• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3407-3412
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• 2012

The Ti incorporation at Fe-site in the double perovskite lattice of $Sr_2FeNbO_6$ (SFNO) system is studied. The Ti concentration optimization yielded an efficient photocatalyst. At an optimum composition of Ti as x = 0.07 in $Sr_2Fe_{1-x}Ti_xNbO_6$, the photocatalyst exhibited 2 times the quantum yield for photolysis of $H_2O$ in presence of $CH_3OH$, than its undoped counterpart under visible light (${\lambda}{\geq}420nm$). Heavily Ti-doped $Sr_2Fe_{1-x}Ti_xNbO_6$ lattice exhibited poor photochemical properties due to the existence of constituent impurity phases as observed in the structural characterization, as well as deteriorated optical absorption. The higher electron-density acquired by n-type doping seem to be responsible for the more efficient charge separation in $Sr_2Fe_{1-x}Ti_xNbO_6$ (0.05 < x < 0.4) and thus consequently displays higher photocatalytic activity. The Ti incorporated structure also found to yield stable photocatalyst.

• 한국재료학회지
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• 제26권8호
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• pp.401-405
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• 2016

The cobalt silicides were investigated for employment as a catalytic layer for a DSSC. Using an E-gun evaporation process, we prepared a sample of 100 nm-thick cobalt on a p-type Si (100) wafer. To form cobalt silicides, the samples were annealed at temperatures of $300^{\circ}C$, $500^{\circ}C$, and $700^{\circ}C$ for 30 minutes in a vacuum. Four-point probe, XRD, FE-SEM, and CV analyses were used to determine the sheet resistance, phase, microstructure, and catalytic activity of the cobalt silicides. To confirm the corrosion stability, we also checked the microstructure change of the cobalt silicides after dipping into iodide electrolyte. Through the sheet resistance and XRD results, we determined that $Co_2Si$, CoSi, and $CoSi_2$ were formed successfully by annealing at $300^{\circ}C$, $500^{\circ}C$, and $700^{\circ}C$, respectively. The microstructure analysis results showed that all the cobalt silicides were formed uniformly, and CoSi and $CoSi_2$ layers were very stable even after dipping in the iodide electrolyte. The CV result showed that CoSi and $CoSi_2$ exhibit catalytic activities 67 % and 54 % that of Pt. Our results for $Co_2Si$, CoSi, and $CoSi_2$ revealed that CoSi and $CoSi_2$ could be employed as catalyst for a DSSC.

• 한국식품저장유통학회지
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• 제12권2호
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• pp.184-189
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• 2005

젓갈은 전남 목포지역의 대형마트 및 가정에서 수집하였으며 오징어젓, 갈치속젓, 꼴뚜기젓, 멸치젓 등 10여종의 젓갈로부터 균을 분리하였다. 이들 분리 유산균 중 3균주가 인공위액과 인공담즙액에서 내성을 나타내었다. 이들 분리된 균주 중 생존력이 왕성한 3균주는 모두 인공위액에서 2시간, 인공담즙액에서 24시간 생존 가능하였다. 특히 유산균 ML 36, ML 128, ML 178 외 2종의 효모는 초기 생균수와 인공위액에서 2시간 배양 후 생균수의 변화가 거의 없어 가장 강한 내성을 나타내었다. 인공위액에서 분리된 균주의 생존율은 낮은 pH로 인하여 낮은 경향을 나타내었으나, 인공담즙액에 대해서는 높은 생존율을 나타내었다. 인공위액 및 인공담즙에 내성을 나타낸 3종의 유산균이 항생물질인 nicin, rifamycin, streptomycin, 그리고 tetracycline에 대하여 내성을 나타내었다. 또한 이들 분리 유산균은 병원성 미생물인 Listeria monocytogenes 대해 뚜렷한 항균 효과가 있는 것으로 나타났다.

• 한국수산과학회지
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• 제30권6호
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• pp.974-983
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• 1997

The Okhotsk Sea is unique natural object with climatic peculiarities. The climate of the Okhotsk Sea results from the general distribution of solar radiation during a year, and the characteristics of the atmospheric circulation that varies through a year: In cold half year the main pressure formations are Siberian high and Aleutian low. Asian low centered on Afghanistan dominates over the Asian continent in summer. The North-Pacific sea surface is under effect of permanent North Pacific high. The changes in their position from year to year are very significant. The anticyclonic activity over the Far Eastern Seas is one of the main factors for the formation of weather anomalies over the adjacent territories. The analysis of summer weather characteristics over the coast of Okhotsk and East Sea using the data obtained from Hydrometeorological stations during $1949\~1990$ showed that, to a great extent, distribution of the air temperature depends on thermal state of the Okhotsk Sea and atmospheric circulation over it. We show some relations between weather characteristics and the intensity of atmospheric action center for the North Pacific high in summer when its ridge propagates to Okhotsk Sea. Correlation coefficients between air pressure over the Okhotsk Sea and air temperature for the coastal areas reach up to 0.7. Analysis of the spatial-temporal distribution of main meteorological values over the Okhotsk Sea such as air pressure, and air temperature are also performed.

• Journal of Electrochemical Science and Technology
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• 제14권4호
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• pp.388-396
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• 2023

Photoelectrochemical (PEC) water splitting is a vital source of clean and sustainable hydrogen energy. Moreover, the large-scale H₂ production is currently necessary, while long-term stability and high PEC activity still remain important issues. In this study, a GaN-based photoelectrode was modified by an additional NH₃ treatment (900℃ for 10 min) and its PEC behavior was monitored. The bare GaN exhibited a highly crystalline wurtzite structure with the (002) plane and the optical bandgap was approximately 3.2 eV. In comparison, the NH₃-treated GaN film exhibited slightly reduced crystallinity and a small improvement in light absorption, resulting from the lattice stress or cracks induced by the excessive N supply. The minor surface nanotexturing created more surface area, providing electroactive reacting sites. From the surface XPS analysis, the formation of an N-Ga-O phase on the surface region of the GaN film was confirmed, which suppressed the charge recombination process and the positive shift of E_FB. Therefore, these effects boosted the PEC activity of the NH₃-treated GaN film, with J values of approximately 0.35 and 0.78 mA·cm^-2 at 0.0 and 1.23 V_RHE, respectively, and an onset potential (V_on) of -0.24 V_RHE. In addition, there was an approximate 50% improvement in the J value within the highly applied potential region with a positive shift of V_on. This result could be explained by the increased nanotexturing on the surface structure, the newly formed defect/trap states correlated to the positive V_on shift, and the formation of a GaO_xN_1-x phase, which partially blocked the charge recombination reaction.

• Korean Chemical Engineering Research
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• 제52권5호
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• pp.667-671
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• 2014

본 연구에서는 전구체 각각의 독립제어가 가능한 이성분계 금속산화물을 얻기 위해 졸-겔법으로 합성한 실리카 나노입자를 $TiO_2$ 전구체와 교반시켜 전기방사법을 이용하여 실리카가 고르게 분산된 $TiO_2$ 나노섬유를 성공적으로 제작하였다. 제작된 나노섬유는 FE-SEM, XRD, EDS를 이용해 구조적 특성분석과 UV-VIS, 광촉매 반응기를 통해 광촉매 특성 분석을 하였다. 그 결과, 실리카가 분산된 $TiO_2$ 나노섬유는 실리카가 분산되지 않은 $TiO_2$ 나노섬유 보다 광촉매 효율이 10% 가량 향상되었다. 이는 실리카 나노입자가 첨가됨으로써 $TiO_2$가 흡수하지 못하는 380~440 nm 가시광선 영역을 흡수하여 광학적 특성 향상되었으며 Ti와 Si 두 금속산화물간에 $Br{\o}nsted$ acid site가 생성되어 OH 라디칼을 증가시킴으로써 광조사에 의해 여기된 전자를 잡아 재결합 손실을 억제하는 역할을 하여 화학적 특성이 개선되어 광촉매 효율이 증가되었을 것으로 사료된다.

• 한국작물학회지
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• 제63권2호
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• pp.120-130
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• 2018

Improvement in rice grain yield has been approached by means of genetic amendment, cultural management, and environmental adaptation. Subjecting the plant during the grain filling period to an appropriate environment plays a key role in achieving a high grain yield in temperate rice. Field experiments were conducted for two consecutive years with two planting times to assess the relations among grain filling traits, loss of leaf activity during the ripening period, and the grain yield of temperate japonica rice with wide environmental variation. Higher grain yields were attained in 2017 than in 2016 and with late planting than with early planting. The high grain yield accompanied a comparatively lesser increase in grain weight at the early filling stage but more gain in grain weight occurred during the late filling stage. Final grain weight correlated positively with grain filling duration but negatively with grain filling rate. Extended grain filling duration was associated with higher cumulative temperature and cumulative solar radiation for an effective grain filling period. The reduction in SPAD value ${\times}$ leaf dry weight from heading to harvest significantly correlated with final grain dry weight in a positive manner. No significant relation was found between grain filling duration and the decrease in SPAD value ${\times}$ leaf dry weight during the grain filling period. The results suggest that grain filling duration and loss of leaf activity during ripening independently contribute to environmentally induced yield improvement in temperate japonica rice.

• 항공우주기술
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• 제4권1호
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• pp.221-228
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• 2005

본 기술 논문에서는 아리랑 2호 APS의 안정적인 운용 및 TPF의 정밀도와 관련하여 궤도예측 시스템의 예측오차를 분석하였다. 본 논문에서는 보다 실제적이고 정확한 성능 및 오차 분석을 위하여 아리랑 2호 정상 운용 및 예상되는 연장 운용 시기와 유사한 태양활동을 보인 기간 동안의 아리랑 1호 실제 데이터를 이용하여 궤도결정 및 예측을 수행하였다. 본 기술 논문의 결과들은 아리랑 2호 APS와 지상 X-Band 수신국 간의 인터페이스 문서에서 할당된 "지상 궤도예측 정밀도"에 대한 분석 및 검증 자료로 활용될 수 있으며, 아리랑 2호 APS의 안정적인 운용에 중요한 참고 자료가 될 것으로 사료된다.

• Journal of Astronomy and Space Sciences
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• 제34권3호
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• pp.207-212
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• 2017

During the last glacial-interglacial transition, there were multiple intense climatic events such as the Bølling-Allerød warming and Younger Dryas cooling. These events show abrupt and rapid climatic changes. In this study, the climate events and cycles during this interval are examined through wavelet analysis of Arctic and Antarctic ice-core $^{18}O$ and tropical marine $^{14}C$ records. The results show that periods of ~1383-1402, ~1029-1043, ~726-736, ~441-497 and ~202-247 years are dominant in the Arctic region, whereas periods of ~1480, ~765, ~518, ~311, and ~207 years are prominent in the Antarctic TALDICE. In addition, cycles of ~1019, ~515, and ~209 years are distinct in the tropical region. Among these variations, the de Vries cycle of ~202-209 years, correlated with variations in solar activity, was detected globally. In particular, this cycle shows a strong signal in the Antarctic between about 13,000 and 10,500 yr before present (BP). In contrast, the Eddy cycle of ~1019-1043 years was prominent in Greenland and the tropical region, but was not detected in the Antarctic TALDICE records. Instead, these records showed that the Heinrich cycle of ~1480 year was very strong and significant throughout the last glacial-interglacial interval.

• 한국초등과학교육학회지:초등과학교육
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• 제34권3호
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• pp.288-296
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• 2015

This study aimed to analysis of concepts and inquiry activities related to the 'Earth Science' area in the South Korean elementary school textbooks to the current and to seek the improvement of future textbook. For the study, we were collected South Korean elementary school textbooks to the current. After the collection had been made, we were analyzed related to the 'Earth' area in the South Korean elementary school textbooks and were extracted central concepts and inquiry activities. The result of this study: First, there were 'A change in the land', 'Strata and Fossil', 'Volcanoes and Earthquakes', 'Earth and Moon', 'The weather', 'The Solar system and the Star', and 'Seasonal Change' in the central concepts related to the 'Earth' area in the South Korean elementary school textbooks to the current. Second, central concepts were almost the same but the curriculum was changed. Third, inquiry activities also were confirmed to be maintained with little change. This result was believed that it can provide a variety of suggestions at this point in changing the curriculum.