• Title/Summary/Keyword: SolI

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Polymerization of Hydrosilanes and Vinyl Monomers in the Presence of Transition Metal Complex

  • Kim, Myoung-Hee;Lee, Jun;Cha, Hyo Chang;Shin, Joong-Hyeok;Woo, Hee-Gweon
    • Journal of Integrative Natural Science
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    • v.2 no.1
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    • pp.18-23
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    • 2009
  • This minireview provides the chosen examples of our recent discoveries in the polymerization of hydrosilanes, dihydrosilole, lactones, and vinyl derivatives using various catalysts. Hydrosilanes and lactones copolymerize to give poly(lactone-co-silane)s with $Cp_2MCl_2$/Red-Al (M = Ti, Zr, Hf) catalyst. Hydrosilanes (including dihydrosilole) reduce noble metal complexes (e.g., $AgNO_3$, $Ag_2SO_4$, $HAuCl_4$, $H_2PtCl_6$) to give nanoparticles along with silicon polymers such as polysilanes, polysilole, polysiloxanes (and silicas) depending on the reaction conditions. Interestingly, phenylsilane dehydrocoupled to polyphenylsilane in the inert nitrogen atmosphere while phenylsilane dehydrocoupled to silica in the ambient air atmosphere. $Cp_2M/CX_4$ (M = Fe, Co, Ni; X = Cl, Br, I) combination initiate the polymerization of vinyl monomers. In the photopolymerization of vinyl monomers using $Cp_2M/CCl_4$ (M = Fe, Co, Ni), the photopolymerization of MMA initiated by $Cp_2M/CCl_4$ (M = Fe, Co, Ni) shows while the polymerization yield decreases in the order $Cp_2Fe$ > $Cp_2Ni$ > $Cp_2Co$, the molecular weight decreases in the order $Cp_2Co$ > $Cp_2Ni$ > $Cp_2Fe$. For the photohomopolymerization and photocopolymerization of MA and AA, the similar trends were observed. The photopolymerizations are not living. Many exciting possibilities remain to be examined and some of them are demonstrated in the body of the minireview.

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Monitoring Vegetation Changes after Constructing the Vegetation-mat Measures for Greening in Embankment - A Case Study of Tancheon, Seongnam - (호안 녹화용 매트 시공 후 식생변화 모니터링 - 성남시 탄천을 중심으로 -)

  • Lee, Soo-Dong;Kang, Hyun-Kyung;Jang, Han-Sol
    • Korean Journal of Environment and Ecology
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    • v.24 no.3
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    • pp.302-317
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    • 2010
  • In this study, not only to present the management plan but also to verify the effectiveness for a area of improving the landscape and the area of creating the base of bio-inhabitation in Tancheon stream concrete embankment where were practised the vegetation-mat measures for greening via monitoring i.e. restoration progress. The results of monitoring, there were a total of 41 taxa, 18 families, 38 species, 3 varieties in 2006, moreover in the 2007, there were a total of 59 taxa, 19 families, 56 species, 3 varieties and in the period 2008, 64 taxa, 29 families, 59 species, 8 varieties. Therefore, these site has increased the plant spaces year by year. The distribution of vegetation characteristics shows that Miscanthus sacchariflorus and Pennisetum alopecuroides expands their influence in the area of applying the construction method. Those area appears a diversity of native species by the stream deposition at the flood. Thus, its condition is very soundly ecological health and eco-friend. At present, native species have been dominant, however, disturbed species and invasive species can be expected to increase dramatically in the future. Therefore, it is necessary to a long-range monitoring and management for maintaining an environmentally sound aquatic ecosystem. On this area refer to mix the river vegetation of primary succession and disturbed vegetation. For that reason, the method of constructing the vegetation-mat measures for greening in embankment does not need to remove the concrete and can install a coir-mat on the top. It leads to improve the landscape, moreover, it was analysed the such dramatic changes in the vegetation species richness by providing continuous the plant growth basis have a impact on in bio-diversity.

CdS-Titania-Nanotube Composite Films for Photocatalytic Hydrogen Production (CdS/Titania-나노튜브 복합 막을 이용한 광촉매적 수소제조)

  • Lee, Hyun-Mi;So, Won-Wook;Baeg, Jin-Ook;Kong, Ki-Jeong;Moon, Sang-Jin
    • Journal of Hydrogen and New Energy
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    • v.18 no.3
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    • pp.230-237
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    • 2007
  • Titania nanotube(TiNT) and CdS sol were synthesized by hydrothermal reaction under strongly basic condition and by precipitation reaction of $Cd(N0_3)_2$ and $Na_2S$ aqueous solutions, respectively. After preparing a series of CdS-TiNT composite films on $F:SnO_2$ conducting glass with variation of the mole ratio (r) of TiNT/(CdS+TiNT), their visible light absorption, photocatalytic activities for hydrogen production, and the photocurrent generation were examined. In general, this CdS-TiNT series showed lower photocatalytic activities and photocurrent generation under Xe light irradiation compared to their counterparts, i.e., CdS-$TiO_2$ particulate series. It appeared that TiNTs are not so effective photocatalyic material in spite of their larger specific surface areas compared to $TiO_2$ nanoparticles, because they indicate a poor crystallinity and less intimate interaction or contact with CdS particles owing to the tubular morphology and an easy agglomeration among themselves.

Characteristics of Chaff Echoes Observed by X-band Dual Polarization Radar (X-밴드 이중편파레이더에서 관측된 채프에코의 특성)

  • Seo, Eun-Kyoung;Park, Sora;Nam, Kyung-Yeub;Heo, Sol-Ip
    • Journal of the Korean earth science society
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    • v.34 no.1
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    • pp.1-12
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    • 2013
  • To effectively remove chaff echoes, which are often misidentified as precipitation echoes on weather radars, this study examines the relationship between the radar reflectivity and each of dual polarimetric parameters. The dual polarimetric parameters are collected only for the echo areas identified as chaff echoes on the NIMR X-band dual polarization radar. Overall, the polarimetric parameters (i.e., reflectivity, differential reflectivity, cross correlation coefficient, standard deviation of differential reflectivity and specific differential phase) for chaff echoes have a wider range of values than those for precipitation echoes and the chaff filaments tend to be horizontally oriented to radar beams. There appears to be a considerable overlap in the cross correlation coefficient range of chaff and precipitation echoes since some precipitation echoes have cross correlation coefficient lower than 0.8. Therefore, although the cross correlation coefficient is known to be a good variable in identifying and separating chaff echoes from precipitation echoes, it is suggested that additional care should be taken when using the cross correlation coefficient solely in removing chaff echoes.

The Effect of Submergence on Phosphorus Adsorption Characteristics in Soils II. Phosphorus Adsorption and Fractions of Inorganic Phosphorus (담수처리(湛水處理)가 토양(土壤)의 인산(燐酸) 흡착(吸着) 특성(特性)에 미치는 영향(影響) II. 인산흡착(燐酸吸着)과 무기태(無機態) 인산(燐酸) 분획(分劃))

  • Kim, Chan-Sub;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.4
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    • pp.248-253
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    • 1991
  • This study examines the effect of submergence on transformations of inorganic phosphorus and the relation between fractions of inorganic phosphorus and adsorbed phosphorus in Gangseo (paddy soil), Yesan (non-cultivated soil), and Jungdong soil (upland soil). The soils were submerged with glucose sol'n at $28^{\circ}C$ for 17 days. After, the soils were incubated with phosphate solution at $25^{\circ}C$ for 24 hours. The seguential fractionation of inorganic phosphorus and of iron were conducted to investigate transformations of them. Results obtained are as follows; 1. By submergence, Bray I-P were decreased from 53mgP/kg to 48mgP/kg in Gangseo, from 3mgP/kg to 1mgP/kg in Yesan, and from 120mgP/kg to 56mgP/kg in Jungdong soil. 2. $NH_4F$ extractable P was dominant fraction of adsorbed P. It was transformed into NaOH extractable P by submergence in Jungdong soil. 3. Dithionite-citrate-bicarbonate extractable iron (crystalline Fe) was transformed to oxalate extractable iron (amorphous Fe) by submergence in Yesan soil.

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Studies on Morphological Variation Among Provenances of a Rare Rhododendron micranthum in Korea (희귀 식물 꼬리진달래의 형태적 변이)

  • Kim, Nam Young;Kim, Heung Sik;Kim, Sol Young;Park, Wan Geun
    • Journal of Korean Society of Forest Science
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    • v.95 no.1
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    • pp.55-59
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    • 2006
  • The objectives of this study, an analysis of the morphological characteristics among six provenances of a rare Rhododendron micranthum could be used for the conservation of gene resources and could provide information on superior trees selection. The following results were obtained. Approximately Mt.worak region showed larger values at petal character. On the other hand, Bonghwa region showed smaller values at petal character. Yeonha-ri region showed larger values at leaf character. On the other hand, Bonghwa region showed smaller values at leaf character. The results of principal component analysis (PCA) for morphological characteristics showed that the first for principal components(PC's) explained 41.6% of the total variation. From th third PC explained 81.5% of the total variation. The first PC was correlated with those characteristics that were mainly related to the Petal length (PL), Leaf length (LL) width (LW), Stigma length (SL). The second PC was correlated with the Petiole length (PTW), Anther length (AL). The third PC was correlated with the Flower pedicel length (FPL), Filament length (FL). Therefore, these characteristics was important to analysis of the variation for morphological characteristics among provenances of Rhododendron micranthum. Cluster analysis using single linkage method based on morphological characteristics showed that six provenances of Rhododendron micranthum could be clustered into three groups. Group I is Jicdong-ri, Group II is Mt.worak and Yeonha-ri, and Group III is Taeback, Bonghwa, and Samcheok. These results corresponded well with that of principal component analysis.

Fabrication of the Conductive Fiber Coated Sb-doped SnO2 Layer (Sb-doped SnO2를 코팅한 도전성 섬유의 제조)

  • Kim, Hong-Dae;Choi, Jin-Sam;Shin, Dong-Woo
    • Journal of the Korean Ceramic Society
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    • v.39 no.4
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    • pp.386-393
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    • 2002
  • Fabricatio of the potassium-titanate fiber with K2O${\cdot}nTiO_2$ composition and coating of electrically conductive Sb-doped $SnO_2$ (ATO: Antimony Tin Oxide) layer on the fiber on the fiber were the fiber were the aims of this work. The fiber fabricated by slow-cooling technique showed the mean length of $15{\mu}m$ and mean diameter of $0.5{\mu}m$. Three different coating methods i.e, sol-gel, co-precipitation and urea technique, were attempted to coat the conductive ATO layer on the potassium-titanate fiber. The influences of coating method, concentrations of ATO(5∼70wt%) and Sb (0∼20wt%), temperature in the range of $450\;to\;800^{\circ}C$, number of washing (3∼4 times) on the resistivity of the ATO coated fiber were examined in details. The fiber coated ATO by coprecipitation exhibited lower resistivity of 103${\Omega}{\cdot}$cm at the 30 wt% of ATO, and showed nearly constant low value of $60{\Omega}{\cdot}cm\;to\;90{\Omega}{\cdot}$cm at the higher concentration of ATO.

A Music Technology-Based Interactive Music-Making for Improving the Social Communication Skills of Children With Autism Spectrum Disorder (자폐스펙트럼장애 아동의 사회적 의사소통 향상을 위한 음악제작 앱 기반 상호적 음악만들기 사례)

  • Yoon, Sol
    • Journal of Music and Human Behavior
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    • v.18 no.2
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    • pp.19-43
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    • 2021
  • The purpose of this case study was to examine whether an interactive music-making intervention using GarageBand was applicable to improve the social communication skills of school-age children with autism spectrum disorder (ASD). Two children with ASD (both male, ages = 8 and 11 yrs.) participated in this study. The interactive music-making intervention included three stages: 1) musical imitation, 2) musical expression and coordination, and 3) musical interaction. Each session lasted 40 minutes, and sessions took place twice a week over 4 weeks. The participants' social communication behaviors were observed and analyzed in terms of exchanging ideas with each other. Engagement in interactive behaviors (e.g., turn-taking, imitating or reflecting the investigator's music, and creating one's own music using the motive from the investigator) during music making was also analyzed. During the sessions, increases in the attempts to express their opinions on music making processes and requests for help for the process were observed. Engagement in turn-taking form of interactive playing and reflecting the musical motive from a partner (i.e., investigator) were also improved. The Social Responsiveness Scale-2 (SRS-2) ratings indicated negative social behaviors decreased after intervention in both participants. The findings of this study suggest that interactive music-making activities using GarageBand can be an effective method in clinical practice to improve social communication skills for school-aged children with ASD.

Thin film growth of ε-Ga2O3 and photo-electric properties of MSM UV photodetectors (ε-Ga2O3 박막 성장 및 MSM UV photodetector의 전기광학적 특성)

  • Park, Sang Hun;Lee, Han Sol;Ahn, Hyung Soo;Yang, Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.4
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    • pp.179-186
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    • 2019
  • In this study, we investigated the structural properties of $Ga_2O_3$ thin films and the photo-electrical properties of metal-semiconductor-metal (MSM) photodetectors deposited by Ti/Au electrodes. $Ga_2O_3$ thin films were grown at different temperatures using metal organic chemical vapor deposition (MOCVD). The crystal phase of $Ga_2O_3$ changed from ${\varepsilon}$-phase to ${\beta}$-phase depending on the growth temperature. The crystal structure of ${\varepsilon}-Ga_2O_3$ was confirmed by X-ray diffraction (XRD) analysis and the formation mechanism of crystal structure was discussed by scanning electron microscopy (SEM) images. From the results of current-voltage (I-V) and time-dependent photoresponse characteristics under the illumination of external lights, we confirmed that the MSM photodetector fabricated by ${\varepsilon}-Ga_2O_3$ showed much better photocurrent characteristics in the 266 nm UV range than in the visible range.

Characterization of Phenotypic Traits and Application of Fruit Flesh Color Marker in Melon (Cucumis melo L.) Accessions (멜론 유전자원의 생육 평가와 과육색 유전형 분석)

  • Bae, Ik Hyun;Kang, Han Sol;Jeong, Woo Jin;Ryu, Jae Hwang;Lee, Oh Hum;Chung, Hee
    • Korean Journal of Plant Resources
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    • v.34 no.5
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    • pp.478-490
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    • 2021
  • We aimed to generate basic breeding data for melon (Cucumis melo L.). A total of 219 melon accessions conserved at the National Agrobiodiversity Center (NAC) in Rural Development Administration (RDA) were used in this study, of which 72 (33%) were collected from India. The majority of accessions showed orange (42%) and white (36%) flesh color. In addition to phenotypic evaluations, the accessions were genotyped using a molecular marker for the carotenoid biosynthesis gene CmOr. DNA fragments of the expected size were amplified in 205 out of 219 accessions. Digestion of the PCR products with HinfI restriction endonuclease showed 100% concordance between phenotype and genotype in green-fleshed accessions, but 98%, 97%, and 80% concordance in orange-, white-, and creamy-fleshed accessions, respectively. Sequence analysis revealed single nucleotide changes in the three positions of SNP1, SNP2 and SNP1int in the CmOr gene among accessions. These newly found alleles suggest that there are multiple mechanisms in determining fruit flesh color in melon. Also, the phenotype data of diverse accessions obtained in this study will be a valuable source for melon breeding.