼국사기), the History of the Koryo Dynasty (고려사), the Annals of the Choson Dynasty (朝鮮王朝實錄), the Daily Records of Royal Secretariat of the Choson Dynasty (승정원일기), and obtained the epochs of their realizations. We analysed these results to understand how the system of hours had been kept and when a day began. During most of the periods encompassed by these annals, the 12 double hours(12진각법) and the system of 100 divisions of the day (백각법) had been used when the lunar and the solar eclipses were calculated by royal astronomers. In these systems, the starting point of a day is midnight. On the other hand, the five watch system of hours (경점법), in which a night is divided into five watches, was also used. In this system, a day begins at the sunrise. We found that the traditional twilight, called dusk and dawn (혼명) and used in the east Asian countries, largely corresponds to the nautical twilight in modern concepts. This fact means that the Korean expressions and words for time system in every day life had originated form the five watch system of hours. We pointed out that the sunrise and sunset were convenient boundary lines to ancient astronomers, as well as to farmers in the agricultural society. Our results can be used to determine the exact epoch of each astronomical record in chronicles.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.10
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• pp.590-597
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• 2018

Recently, the installation of PV systems has been increasing due to the worldwide interest in eco-friendly and renewable solar energy. On the other hand, the output power of PV systems is influenced strongly by the surrounding weather conditions. In addition, the entire operation efficiency of PV systems may be decreased considerably even if only some of the PV modules are in the shade. In other words, the existing control method at which strings with modules in series are connected to an inverter may be not operated in the case that the string voltage in partial shade is lower than the operating range of the grid connected inverter. To overcome these problems, this paper proposes an operation efficiency improvement device of a PV system using a Li-ion battery, which can compensate for the voltage of each string in the PV system when it is partially shaded. In addition, this paper presents the modeling of the operation efficiency improvement device, including PV strings, Li-ion battery and a 3-Phase grid inverter based on the PSIM S/W. From the simulation results, it was confirmed that the proposed control method can improve the operating efficiency of PV systems by compensating for the string voltage with partial shade.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.4
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• pp.1458-1467
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• 2010

Recently, imitation and infringement rights of an intellectual property are being recognized as impediments to nation's industrial growth. To prevent the huge loss which comes from theses impediments, many researchers are studying protection and efficient management of an intellectual property in various ways. Especially, the prediction of patent registration is very important part to protect and assert intellectual property rights. In this study, we propose the patent document analysis method by using text mining to predict whether the patent is registered or rejected. In the first instance, the proposed method builds the database by using the word frequencies of the rejected patent documents. And comparing the builded database with another patent documents draws the similarity value between each patent document and the database. In this study, we used k-means which is partitioning clustering algorithm to select criteria value of patent rejection. In result, we found conclusion that some patent which similar to rejected patent have strong possibility of rejection. We used U.S.A patent documents about bluetooth technology, solar battery technology and display technology for experiment data.

• Proceedings of KOSOMES biannual meeting
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• 2006.11a
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• pp.181-186
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• 2006

Geostationary Orbit satellite, unlike other sun-synchronous polar-orbit satellites, will be able to take a picture of a large region several times a day (almost with everyone hour interval). For geostationary satellite, the target region is fixed though the location of sun is changed always. However, Sun-synchronous polar-orbit satellites able to take a picture of target region same time a everyday. Thus Ocean signal is almost same. Accordingly, the ocean signal of a given target point is largely dependent on time. In other words, the ocean signal detected by geostationary satellite sensor must translate to the signal of target when both sun and satellite are located in nadir, using another correction model. This correction is performed with a standardization of signal throughout relative geometric relationship among satellite-sun-target points. This relative ratio called bidirectional factor. To find relationship between time and $[L_w]_N$/Bidirectional Factor differences, we are calculate solar position, geometry parameters. And reflectance, total radiance at the top of atmosphere(). And water leaving radiance, normalized water leaving radiance. And calculate bidirectional factor, that is the ratio of $[L_w]_N$ between target region and aiming the point. Then, we can make the bidirectional factor lookup table for one year imaging. So, we suggested for necessary to simulation experiment bidirectional factor in more various condition(wavelength and ocean/air condition).

• Journal of Astronomy and Space Sciences
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• v.26 no.4
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• pp.499-510
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• 2009

In this paper, relative orbit of Low Earth Orbit satellites is determined using only GPS measurements and the effects of Equatorial Spread-F (ESF), that is one of biggest ionospheric irregularities, are investigated. First, relative orbit determiation process is constructed based on doubly differenced GPS observations. In order to see orbit determination performance, relative orbit of two GRACE satellites is estimated for one month in 2004 when no ESF is observed. The root mean square of the achieved baselines compared with that from K-Band Ranger sensor is about 2~3 mm and average of 95% of ambiguities are resolved. Based on this performance, the relative orbit is estimated for two weeks of two difference years, 2003 when there are lots of ESF occurred, and 2004 when only few ESF occurred. For 2003, the averaged baseline error over two weeks is about 15 mm. That is about 4 times larger than the case of 2004 (3.6 mm). Ionospheric status achieved from K-Band Ranging sensor also shows that more Equatorial Spread-F occurred at 2003 than 2004. Investigation on raw observations and screening process revealed that the ionospheric irregualarities caused by Equatorial Spread-F gave significant effects on GPS signal like signal loss or enhancement ionospheric error, From this study, relative orbit determination using GPS observations should consider the effect of Equatorial Spread-F and adjust orbit determination strategy, especially at the time of solar maximum.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.7
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• pp.704-712
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• 2016

Recently, the installation of photovoltaic (PV) systems has been increasing due to the worldwide interest in eco-friendly and infinitely abundant solar energy. However, the output power of PV systems is highly influenced by the surrounding environment. For instance, a string of PV systems composed of modules in series may become inoperable under cloudy conditions or when in the shade of a building. In other words, under these conditions, the existing control method of PV systems does not allow the string to be operated in the normal way, because its output voltage is lower than the operating range of the grid connected inverter. In order to overcome this problem, we propose a new control method using a DC-DC voltage regulator which can compensate for the voltage of each string in the PV system. Also, based on the PSIM S/W, we model the DC-DC voltage regulator with constant voltage control & MPPT (Maximum Power Point Tracking) control functions and 3-Phase grid connected inverter with PLL (Phase-Locked Loop) control function. From the simulation results, it is confirmed that the present control method can improve the operating efficiency of PV systems by compensating for the fluctuation of the voltage of the strings caused by the surrounding conditions.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.12
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• pp.801-809
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• 2012

Long-term measurement of total mercury (TM) and dissolved gaseous mercury (DGM) were performed in Yangsuri marsh. Average TM and DGM concentrations were $2.0{\pm}2.0$ ng/L and $15.0{\pm}2.8$ pg/L, respectively, indicating that only 2.6% of TM existed as the form of DGM in Yangsuri marsh. While TM did not show the seasonal variation a statistically high DGM concentration was observed in warm season, indicating that DGM was effectively produced by strong solar radiation and high water temperature. There was no relationship between TM and DGM concentrations in Yangsuri marsh, as observed in other studies. DGM in Yangsuri marsh was supersaturated for most of sampling period; therefore, one can conclude that $Hg^0$ in water surface can readily volatilize to the atmosphere.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.369-380
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• 2020

Most mono-crystalline silicon ingots are manufactured by the Czochralski (Cz) process. But If there are oxygen impurities, These Si-ingot tends to show low-efficiency when it is processed to be solar cell substrate. For making single-crystal Si- ingot, We need Czochralski (Cz) process which melts molten Si and then crystallizing it with seed of single-crystal Si. For melts poly Si-chunk and forming of single-crystalline Si-ingot, the heat transfer plays a main role in the structure of Cz-process. In this study to obtain high-quality Si ingot, the Cz-process was modified with the process design. The crystal growth simulation was employed with pulling rate and rotation speed optimization. Studies for modified Cz-process and the corresponding results have been discussed. The results revealed that using crystal growth simulation, we optimized the oxygen concentration of single crystal silicon by the optimal design of the pulling rate, rotation speed and melt charge level of Cz-process.